# Americium-241

Americium-241

Small button containing 241AmO2 from a smoke alarm

General
Name, symbol Americium-241,241Am
Neutrons 146
Protons 95
Nuclide data
Natural abundance synthetic
Half-life 432.2 years
Parent isotopes 241Pu (β)
241Cm (EC)
245Bk (α)
Decay products 237Np
Spin 5/2-
Excess energy 52,930 keV
Decay mode Decay energy
α-decay (alpha) 5.486 MeV
γ-emission (gamma) .0595409 MeV
CD (Cluster Decay)
SF (Spontaneous Fission)

Americium-241 (241Am) is an isotope of americium. Like all isotopes of americium, it is radioactive. 241Am is the most common isotope of americium. It is the most prevalent isotope of americium in nuclear waste. Americium-241 has a half-life of 432.2 years. It is commonly found in ionization type smoke detectors. It is a potential fuel for long-lifetime radioisotope thermoelectric generators (RTGs). Its common parent nuclides are β- from 241Pu, EC from 241Cm and α from 245Bk. 241Am is fissile and the critical mass of a bare sphere is 57.6-75.6 kilograms and a sphere diameter of 19–21 centimeters.[1] Americium-241 has a specific activity of 3.43 Ci/g (Curies per gram or 117.29 Gigabequerels (GBq) per gram).[2] It is commonly found in the form of americium-241 dioxide (241AmO2). This isotope also has one meta state; 241mAm, with an exitation energy of 2.2 MeV, and a half-life of 1.23 μs. Its presence in plutonium is determined by the original concentration of plutonium-241 and the sample age. Because of the low penetration of alpha radiation, americium-241 only poses a health risk when ingested or inhaled. Older samples of plutonium containing plutonium-241 contain a buildup of 241Am. A chemical removal of americium-241 from reworked plutonium (e.g. during reworking of plutonium pits) may be required in some cases.

## Nucleosynthesis

Americium-241 has been produced in small quantities in nuclear reactors for decades, and many kilograms of 241Am have been accumulated by now.[3] Nevertheless, since it was first offered for sale in 1962, its price, about 1,500 USD per gram of 241Am, remains almost unchanged owing to the very complex separation procedure.[4]

Americium-241 is not synthesized directly from uranium – the most common reactor material – but from the plutonium isotope 239Pu. The latter needs to be produced first, according to the following nuclear process:

${\displaystyle \mathrm {^{238}_{\ 92}U\ {\xrightarrow {(n,\gamma )}}\ _{\ 92}^{239}U\ {\xrightarrow[{23.5\ min}]{\beta ^{-}}}\ _{\ 93}^{239}Np\ {\xrightarrow[{2.3565\ d}]{\beta ^{-}}}\ _{\ 94}^{239}Pu} }$

The capture of two neutrons by 239Pu (a so-called (n,γ) reaction), followed by a β-decay, results in 241Am:

${\displaystyle \mathrm {^{239}_{\ 94}Pu\ {\xrightarrow {2~(n,\gamma )}}\ _{\ 94}^{241}Pu\ {\xrightarrow[{14.35\ yr}]{\beta ^{-}}}\ _{\ 95}^{241}Am} }$

The plutonium present in spent nuclear fuel contains about 12% of 241Pu. Because it converts to 241Am, 241Pu can be extracted and may be used to generate further 241Am.[4] However, this process is rather slow: half of the original amount of 241Pu decays to 241Am after about 14 years, and the 241Am amount reaches a maximum after 70 years.[5]

The obtained 241Am can be used for generating heavier americium isotopes by further neutron capture inside a nuclear reactor. In a light water reactor (LWR), 79% of 241Am converts to 242Am and 10% to its nuclear isomer 242mAm:[6]

79%:   ${\displaystyle \mathrm {^{241}_{\ 95}Am\ {\xrightarrow {(n,\gamma )}}\ _{\ 95}^{242}Am} }$

## Decay

Main article: Radioactive decay

Americium-241 decays mainly via alpha decay, with a weak gamma ray product. The α-decay is shown as follows:

${\displaystyle \mathrm {^{241\!\,}_{\ 95}Am\ {\overset {432.2y}{\longrightarrow }}\ _{\ 93}^{237}Np~+~_{2}^{4}\alpha ^{2+}+\gamma ~59.5409~keV} }$

