Antoine Lavoisier

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Antoine-Laurent de Lavoisier
Antoine lavoisier color.jpg
Line engraving by Louis Jean Desire Delaistre, after a design by Julien Leopold Boilly
Born (1743-08-26)26 August 1743
Paris, France
Died 8 May 1794(1794-05-08) (aged 50)
Paris, France
Execution by guillotine
Resting place Picpus Cemetery
Fields biologist, chemist
Alma mater Collège des Quatre-Nations, University of Paris
Notable students Éleuthère Irénée du Pont
Known for
Influences Guillaume-François Rouelle, Étienne Condillac
Signature
Antoine-Laurent Lavoisier by Jules Dalou 1866

Antoine-Laurent de Lavoisier (also Antoine Lavoisier after the French Revolution; French pronunciation: ​[ɑ̃twan lɔʁɑ̃ də lavwazje]; 26 August 1743 – 8 May 1794;[1]) was a French nobleman and chemist central to the 18th-century chemical revolution and had a large influence on both the history of chemistry and the history of biology.[2] He is widely considered in popular literature as the "father of modern chemistry".[3] [4]

It is generally accepted that Lavoisier's great accomplishments in chemistry largely stem from his changing the science from a qualitative to a quantitative one. Lavoisier is most noted for his discovery of the role oxygen plays in combustion. He recognized and named oxygen (1778) and hydrogen (1783) and opposed the phlogiston theory. Lavoisier helped construct the metric system, wrote the first extensive list of elements, and helped to reform chemical nomenclature. He predicted the existence of silicon (1787)[5] and was also the first to establish that sulfur was an element (1777) rather than a compound.[6] He discovered that, although matter may change its form or shape, its mass always remains the same.

Lavoisier was a powerful member of a number of aristocratic councils, and an administrator of the Ferme générale. The Ferme générale was one of the most hated components of the Ancien Régime because of the profits it took at the expense of the state, the secrecy of the terms of its contracts, and the violence of its armed agents.[7] All of these political and economic activities enabled him to fund his scientific research. At the height of the French Revolution, he was accused by Jean-Paul Marat of selling adulterated tobacco and of other crimes, and was eventually guillotined a year after Marat's death.

Biography[edit]

Early life and education[edit]

Antoine-Laurent Lavoisier was born to a wealthy family of the nobility in Paris on 26 August 1743. The son of an attorney at the Parliament of Paris, he inherited a large fortune at the age of five with the passing of his mother.[8] Lavoisier began his schooling at the Collège des Quatre-Nations, University of Paris (also known as the Collège Mazarin) in Paris in 1754 at the age of 11. In his last two years (1760–1761) at the school, his scientific interests were aroused, and he studied chemistry, botany, astronomy, and mathematics. In the philosophy class he came under the tutelage of Abbé Nicolas Louis de Lacaille, a distinguished mathematician and observational astronomer who imbued the young Lavoisier with an interest in meteorological observation, an enthusiasm which never left him. Lavoisier entered the school of law, where he received a bachelor's degree in 1763 and a licentiate in 1764. Lavoisier received a law degree and was admitted to the bar, but never practiced as a lawyer. However, he continued his scientific education in his spare time.

Early scientific work[edit]

Lavoisier's education was filled with the ideals of the French Enlightenment of the time, and he was fascinated by Pierre Macquer's dictionary of chemistry. He attended lectures in the natural sciences. Lavoisier's devotion and passion for chemistry were largely influenced by Étienne Condillac, a prominent French scholar of the 18th century. His first chemical publication appeared in 1764. From 1763 to 1767, he studied geology under Jean-Étienne Guettard. In collaboration with Guettard, Lavoisier worked on a geological survey of Alsace-Lorraine in June 1767. In 1764 he read his first paper to the French Academy of Sciences, France's most elite scientific society, on the chemical and physical properties of gypsum (hydrated calcium sulfate), and in 1766 he was awarded a gold medal by the King for an essay on the problems of urban street lighting. In 1768 Lavoisier received a provisional appointment to the Academy of Sciences.[9] In 1769, he worked on the first geological map of France.

Ferme générale and marriage[edit]

At the age of 26, around the time he was elected to the Academy of Sciences, Lavoisier bought a share in the Ferme générale, a tax farming financial company which advanced the estimated tax revenue to the royal government in return for the right to collect the taxes. His participation in the French Government and the collection of its taxes did not help his reputation when the Reign of Terror began in France, as taxes and poor government reform were the primary motivators during the French Revolution. Lavoisier attempted to introduce reforms in the French monetary and taxation system to help the peasants. While in government work, he helped develop the metric system to secure uniformity of weights and measures throughout France. Lavoisier consolidated his social and economic position when, in 1771 at age 28, he married Marie-Anne Pierrette Paulze, the 13-year-old daughter of a senior member of the Ferme générale.[10] She was to play an important part in Lavoisier's scientific career—notably, she translated English documents for him, including Richard Kirwan's Essay on Phlogiston and Joseph Priestley's research. In addition, she assisted him in the laboratory and created many sketches and carved engravings of the laboratory instruments used by Lavoisier and his colleagues for their scientific works.

