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Aluminium cyanide
Names
IUPAC name
Aluminium tricyanide
Identifiers
ChemSpider
InChI=1S/3CN.Al/c3*1-2;/q3*-1;+3
Key: BIABJQLRIVAXSJ-UHFFFAOYSA-N
[C-]#N.[C-]#N.[C-]#N.[Al+3]
Properties
C 3 Al N 3
Molar mass
105.036 g·mol−1
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Aluminium cyanide is a metallic cyanide . The chemical formula is Al(CN)3 .[1] Aluminium cyanide was produced as an ammoniate by reacting aluminium metal with mercuric cyanide in liquid ammonia . Aluminium cyanide is destroyed by water to form aluminium hydroxide .[1]
References [ edit ]
^ a b Bergstrom, F. W. (July 1924). "The Reaction Between Mercuric Cyanide and Certain Metals in Liquid Ammonia". Journal of the American Chemical Society . 46 (7): 1559–1568. doi :10.1021/ja01672a002 .
Al(I)
Al(II) Al(III) Alums Organoaluminium(III) compounds
Salts and covalent derivatives of the
cyanide ion
HCN
He
LiCN
Be(CN)2
B(CN)3
C(CN)4 C2 (CN)2
NH4 CN , N3 CN
OCN− ,-NCO
FCN
Ne
NaCN
Mg(CN)2
Al(CN)3
Si(CN)4 ,(CH3 )3 SiCN
P(CN)3
SCN− ,-NCS ,(SCN)2 ,S(CN)2
ClCN
Ar
KCN
Ca(CN)2
Sc(CN)3
Ti
V
Cr(CN)6 3−
Mn
Fe(CN)2 ,Fe(CN)6 4− ,Fe(CN)6 3−
Co(CN)2
Ni(CN)2 Ni(CN)4 2− Ni(CN)4 4−
CuCN
Zn(CN)2
Ga(CN)3
Ge
As(CN)3 ,(CH3 )2 AsCN
SeCN− (SeCN)2 Se(CN)2
BrCN
Kr
RbCN
Sr(CN)2
Y(CN)3
Zr
Nb
Mo(CN)8 4−
Tc
Ru
Rh
Pd(CN)2
AgCN
Cd(CN)2
In(CN)3
Sn
Sb(CN)3
Te
ICN
Xe
CsCN
Ba(CN)2
*
Lu(CN)3
Hf
Ta
W(CN)8 4−
Re
Os
Ir
Pt(CN)4 2- , Pt(CN)6 4-
AuCN ,K[Au(CN)2 ]
Hg2 (CN)2 , Hg(CN)2
TlCN
Pb(CN)2
Bi(CN)3
Po
At
Rn
Fr
Ra
**
Lr
Rf
Db
Sg
Bh
Hs
Mt
Ds
Rg
Cn
Nh
Fl
Mc
Lv
Ts
Og
*
La(CN)3
Ce(CN)3 , Ce(CN)4
Pr
Nd
Pm
Sm(CN)3
Eu(CN)3
Gd(CN)3
Tb
Dy(CN)3
Ho(CN)3
Er
Tm
Yb(CN)3
**
Ac(CN)3
Th(CN)4
Pa
UO2 (CN)2
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
Md
No