The α-decay energies are 5.486 MeV for 85% of the time (the one which is widely accepted for standard α-decay energy), 5.443 MeV for 13% of the time, and 5.388 MeV for the remaining 2%.[7] The γ-ray energy is 59.5409 keV for the most part, with little amounts of other energies such as 13.9 keV, 17.8 keV and 26.4 keV.[8]

The second most common type of decay for americium-241 is cluster decay, with a branching ratio of less than 7.4×10−16. Also shown as follows:

${\displaystyle \mathrm {^{241\!\,}_{\ 95}Am\longrightarrow _{\ 81}^{207}Tl+_{14}^{34}Si} }$

The least common (rarest) type of decay that americium-241 undergoes is spontaneous fission, with a branching ratio of 4×10-12 and happening 1.2 times a second per gram of 241Am. It is written as such (the asterisk denotes an excited nucleus):

${\displaystyle \mathrm {^{241}_{\ 95}Am\longrightarrow ~_{\ 95}^{241}Am^{*}\longrightarrow 3_{0}^{1}n~+~fission~products~+energy~(\gamma )} }$

## Applications

### Ionization-type smoke detector

Main article: Smoke detector

Americium-241 is the only synthetic isotope to have found its way into the household, where the most common type of smoke detector (the ionization-type) uses 241AmO2 (americium-241 dioxide) as its source of ionizing radiation.[9] This isotope is preferred over 226Ra as 241Am emits 5 times more alpha particles and also emits relatively little harmful gamma radiation. With its half-life of 432.2 years, the americium in a smoke detector decreases and includes about 4.4% neptunium after 19 years, and about 7.4% after 32 years.The amount of americium in a typical new smoke detector is 0.29 microgram (about one-third the weight of a grain of sand) with an activity of 1 microcurie/37 kilobequerels (1.0 μCi/37 kBq). Some old industrial smoke detectors (notably from the Pyrotronics Corporation) can contain up to 80 μCi. The amount of 241Am declines slowly as it decays into neptunium-237 a different transuranic element with a much longer half-life (about 2.14 million years). With its half-life of 432.2 years, the americium in a smoke detector includes about 4.4% neptunium after 19 years, and about 7.4% after 32 years. The radiated alpha-particles pass through an ionization chamber, an air-filled space between two electrodes, which allows a small, constant electric current to pass between the capacitor plates due to the radiation ionizing the air space between. Any smoke that enters the chamber blocks/absorbs some of the alpha particles from freely passing through and reduces the ionization and therefore causes a drop in the current. The alarm's circuitry detects this drop in the current and as a result, triggers the piezoelectric buzzer to sound. Compared to the alternative optical smoke detector, the ionization smoke detector is cheaper and can detect particles which are too small to produce significant light scattering. However, it is more prone to false alarms.[10][11][12][13]

As 241Am has a roughly similar half-life to 238Pu (432.2 years vs. 87 years), it has been proposed as an active isotope of radioisotope thermoelectric generators, for use in spacecraft.[14][15] Even though americium-241 produces less heat and electricity than plutonium-238 (the power yield is 114.7 mW/g for 241Am vs. 390 mW/g for 238Pu). [14] and although its radiation poses a bigger threat to humans owing to gamma and neutron emission, the European Space Agency is still considering to use americium-241 for its space probes, as a result of the global shortage of plutonium-238.[16]

### Neutron source

Oxides of 241Am pressed with beryllium can be very efficient neutron sources, since it emits alpha particle during its radioactive decay:

${\displaystyle \mathrm {^{241\!\,}_{\ 95}Am\ {\overset {432.2y}{\longrightarrow }}\ _{\ 93}^{237}Np\ +\ _{2}^{4}\alpha ^{2+}+\ \gamma ~59.5~keV} }$

Here americium acts as the alpha source, and beryllium produces neutrons owing to its large cross-section for the (α,n) nuclear reaction:

${\textstyle \mathrm {^{9}_{4}Be\ +\ _{2}^{4}\alpha ^{2+}\longrightarrow \ _{\ 6}^{12}C\ +\ _{0}^{1}n\ +\ \gamma } }$

The most widespread use of 241AmBe neutron sources is a neutron probe – a device used to measure the quantity of water present in soil, as well as moisture/density for quality control in highway construction. 241Am neutron sources are also used in well logging applications, as well as in neutron radiography, tomography and other radiochemical investigations.

### Production of other elements

Chart displaying actinides and their decays and transmutations.