Madame Lavoisier edited and published Antoine's memoirs (whether any English translations of those memoirs have survived is unknown as of today) and hosted parties at which eminent scientists discussed ideas and problems related to chemistry.[11] For 3 years following his entry into the Ferme générale, Lavoisier's scientific activity diminished somewhat, for much of his time was taken up with official Ferme générale business. He did, however, present one important memoir to the Academy of Sciences during this period, on the supposed conversion of water into earth by evaporation. By a very precise quantitative experiment Lavoisier showed that the "earthy" sediment produced after long-continued reflux heating of water in a glass vessel was not due to a conversion of the water into earth but rather to the gradual disintegration of the inside of the glass vessel produced by the boiling water.

Gunpowder Commission[edit]

Lavoisier's researches on combustion were carried out in the midst of a very busy schedule of public and private duties, especially in connection with the Ferme Générale. There were also innumerable reports for and committees of the Academy of Sciences to investigate specific problems on order of the royal government. Lavoisier, whose organizing skills were outstanding, frequently landed the task of writing up such official reports. In 1775 he was made one of four commissioners of gunpowder appointed to replace a private company, similar to the Ferme générale, which had proved unsatisfactory in supplying France with its munitions requirements. As a result of his efforts, both the quantity and quality of French gunpowder greatly improved, and it became a source of revenue for the government. His appointment to the Gunpowder Commission brought one great benefit to Lavoisier's scientific career as well. As a commissioner, he enjoyed both a house and a laboratory in the Royal Arsenal. Here he lived and worked between 1775 and 1792.

Final days and execution[edit]

As the French Revolution gained momentum from 1789 on, Lavoisier's world inexorably collapsed around him. Attacks mounted on the deeply unpopular Ferme Générale, and it was eventually suppressed in 1791. In 1792 Lavoisier was forced to resign from his post on the Gunpowder Commission and to move from his house and laboratory at the Royal Arsenal. On 8 August 1793, all the learned societies, including the Academy of Sciences, were suppressed.

It is difficult to assess Lavoisier's own attitude to the political turmoil. Like so many intellectual liberals, he felt that the Ancien Régime could be reformed from the inside if only reason and moderation prevailed. Characteristically, one of his last major works was a proposal to the National Convention for the reform of French education. He tried to remain aloof from the political cockpit, no doubt fearful and uncomprehending of the violence he saw therein. However, on 24 November 1793, the arrest of all the former tax gatherers was ordered. He was branded a traitor by the Convention under Maximilien de Robespierre during the Reign of Terror in 1794. Actions such as attacking distinguished academics such as Antoine Lavoisier helped to establish Robespierre as a tyrant and intolerant of progress; eventually this would be one of the keys to his downfall. Lavoisier had also intervened on behalf of a number of foreign-born scientists including mathematician Joseph Louis Lagrange, which helped to exempt them from a mandate stripping all foreigners of possessions and freedom.[12] Lavoisier was tried, convicted, and guillotined on 8 May 1794 in Paris, at the age of 50, along with his 27 co-defendants.[13]

According to a (probably apocryphal) story, the appeal to spare his life so that he could continue his experiments was cut short by the judge: "La République n'a pas besoin de savants ni de chimistes; le cours de la justice ne peut être suspendu." ("The Republic has no need of scientists or chemists; the course of justice cannot be delayed.")[14] Lavoisier was convicted with summary justice of having plundered the people and the treasury of France, of having adulterated the nation's tobacco with water, and of having supplied the enemies of France with huge sums of money from the national treasury.

Lavoisier's importance to science was expressed by Joseph Louis Lagrange who lamented the beheading by saying: "Il ne leur a fallu qu’un moment pour faire tomber cette tête, et cent années peut-être ne suffiront pas pour en reproduire une semblable." ("It took them only an instant to cut off this head, and one hundred years might not suffice to reproduce its like.")[15][16]

Post-mortem[edit]

A year and a half after his death, Lavoisier was exonerated by the French government. During the White Terror, his private belongings were delivered to his widow, a brief note was included, reading "To the widow of Lavoisier, who was falsely convicted".[17]

About a century after his death, a statue of Lavoisier was erected in Paris. It was later discovered that the sculptor had not actually copied Lavoisier's head for the statue, but used a spare head of the Marquis de Condorcet, the Secretary of the Academy of Sciences during Lavoisier's last years.[citation needed] Lack of money prevented alterations from being made. The statue was melted down during the Second World War and has not since been replaced. However, one of the main "lycées" (high schools) in Paris and a street in the 8th arrondissement are named after Lavoisier, and statues of him are found on the Hôtel de Ville and on the façade of the Cour Napoléon of the Louvre. His name is one of the 72 names of eminent French scientists, engineers and mathematicians inscribed on the Eiffel Tower as well as on buildings around Killian Court at MIT in Cambridge, MA US.

