Arsenide

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Arsenide
Identifiers
3D model (JSmol)
ChemSpider
Properties
As3−
Molar mass 74.92 g·mol−1
Related compounds
Other anions
Phosphide
Antimonide
Bismuthide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many stoichiometries, and in this respect arsenides are similar to phosphides.[1]

Alkali metal and alkaline earth arsenides[edit]

The group 1 alkali metals and the group 2, alkaline earth metals, form arsenides with isolated arsenic atoms. They form upon heating arsenic powder with excess sodium gives sodium arsenide (Na3As). The structure of Na3As is complex with unusually short Na–Na distances of 328–330 pm which are shorter than in sodium metal. This short distance indicates the complex bonding in these simple phases, i.e. they are not simply salts of As3− anion, for example.[1] The compound LiAs, has a metallic lustre and electrical conductivity indicating some metallic bonding.[1] These compounds are mainly of academic interest. For example, "sodium arsenide" is a structural motif adopted by many compounds with the A3B stoichiometry.

Indicative of their salt-like properties, hydrolysis of alkali metal arsenides gives arsine:

Na3As + 3 H2O → AsH3 + 3 NaOH
Nickel arsenide is a common impurity in ores of nickel. It is also a prototype of a class of structures.

III–V Compounds[edit]

Many arsenides of the group 13 elements (group III) are valuable semiconductors. Gallium arsenide (GaAs) features isolated arsenic centers with a zincblende structure (wurtzite structure can eventually also form in nanostructures), and with predominantly covalent bonding – it is a III–V semiconductor.

Polyarsenides[edit]

Transition metal arsenides[edit]

Arsenic anionics are known to catenate, that is, form chains, rings, and cages. The mineral skutterudite (CoAs3) features rings that are usually described as As4−
4
.[1] Assigning formal oxidation numbers is difficult because these materials are highly covalent and often are best described with band theory. Sperrylite (PtAs2) is usually described as Pt4+
As4−
2
. The arsenides of the transition metals are mainly of interest because they contaminate sulfidic ores of commercial interest. The extraction of the metals – nickel, iron, cobalt, copper – entails chemical processes such as smelting that poses environmental risks. In the mineral, arsenic is immobile and poses no environmental risk. Released from the mineral, arsenic is poisonous and mobile.

Zintl phases[edit]

Structure of [As7]3− subunit in the Zintl phase Cs2NaAs7.[2]

Partial reduction of arsenic with alkali metals (and related electropositive elements) affords polyarsenic compounds, which are members of the Zintl phases.

See also[edit]

References[edit]

  1. ^ a b c d Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9. 
  2. ^ He, Hua; Tyson, C.-T.; Bobev, S. (2011). "New compounds with (As7)3− Clusters: Synthesis and Crystal Structures of the Zintl Phases Cs2NaAs7, Cs4ZnAs14 and Cs4CdAs14". Crystals: 87–p98. doi:10.3390/cryst1030087. 

External links[edit]