A boilover (or boil-over) type of fire refers to an extremely hazardous situation where an attempt is made to extinguish semi-enclosed oil or petrochemical fueled fire with water. The hazard results due to the difference in density between oil and water.
NFPA defines boil-over as: An event in the burning of certain oils in an open-top tank when, after a long period of quiescent burning, there is a sudden increase in fire intensity associated with expulsion of burning oil from the tank.
Boilover is also common in the home as a chip pan fire when cooking.
As water is poured onto the fuel, it quickly sinks to the bottom of the container due to the water's higher density, and has little effect on extinguishing the flames on the surface. Under certain conditions, after some time, the water on the bottom rapidly vaporises into steam, causing it to expand more than 1700 times in volume. The rapidly expanding steam (possibly superheated) expels the oil or fuel above upward and out of the tank, resulting in the discharging of burning oil onto a large and uncontrolled area outside of the container. Mathematical modelling of the phenomenon is difficult and complicated, making boilover prediction unreliable.
- Expansion ratio
- Fire Extinguisher Foams
- Phreatic eruption - a similar concept in volcanic eruption
- Wax fire
- National Fire Protection Association: "NFPA 30 - Flammable and Combustible Liquids Code"
- GARO, Jean-Pierre; Hiroshi KOSEKI; Jean-Pierre VANTELON (2007). "COMBUSTION OF LIQUID FUELS FLOATING ON WATER" (PDF). Thermal Science:. 11 (2): 119–140. doi:10.2298/TSCI0702119G. Retrieved 2008-11-09.
- Hristov, Jordan (2006). "An inverse Stefan problem relevant to boilover: Heat Balance Integral Solutions and Analysis" (PDF). Thermal Science. 11 (2): 141–160. doi:10.2298/TSCI0702141H. Archived from the original (PDF) on 2011-07-23.
- Media related to Chip-pan fires at Wikimedia Commons