Contributions to chemistry[edit]

Oxygen theory of combustion[edit]

Antoine Lavoisier's famous phlogiston experiment. Engraving by Mme Lavoisier in the 1780s taken from Traité élémentaire de chimie (Elementary treatise on chemistry)

During late 1772 Lavoisier turned his attention to the phenomenon of combustion, the topic on which he was to make his most significant contribution to science. He reported the results of his first experiments on combustion in a note to the Academy on 20 October, in which he reported that when phosphorus burned, it combined with a large quantity of air to produce acid spirit of phosphorus, and that the phosphorus increased in weight on burning. In a second sealed note deposited with the Academy a few weeks later (1 November) Lavoisier extended his observations and conclusions to the burning of sulfur and went on to add that "what is observed in the combustion of sulfur and phosphorus may well take place in the case of all substances that gain in weight by combustion and calcination: and I am persuaded that the increase in weight of metallic calces is due to the same cause."

Joseph Black's "fixed air"[edit]

During 1773 Lavoisier determined to review thoroughly the literature on air, particularly "fixed air," and to repeat many of the experiments of other workers in the field. He published an account of this review in 1774 in a book entitled Opuscules physiques et chimiques (Physical and Chemical Essays). In the course of this review he made his first full study of the work of Joseph Black, the Scottish chemist who had carried out a series of classic quantitative experiments on the mild and caustic alkalies. Black had shown that the difference between a mild alkali, for example, chalk (CaCO3), and the caustic form, for example, quicklime (CaO), lay in the fact that the former contained "fixed air," not common air fixed in the chalk, but a distinct chemical species, now understood to be carbon dioxide (CO2), which was a constituent of the atmosphere. Lavoisier recognized that Black's fixed air was identical with the air evolved when metal calces were reduced with the charcoal and even suggested that the air which combined with metals on calcination and increased the weight might be Black's fixed air, that is, CO2.

Joseph Priestley[edit]

Joseph Priestley, an English chemist known for isolating oxygen, which he termed "dephlogisticated air."

In the spring of 1774 Lavoisier carried out experiments on the calcination of tin and lead in sealed vessels which conclusively confirmed that the increase in weight of metals in combustion was due to combination with air. But the question remained about whether it was combination with common atmospheric air or with only a part of atmospheric air. In October the English chemist Joseph Priestley visited Paris, where he met Lavoisier and told him of the air which he had produced by heating the red calx of mercury with a burning glass and which had supported combustion with extreme vigor. Priestley at this time was unsure of the nature of this gas, but he felt that it was an especially pure form of common air. Lavoisier carried out his own researches on this peculiar substance. The result was his famous memoir On the Nature of the Principle Which Combines with Metals during Their Calcination and Increases Their Weight, read to the Academy on 26 April 1775 (commonly referred to as the Easter Memoir). In the original memoir Lavoisier showed that the mercury calx was a true metallic calx in that it could be reduced with charcoal, giving off Black's fixed air in the process.[18] When reduced without charcoal, it gave off an air which supported respiration and combustion in an enhanced way. He concluded that this was just a pure form of common air, and that it was the air itself "undivided, without alteration, without decomposition" which combined with metals on calcination.

After returning from Paris, Priestley took up once again his investigation of the air from mercury calx. His results now showed that this air was not just an especially pure form of common air but was "five or six times better than common air, for the purpose of respiration, inflammation, and ... every other use of common air." He called the air dephlogisticated air, as he thought it was common air deprived of its phlogiston. Since it was therefore in a state to absorb a much greater quantity of phlogiston given off by burning bodies and respiring animals, the greatly enhanced combustion of substances and the greater ease of breathing in this air were explained.

Pioneer of stoichiometry[edit]

Lavoisier's researches included some of the first truly quantitative chemical experiments. He carefully weighed the reactants and products of a chemical reaction in a sealed glass vessel so that no gases could escape, which was a crucial step in the advancement of chemistry.[19] In 1774, he showed that, although matter can change its state in a chemical reaction, the total mass of matter is the same at the end as at the beginning of every chemical change. Thus, for instance, if a piece of wood is burned to ashes, the total mass remains unchanged if gaseous reactants and products are included. Lavoisier's experiments supported the law of conservation of mass. In France it is taught as Lavoisier's Law and is paraphrased from a statement in his "Traité Élémentaire de Chimie" to "Rien ne se perd, rien ne se crée, tout se transforme." ("Nothing is lost, nothing is created, everything is transformed."). Mikhail Lomonosov (1711–1765) had previously expressed similar ideas in 1748 and proved them in experiments; others whose ideas pre-date the work of Lavoisier include Jean Rey (1583–1645), Joseph Black (1728–1799), and Henry Cavendish (1731–1810). (See An Historical Note on the Conservation of Mass)

Chemical nomenclature[edit]