Americium-241 is sometimes used as a starting material for the production of other transuranic elements and transactinides – for example, neutron bombardment of 241Am yields 242Am:

${\displaystyle \mathrm {^{241}_{\ 95}Am\ {\xrightarrow {(n,\gamma )}}\ _{\ 95}^{242}Am} }$

From there, 82.7% of 242Am decays to 242Cm and 17.3% to 242Pu:

82.7% ${\displaystyle \mathrm {^{241}_{\ 95}Am\ {\xrightarrow {(n,\gamma )}}\ _{\ 95}^{242}Am\ {\xrightarrow[{16.02\ h}]{\beta ^{-}}}\ _{\ 96}^{242}Cm} }$

17.3% ${\displaystyle \mathrm {^{241}_{\ 95}Am\ {\xrightarrow {(n,\gamma )}}\ _{\ 95}^{242}Am\ {\xrightarrow[{16.02\ h}]{\beta ^{+}}}\ _{\ 94}^{242}Pu} }$

In the nuclear reactor, 242Am is also up-converted by neutron capture to 243Am and 244Am, which transforms by β-decay to 244Cm:

${\displaystyle \mathrm {^{242}_{\ 95}Am{\xrightarrow {(n,\gamma )}}~_{\ 95}^{243}Am\ {\xrightarrow {(n,\gamma )}}\ _{\ 95}^{244}Am\ {\xrightarrow[{10.1\ h}]{\beta ^{-}}}\ _{\ 96}^{244}Cm} }$

Irradiation of 241Am by 12C or 22Ne ions yields the isotopes 253Es (einsteinium) or 263Db (dubnium), respectively.[17] Furthermore, the element berkelium (243Bk isotope) had been first intentionally produced and identified by bombarding 241Am with alpha particles, in 1949, by the same Berkeley group, using the same 60-inch cyclotron that had been used for many previous experiments. Similarly, nobelium was produced at the Joint Institute for Nuclear Research, Dubna, Russia, in 1965 in several reactions, one of which included irradiation of 243Am with 15N ions. Besides, one of the synthesis reactions for lawrencium, discovered by scientists at Berkeley and Dubna, included bombardment of 243Am with 18O.[18]

### Spectrometer

Americium-241 has been used as a portable source of both gamma rays and alpha particles for a number of medical and industrial uses. The 59.5409 keV gamma ray emissions from 241Am in such sources can be used for indirect analysis of materials in radiography and X-ray fluorescence spectroscopy, as well as for quality control in fixed nuclear density gauges and nuclear densometers. For example, this isotope has been employed to gauge glass thickness to help create flat glass.[19] Americium-241 is also suitable for calibration of gamma-ray spectrometers in the low-energy range, since its spectrum consists of nearly a single peak and negligible Compton continuum (at least three orders of magnitude lower intensity).[20]

### Medicine

Americium-241 gamma rays has been used to provide passive diagnosis of thyroid function. This medical application is now obsolete. Americium-241's gamma rays can provide reasonable quality radiograghs, with a 10 minute exposure time. 241Am radiographs have only been taken for experimentally and are never used due to the long exposure time which is carcinogenic (due to gamma exposure), as well as the fact that like before, it takes a long time.[21]

## Hazards

Americium-241 is a form of americium therefore having the same general hazards. Americium and its isotopes are both extremely toxic and radioactive. Although α-particles can be stopped by a sheet of paper, there are serious health concerns for ingestion of α-emitters. Americium and its isotopes are also very chemically toxic as well, in the form of heavy-metal toxicity.

Americium-241 is an α-emitter with a weak γ-ray byproduct. It is crucial to handle americium-241 with knowing proper safety precautions, as without them it would be extremely dangerous. Its specific gamma dose constant is 3.14 x 10−1 mR/hr/mCi or 8.48 x10−5 mSv/hr/MBq at 1 meter[22]

If consumed, americium-241 is excreted within a few days and only 0.05% is absorbed in the blood. From there, roughly 45% of it goes to the liver and 45% to the bones, and the remaining 10% is excreted. The uptake to the liver depends on the individual and increases with age. In the bones, americium is first deposited over cortical and trabecular surfaces and slowly redistributes over the bone with time. The biological half-life of 241Am is 50 years in the bones and 20 years in the liver, whereas in the gonads (testicles and ovaries) it remains permanently; in all these organs, americium promotes formation of cancer cells as a result of its radioactivity.[23]

