Allophane from Maid of Sunshine Mine, Courtland-Gleeson District, Cochise County, Arizona, US
|Color||White, pale blue to sky-blue, green, brown, yellow|
|Crystal habit||Crusts and masses|
|Mohs scale hardness||3|
|Luster||Waxy to earthy|
Allophane is an amorphous to poorly crystalline hydrous aluminium silicate clay mineraloid. Its chemical formula is Al2O3·(SiO2)1.3-2·(2.5-3)H2O. Since it has short-range atomic order, it is a mineraloid, rather than a mineral, and can be identified by its distinctive infrared spectrum and its X-ray diffraction pattern. It was first described in 1816 in Gräfenthal, Thuringia, Germany. Allophane is a weathering or hydrothermal alteration product of volcanic glass and feldspars and sometimes has a composition similar to kaolinite but generally has a molar ratio of Al:Si = 2. It typically forms under mildly acidic to neutral pH (5-7). Its structure has been debated, but it is similar to clay minerals and is composed of curved alumina octahedral and silica tetrahedral layers. Transmission electron micrographs show that it is generally made up of aggregates of hollow spherules ~3-5 nm in diameter. Allophane can alter to form halloysite under resilicating aqueous conditions and can alter to form gibbsite under desilicating conditions. A copper containing variety cupro-allophane has been reported.
- Smalley,I.J. 1979. A spherical structure for allophane. Nature 281, 339 only
- Webmineral data
- Handbook of Mineralogy
- Wada, K. (1989), Allophane and Imogolite in Minerals in Soil Environments, Soil Science Society of America, no.1, pp. 1051–1087.
- Parfitt, R.L. (1990), Allophane in New Zealand. A Review. Australian Journal of Soil Research 28, pp. 343–360.
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