Lavoisier, together with L. B. Guyton de Morveau, Claude-Louis Berthollet, and Antoine François de Fourcroy, submitted a new program for the reforms of chemical nomenclature to the Academy in 1787, for there was virtually no rational system of chemical nomenclature at this time. This work, titled Méthode de nomenclature chimique (Method of Chemical Nomenclature, 1787), introduced a new system which was tied inextricably to Lavoisier's new oxygen theory of chemistry.[20] The Classical elements of earth, air, fire, and water were discarded, and instead some 55 substances which could not be decomposed into simpler substances by any known chemical means were provisionally listed as elements. The elements included light; caloric (matter of heat); the principles of oxygen, hydrogen, and azote (nitrogen); carbon; sulfur; phosphorus; the yet unknown "radicals" of muriatic acid (hydrochloric acid), boric acid, and "fluoric" acid; 17 metals; 5 earths (mainly oxides of yet unknown metals such as magnesia, barite, and strontia); three alkalies (potash, soda, and ammonia); and the "radicals" of 19 organic acids. The acids, regarded in the new system as compounds of various elements with oxygen, were given names which indicated the element involved together with the degree of oxygenation of that element, for example sulfuric and sulfurous acids, phosphoric and phosphorus acids, nitric and nitrous acids, the "ic" termination indicating acids with a higher proportion of oxygen than those with the "ous" ending. Similarly, salts of the "ic" acids were given the terminal letters "ate," as in copper sulfate, whereas the salts of the "ous" acids terminated with the suffix "ite," as in copper sulfite. The total effect of the new nomenclature can be gauged by comparing the new name "copper sulfate" with the old term "vitriol of Venus." Lavoisier's new nomenclature spread throughout Europe and to the United States and became common use in the field of chemistry. This marked the beginning of the anti-phlogistic approach to the field.

Chemical revolution and opposition[edit]

Antoine Lavoisier is commonly cited as a central contributor to the chemical revolution. His precise measurements and meticulous keeping of balance sheets throughout his experiment were vital to the wide spread acceptance of the law of conservation of mass. His introduction of new terminology, a binomial system modeled after that of Linnaeus, also helps to mark the dramatic changes in the field which are referred to generally as the chemical revolution. However, Lavoisier encountered much opposition in trying to change the field, especially from British phlogistic scientists. Joseph Priestley, Richard Kirwan, James Keir, and William Nicholson, among others, argued that quantification of substances did not imply conservation of mass.[21] Rather than reporting factual evidence, opposition claimed Lavoisier was misinterpreting the implications of his research. One of Lavoisier's allies, Jean Baptiste Biot, wrote of Lavoisier's methodology, "one felt the necessity of linking accuracy in experiments to rigor of reasoning."[21] His opposition, however, that a precision in experimentation did not imply precision in inferences and reasonings. Despite opposition, Lavoisier continued to use precise instrumentation to convince other chemists of his conclusions, often results to five to eight decimal places. Nicholson, who estimated that only three of these decimal places were meaningful, stated:

If it be denied that these results are pretended to be true in the last figures, I must beg leave to observe, that these long rows of figures, which in some instances extend to a thousand times the nicety of experiment, serve only to exhibit a parade which true science has no need of: and, more than this, that when the real degree of accuracy in experiments is thus hidden from our contemplation, we are somewhat disposed to doubt whether the exactitude scrupuleuse of the experiments be indeed such as to render the proofs de l'ordre demonstratif.[22]

Notable works[edit]

Easter memoir[edit]

Antoine Lavoisier Portrait

The "official" version of Lavoisier's Easter Memoir appeared in 1778. In the intervening period Lavoisier had ample time to repeat some of Priestley's latest experiments and perform some new ones of his own. In addition to studying Priestley's dephlogisticated air, he studied more thoroughly the residual air after metals had been calcined. He showed that this residual air supported neither combustion nor respiration and that approximately five volumes of this air added to one volume of the dephlogisticated air gave common atmospheric air. Common air was then a mixture of two distinct chemical species with quite different properties. Thus when the revised version of the Easter Memoir was published in 1778, Lavoisier no longer stated that the principle which combined with metals on calcination was just common air but "nothing else than the healthiest and purest part of the air" or the "eminently respirable part of the air." In the following year Lavoisier coined the name oxygen for this constituent of the air, from the Greek words meaning "acid former."[18] and "Considérations générales sur la nature des acides" ("General Considerations on the Nature of Acids," 1778),[23] He was struck by the fact that the combustion products of such nonmetals as sulfur, phosphorus, charcoal, and nitrogen were acidic. He held that all acids contained oxygen and that oxygen was therefore the acidifying principle.