Americium-241 often enters landfills from discarded smoke detectors. The rules associated with the disposal of smoke detectors are relaxed in most jurisdictions. In the U.S., the "Radioactive Boy Scout" David Hahn was able to concentrate americium-241 from smoke detectors after managing to buy a hundred of them at remainder prices and also stealing a few.[24][25][26][27] There have been a few cases of exposure to americium-241, the worst case being that of Harold McCluskey, who at the age of 64 was exposed to 500 times the occupational standard for americium-241 as a result of an explosion in his lab. McCluskey died at the age of 75, not as a result of exposure, but of a heart disease which he had before the accident.[28][29]

## References

1. ^
2. ^ "The Preparation, Properties and Uses of Americium-241, Alpha, Gamma and Neutron Sources" (PDF). Oak Ridge National Laboratory.
3. ^ Greenwood, p. 1262
4. ^ a b Smoke detectors and americium, World Nuclear Association, January 2009, Retrieved 28 November 2010
5. ^ BREDL Southern Anti-Plutonium Campaign, Blue Ridge Environmental Defense League, Retrieved 28 November 2010
6. ^ Sasahara, A.; et al. (2004). "Neutron and Gamma Ray Source Evaluation of LWR High Burn-up UO2 and MOX Spent Fuels". Journal of Nuclear Science and Technology 41 (4): 448–456. doi:10.3327/jnst.41.448. article/200410/000020041004A0333355.php Abstract
7. ^
8. ^
9. ^ "Smoke Detectors and Americium", Nuclear Issues Briefing Paper 35, May 2002, archived from the original on 2008-03-03, retrieved 2015-08-26
10. ^ Residential Smoke Alarm Performance, Thomas Cleary. Building and Fire Research Laboratory, National Institute of Standards and Technology; UL Smoke and Fire Dynamics Seminar. November 2007
11. ^ Bukowski, R. W. et al. (2007) Performance of Home Smoke Alarms Analysis of the Response of Several Available Technologies in Residential Fire Settings, NIST Technical Note 1455-1
12. ^ "Smoke detectors and americium-241 fact sheet" (PDF). Canadian Nuclear Society. Retrieved 31 August 2009.
13. ^ Gerberding, Julie Louise (2004). "Toxicological Profile For Americium" (PDF; 2.1 MB). United States Department of Health and Human Services/Agency for Toxic Substances and Disease Registry. Archived (PDF) from the original on 6 September 2009. Retrieved 29 August 2009.
14. ^ a b Basic elements of static RTGs
15. ^ G.L. Kulcinski, NEEP 602 Course Notes (Spring 2000), Nuclear Power in Space, University of Wisconsin Fusion Technology Institute (see last page)
16. ^ Space agencies tackle waning plutonium stockpiles, Spaceflight now, 9 July 2010
17. ^ Binder, Harry H. (1999). Lexikon der chemischen Elemente: das Periodensystem in Fakten, Zahlen und Daten : mit 96 Abbildungen und vielen tabellarischen Zusammenstellungen. ISBN 978-3-7776-0736-8.
18. ^ Greenwood, p. 1252
19. ^ Greenwood, p. 1262
20. ^ Nuclear Data Viewer 2.4, NNDC
21. ^ "Americium-241 Uses" (PDF).
22. ^
23. ^ Frisch, Franz Crystal Clear, 100 x energy, Bibliographisches Institut AG, Mannheim 1977, ISBN 3-411-01704-X, p. 184
24. ^
25. ^ "'Radioactive Boy Scout' Charged in Smoke Detector Theft". Fox News. 4 August 2007. Archived from the original on 8 December 2007. Retrieved 28 November 2007.
26. ^ "Man dubbed 'Radioactive Boy Scout' pleads guilty". Detroit Free Press. Associated Press. 27 August 2007. Archived from the original on 29 September 2007. Retrieved 27 August 2007.
27. ^ "'Radioactive Boy Scout' Sentenced to 90 Days for Stealing Smoke Detectors". Fox News. 4 October 2007. Archived from the original on 13 November 2007. Retrieved 28 November 2007.
28. ^ Cary, Annette (25 April 2008). "Doctor remembers Hanford's 'Atomic Man'". Tri-City Herald. Retrieved 17 June 2008.
29. ^ AP wire (3 June 2005). "Hanford nuclear workers enter site of worst contamination accident". Archived from the original on 13 June 2005. Retrieved 17 June 2007.