Dismantling phlogiston theory[edit]

Lavoisier's chemical research between 1772 and 1778 was largely concerned with developing his own new theory of combustion. In 1783 he read to the academy his famous paper entitled Réflexions sur le phlogistique (Reflections on Phlogiston), a full-scale attack on the current phlogiston theory of combustion. That year Lavoisier also began a series of experiments on the composition of water which were to prove an important capstone to his combustion theory and win many converts to it. Many investigators had been experimenting with the combination of Henry Cavendish's inflammable air, which Lavoisier termed hydrogen (Greek for "water-former"), with dephlogisticated air (oxygen) by electrically sparking mixtures of the gases. All of the researchers noted the production of water, but all interpreted the reaction in varying ways within the framework of the phlogiston theory. In cooperation with mathematician Pierre Simon de Laplace, Lavoisier synthesized water by burning jets of hydrogen and oxygen in a bell jar over mercury. The quantitative results were good enough to support the contention that water was not an element, as had been thought for over 2,000 years, but a compound of two gases, hydrogen and oxygen. The interpretation of water as a compound explained the inflammable air generated from dissolving metals in acids (hydrogen produced when water decomposes) and the reduction of calces by inflammable air (combination of gas from calx with oxygen to form water).[21]

Despite these experiments, Lavoisier's antiphlogistic approach remained unaccepted by many other chemists. Lavoisier labored to provide definitive proof of the composition of water, attempting to use this in support of his theory. Working with Jean-Baptiste Meusnier, Lavoisier passed water through a red-hot iron gun barrel, allowing the oxygen to form an oxide with the iron and the hydrogen to emerge from the end of the pipe. He submitted his findings of the composition of water to the Académie des Sciences in April of 1784, reporting his figures to eight decimal places.[21] Opposition responded to this further experimentation by stating that Lavoisier continued to draw the incorrect conclusions, and that his experiment demonstrated the displacement of phlogiston from iron by the combination of water with the metal. Lavoisier developed a new apparatus which utilized a pneumatic trough, a set of balances, a thermometer, and a barometer, all calibrated carefully. Thirty savants were invited to witness the decomposition and synthesis of water using this apparatus, convincing many who attended of the correctness of Lavoisier's theories. This demonstration established water as a compound of oxygen and hydrogen with great certainty for those who viewed it. The dissemination of the experiment, however, proved subpar, as it lacked the details to properly display the amount of precision taken in the measurements. The paper ended with a hasty statement that the experiment was "more than sufficient to lay hold of the certainty of the proposition" of the composition of water and stated that the methods uses in the experiment would unite chemistry with the other physical sciences and advance discoveries.[24]

Lavoisier and Berthollet, Chimistes Celebres, Liebig's Extract of Meat Company Trading Card, 1929

Elementary Treatise of Chemistry[edit]

Lavoisier employed the new nomenclature in his Traité élémentaire de chimie (Elementary Treatise on Chemistry), published in 1789. This work represents the synthesis of Lavoisier's contribution to chemistry and can be considered the first modern textbook on the subject. The core of the work was the oxygen theory, and the work became a most effective vehicle for the transmission of the new doctrines. It presented a unified view of new theories of chemistry, contained a clear statement of the law of conservation of mass, and denied the existence of phlogiston. This text clarified the concept of an element as a substance that could not be broken down by any known method of chemical analysis, and presented Lavoisier's theory of the formation of chemical compounds from elements. It remains a classic in the history of science. While many leading chemists of the time refused to accept Lavoisier's new ideas, demand for Traité élémentaire as a textbook in Edinburgh was sufficient to merit translation into English within about a year of its French publication.[25] In any event, the Traité élémentaire was sufficiently sound to convince the next generation.

Lavoisier's Laboratory, Musée des Arts et Métiers, Paris.
Lavoisier conducting an experiment on respiration in the 1770s

Physiological work[edit]

Constant-pressure calorimeter, engraving made by madame Lavoisier for thermochemistry experiments

The relationship between combustion and respiration had long been recognized from the essential role which air played in both processes. Lavoisier was almost obliged, therefore, to extend his new theory of combustion to include the area of respiration physiology. His first memoirs on this topic were read to the Academy of Sciences in 1777, but his most significant contribution to this field was made in the winter of 1782/1783 in association with Laplace. The result of this work was published in a famous memoir, "On Heat." Lavoisier and Laplace designed an ice calorimeter apparatus for measuring the amount of heat given off during combustion or respiration. The outer shell of the calorimeter was packed with snow, which melted to maintain a constant temperature of 0 °C around an inner shell filled with ice. By measuring the quantity of carbon dioxide and heat produced by confining a live guinea pig in this apparatus, and by comparing the amount of heat produced when sufficient carbon was burned in the ice calorimeter to produce the same amount of carbon dioxide as that which the guinea pig exhaled, they concluded that respiration was in fact a slow combustion process. Lavoisier stated, "la respiration est donc une combustion," that is, respiratory gas exchange is a combustion, like that of a candle burning.[26]

This continuous slow combustion, which they supposed took place in the lungs, enabled the living animal to maintain its body temperature above that of its surroundings, thus accounting for the puzzling phenomenon of animal heat. Lavoisier continued these respiration experiments in 1789–1790 in cooperation with Armand Seguin. They designed an ambitious set of experiments to study the whole process of body metabolism and respiration using Seguin as a human guinea pig in the experiments. Their work was only partially completed and published because of the disruption of the Revolution; but Lavoisier's pioneering work in this field served to inspire similar research on physiological processes for generations to come.

Legacy[edit]

The work of Lavoisier was translated in Japan in the 1840s, through the process of Rangaku. Page from Udagawa Yōan's 1840 Seimi Kaisō

Lavoisier's fundamental contributions to chemistry were a result of a conscious effort to fit all experiments into the framework of a single theory. He established the consistent use of the chemical balance, used oxygen to overthrow the phlogiston theory, and developed a new system of chemical nomenclature which held that oxygen was an essential constituent of all acids (which later turned out to be erroneous).

Lavoisier also did early research in physical chemistry and thermodynamics in joint experiments with Laplace. They used a calorimeter to estimate the heat evolved per unit of carbon dioxide produced, eventually finding the same ratio for a flame and animals, indicating that animals produced energy by a type of combustion reaction.

Statue of Lavoisier, at Hôtel de Ville, Paris

Lavoisier also contributed to early ideas on composition and chemical changes by stating the radical theory, believing that radicals, which function as a single group in a chemical process, combine with oxygen in reactions. He also introduced the possibility of allotropy in chemical elements when he discovered that diamond is a crystalline form of carbon.

He was also responsible for the construction of the gasometer, an expensive instrument he used at his demonstrations. While he used his gasometer exclusively for these, he also created smaller, cheaper, more practical gasometers that worked with a sufficient degree of precision that more chemists could recreate.[27]

He was essentially a theorist, and his great merit lay in his capacity to take over experimental work that others had carried out—without always adequately recognizing their claims—and by a rigorous logical procedure, reinforced by his own quantitative experiments, expounding the true explanation of the results.[citation needed] He completed the work of Black, Priestley and Cavendish, and gave a correct explanation of their experiments.

Overall, his contributions are considered the most important in advancing chemistry to the level reached in physics and mathematics during the 18th century.[28]

Awards and honours[edit]

During his lifetime, Lavoisier was awarded a gold medal by the King of France for his work on urban street lighting (1766), and was appointed to the French Academy of Sciences (1768).[9]

Lavoisier's work was recognized as an International Historic Chemical Landmark by the American Chemical Society, Académie des sciences de L'institut de France and the Société Chimique de France in 1999.[29] Antoine Laurent Lavoisier’s Louis 1788 publication entitled Méthode de Nomenclature Chimique, published with colleagues Louis-Bernard Guyton de Morveau, Claude Louis Berthollet, and Antoine François, comte de Fourcroy,[30] was honored by a Citation for Chemical Breakthrough Award from the Division of History of Chemistry of the American Chemical Society, presented at the Académie des Sciences (Paris) in 2015.[31][32]

A number of Lavoisier Medals have been named and given in Lavoisier's honour, by organizations including the Société chimique de France, the International Society for Biological Calorimetry, and the DuPont company.[citation needed]

Selected writings[edit]

In translation[edit]

  1. "Experiments on the Respiration of Animals, and on the Changes effected on the Air in passing through their Lungs." (Read to the Académie des Sciences, 3 May 1777)
  2. "On the Combustion of Candles in Atmospheric Air and in Dephlogistated Air." (Communicated to the Académie des Sciences, 1777)
  3. "On the Combustion of Kunckel's Phosphorus."
  4. "On the Existence of Air in the Nitrous Acid, and on the Means of decomposing and recomposing that Acid."
  5. "On the Solution of Mercury in Vitriolic Acid."
  6. "Experiments on the Combustion of Alum with Phlogistic Substances, and on the Changes effected on Air in which the Pyrophorus was burned."
  7. "On the Vitriolisation of Martial Pyrites."
  8. "General Considerations on the Nature of Acids, and on the Principles of which they are composed."
  9. "On the Combination of the Matter of Fire with Evaporable Fluids; and on the Formation of Elastic Aëriform Fluids."
  • “Reflections on Phlogiston”, translation by Nicholas W. Best of “Réflexions sur le phlogistique, pour servir de suite à la théorie de la combustion et de la calcination, publiée en 1777” (1783). Published in two parts:
  1. "Lavoisier’s ‘Reflections on phlogiston’ I: against phlogiston theory", Foundations of Chemistry 17(2015), 137-151.
  2. "Lavoisier’s ‘Reflections on phlogiston’ II: on the nature of heat", Foundations of Chemistry 18(2016), 3-13.
  • Method of chymical nomenclature: proposed by Messrs. De Moreau, Lavoisier, Bertholet, and De Fourcroy (1788) Dictionary
  • Elements of Chemistry, in a New Systematic Order, Containing All the Modern Discoveries (Edinburgh: William Creech, 1790; New York: Dover, 1965) translation by Robert Kerr of Traité élémentaire de chimie. ISBN 978-0486646244 (Dover).

Notes[edit]

  1. ^ (French)Lavoisier, le parcours d'un scientifique révolutionnaire CNRS (Centre National de la Recherche Scientifique)
  2. ^ Schwinger, Julian (1986). Einstein's Legacy. New York: Scientific American Library. p. 93. ISBN 0-7167-5011-2. 
  3. ^ "More recently, he has been dubbed the "father of modern nutrition", as being the first to discover the metabolism that occurs inside the human body. Lavoisier, Antoine." Encyclopædia Britannica. 2007. Encyclopædia Britannica Online. 24 July 2007.
  4. ^ Matthew Daniel Eddy; William R. Newman; Seymour Mauskopf (2014). "Chemical Knowledge in the Early Modern World". Chicago: University of Chicago Press. 
  5. ^ In his table of the elements, Lavoisier listed five "salifiable earths" (i.e., ores that could be made to react with acids to produce salts (salis = salt, in Latin)): chaux (calcium oxide), magnésie (magnesia, magnesium oxide), baryte (barium sulfate), alumine (alumina, aluminum oxide), and silice (silica, silicon dioxide). About these "elements", Lavoisier speculates: "We are probably only acquainted as yet with a part of the metallic substances existing in nature, as all those which have a stronger affinity to oxygen than carbon possesses, are incapable, hitherto, of being reduced to a metallic state, and consequently, being only presented to our observation under the form of oxyds, are confounded with earths. It is extremely probable that barytes, which we have just now arranged with earths, is in this situation; for in many experiments it exhibits properties nearly approaching to those of metallic bodies. It is even possible that all the substances we call earths may be only metallic oxyds, irreducible by any hitherto known process." – from page 218 of: Lavoisier with Robert Kerr, trans., Elements of Chemistry, ..., 4th ed. (Edinburgh, Scotland: William Creech, 1799). (The original passage appears in: Lavoisier, Traité Élémentaire de Chimie, ... (Paris, France: Cuchet, 1789), vol. 1, page 174.)
  6. ^ C.Michael Hogan. 2011. Sulfur. Encyclopedia of Earth, eds. A. Jorgensen and C.J.Cleveland, National Council for Science and the environment, Washington DC
  7. ^ Schama, Simon (1989). Citizens: A Chronicle of the French Revolution. Alfred A Knopf. p. 73. 
  8. ^ Wikisource-logo.svg Herbermann, Charles, ed. (1913). "Antoine-Laurent Lavoisier". Catholic Encyclopedia. New York: Robert Appleton Company. 
  9. ^ a b Yount, Lisa (2008). Antoine Lavoisier : founder of modern chemistry. Berkeley Heights, NJ: Enslow Publishers. p. 115. ISBN 978-0766030114. Retrieved 25 July 2016. 
  10. ^ (French)Lavoisier, le parcours d'un scientifique révolutionnaire
  11. ^ Eagle, Cassandra T.; Jennifer Sloan (1998). "Marie Anne Paulze Lavoisier: The Mother of Modern Chemistry". The Chemical Educator. 3 (5): 1–18. doi:10.1007/s00897980249a. 
  12. ^ O'Connor, J. J.; Robertson, E. F. (26 September 2006). "Lagrange Biography". Archived from the original on 2 May 2006. Retrieved 20 April 2006. In September 1793 a law was passed ordering the arrest of all foreigners born in enemy countries and all their property to be confiscated. Lavoisier intervened on behalf of Lagrange, who certainly fell under the terms of the law. On 8 May 1794, after a trial that lasted less than a day, a revolutionary tribunal condemned Lavoisier and 27 others to death. Lagrange said on the death of Lavoisier, who was guillotined on the afternoon of the day of his trial 
  13. ^ Today in History: 1794: Antoine Lavoisier, the father of modern chemistry, is executed on the guillotine during France’s Reign of Terror
  14. ^ Commenting on this quotation, Denis Duveen, an English expert on Lavoiser and a collector of his works, wrote that "it is pretty certain that it was never uttered". For Duveen's evidence, see the following: Duveen, Denis I. (February 1954). "Antoine Laurent Lavoisier and the French Revolution". Journal of Chemical Education. 31 (2): 60–65. Bibcode:1954JChEd..31...60D. doi:10.1021/ed031p60. .
  15. ^ Delambre, Jean-Baptiste (1867) (in French). Wikisource link to Œuvres de Lagrange. Gauthier-Villars. Wikisource. 15–57. 
  16. ^ Guerlac, Henry (1973). Antoine-Laurent Lavoisier – Chemist and Revolutionary. New York: Charles Scribner's Sons. p. 130. 
  17. ^ (In French) M.-A. Paulze, épouse et collaboratrice de Lavoisier, Vesalius, VI, 2,105-113, 2000, p. 110.
  18. ^ a b in French and Memoir on Combustion in General (English translation)
  19. ^ Petrucci R.H., Harwood W.S. and Herring F.G., General Chemistry (8th ed. Prentice-Hall 2002), p.34
  20. ^ Duveen, Denis; Klickstein, Herbert (Sep 1954). "The Introduction of Lavoisier's Chemical Nomenclature into America". The History of Science Society. 45 (3). 
  21. ^ a b c d Jan Golinski, “Precision instruments and the demonstrative order of proof in Lavoisier’s chemistry,” Osiris, 2nd Series (1994): 30-47.
  22. ^ Kirwan, Essay on Phlogiston, viii, xi.
  23. ^ in French
  24. ^ Lavoisier and Meusnier, "Développement" (cit. n. 27), pp. 205209; cf. Holmes, Lavoisier (cn. 8), p. 237.
  25. ^ See the "Advertisement," p. vi of Kerr's translation, and pp. xxvi–xxvii, xxviii of Douglas McKie's introduction to the Dover edition.
  26. ^ Is a Calorie a Calorie? American Journal of Clinical Nutrition, Vol. 79, No. 5, 899S–906S, May 2004
  27. ^ Levere, Trevor (2001). Transforming Matter. Maryland: The Johns Hopkins University Press. pp. 72–73. ISBN 0-8018-6610-3. 
  28. ^ Charles C. Gillespie, Foreword to Lavoisier by Jean-Pierre Poirier, University of Pennsylvania Press, English Edition, 1996.
  29. ^ "Antoine-Laurent Lavoisier: The Chemical Revolution". National Historic Chemical Landmarks. American Chemical Society. Retrieved 25 March 2013. 
  30. ^ Guyton de Morveau, Louis Bernard; Lavoisier, Antoine Laurent; Berthollet, Claude-Louis; Fourcroy, Antoine-François de (1787). Méthode de Nomenclature Chimique. Paris, France: Chez Cuchet (Sous le Privilége de l’Académie des Sciences). 
  31. ^ "2015 Awardees". American Chemical Society, Division of the History of Chemistry. University of Illinois at Urbana-Champaign School of Chemical Sciences. 2015. Retrieved 1 July 2016. 
  32. ^ "Citation for Chemical Breakthrough Award" (PDF). American Chemical Society, Division of the History of Chemistry. University of Illinois at Urbana-Champaign School of Chemical Sciences. 2015. Retrieved 1 July 2016. 
  33. ^ See Denis I. Duveen and Herbert S. Klickstein, "The "American" Edition of Lavoisier's L'art de fabriquer le salin et la potasse," The William and Mary Quarterly, Third Series 13:4 (October 1956), 493–498.

Further reading[edit]

  • Berthelot, M. (1890). La révolution chimique: Lavoisier. Paris: Alcan. 
  • Catalogue of Printed Works by and Memorabilia of Antoine Laurent Lavoisier, 1743–1794... Exhibited at the Grolier Club (New York, 1952).
  • Daumas, M. (1955). Lavoisier, théoricien et expérimentateur. Paris: Presses Universitaires de France. 
  • Donovan, Arthur (1993). Antoine Lavoisier: Science, Administration, and Revolution. Cambridge, England: Cambridge University Press. 
  • Duveen, D. I. and H. S. Klickstein, A Bibliography of the Works of Antoine Laurent Lavoisier, 1743–1794 (London, 1954)
  • Grey, Vivian (1982). The Chemist Who Lost His Head: The Story of Antoine Lavoisier. Coward, McCann & Geoghegan, Inc. 
  • Gribbin, John (2003). Science: A History 1543–2001,. Gardners Books. ISBN 0-14-029741-3. 
  • Guerlac, Henry (1961). Lavoisier – The Crucial Year. Ithaca, New York: Cornell University Press. 
  • Holmes, Frederic Lawrence (1985). Lavoisier and the Chemistry of Life. Madison, Wisconsin: University of Wisconsin Press. 
  • Holmes, Frederic Lawrence (1998). Antoine Lavoisier – The Next Crucial Year, or the Sources of his Quantitative Method in Chemistry. Princeton University Press. 
  • Jackson, Joe (2005). A World on Fire: A Heretic, An Aristocrat And The Race to Discover Oxygen. Viking. 
  • Johnson, Horton A. (2008). "Revolutionary Instruments, Lavoisier's Tools as Objets d'Art". Chemical Heritage. 26 (1): 30–35. 
  • Kelly, Jack (2004). Gunpowder: Alchemy, Bombards, & Pyrotechnics. Basic Books. ISBN 0-465-03718-6. 
  • McKie, Douglas (1935). Antoine Lavoisier: The Father of Modern Chemistry. Philadelphia: J. P. Lippincott Company. 
  • McKie, Douglas (1952). Antoine Lavoisier: Scientist, Economist, Social Reformer. New York: Henry Schuman. 
  • Poirier, Jean-Pierre (1996). Lavoisier (English ed.). University of Pennsylvania Press. 
  • Scerri, Eric (2007). The Periodic Table: Its Story and Its Significance. Oxford University Press. 
  • Smartt Bell, Madison (2005). Lavoisier in the Year One: The Birth of a New Science in an Age of Revolution. Atlas Books, W. W. Norton. 

External links[edit]

About his work[edit]

His writings[edit]