Isotopes of caesium
|Standard atomic weight Ar, standard(Cs)||132.90545196(6)|
Caesium (55Cs) has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. The atomic masses of these isotopes range from 112 to 151. Only one isotope, 133Cs, is stable. The longest-lived radioisotopes are 135Cs with a half-life of 2.3 million years, 137Cs with a half-life of 30.1671 years and 134Cs with a half-life of 2.0652 years. All other isotopes have half-lives less than 2 weeks, most under an hour.
Beginning in 1945 with the commencement of nuclear testing, caesium radioisotopes were released into the atmosphere where caesium is absorbed readily into solution and is returned to the surface of the earth as a component of radioactive fallout. Once caesium enters the ground water, it is deposited on soil surfaces and removed from the landscape primarily by particle transport. As a result, the input function of these isotopes can be estimated as a function of time.
List of isotopes
|Z||N||Isotopic mass (Da)
[n 2][n 3]
[n 5][n 6]
[n 7][n 8]
|Natural abundance (mole fraction)|
|Excitation energy[n 8]||Normal proportion||Range of variation|
|113Cs||55||58||112.94449(11)||16.7(7) μs||p (99.97%)||112Xe||5/2+#|
|114Cs||55||59||113.94145(33)#||0.57(2) s||β+ (91.09%)||114Xe||(1+)|
|β+, p (8.69%)||113I|
|β+, α (.19%)||110Te|
|115Cs||55||60||114.93591(32)#||1.4(8) s||β+ (99.93%)||115Xe||9/2+#|
|β+, p (.07%)||114I|
|116Cs||55||61||115.93337(11)#||0.70(4) s||β+ (99.67%)||116Xe||(1+)|
|β+, p (.279%)||115I|
|β+, α (.049%)||112Te|
|116mCs||100(60)# keV||3.85(13) s||β+ (99.48%)||116Xe||4+, 5, 6|
|β+, p (.51%)||115I|
|β+, α (.008%)||112Te|
|117mCs||150(80)# keV||6.5(4) s||β+||117Xe||3/2+#|
|118Cs||55||63||117.926559(14)||14(2) s||β+ (99.95%)||118Xe||2|
|β+, p (.042%)||117I|
|β+, α (.0024%)||114Te|
|118mCs||100(60)# keV||17(3) s||β+ (99.95%)||118Xe||(7−)|
|β+, p (.042%)||117I|
|β+, α (.0024%)||114Te|
|β+, α (2×10−6%)||115Te|
|119mCs||50(30)# keV||30.4(1) s||β+||119Xe||3/2(+)|
|β+, α (2×10−5%)||116Te|
|β+, p (7×10−6%)||119I|
|120mCs||100(60)# keV||57(6) s||β+||120Xe||(7−)|
|β+, α (2×10−5%)||116Te|
|β+, p (7×10−6%)||119I|
|121mCs||68.5(3) keV||122(3) s||β+ (83%)||121Xe||9/2(+)|
|β+, α (2×10−7%)||118Te|
|122m1Cs||45.8 keV||>1 μs||(3)+|
|122m2Cs||140(30) keV||3.70(11) min||β+||122Xe||8−|
|122m3Cs||127.0(5) keV||360(20) ms||(5)−|
|123m1Cs||156.27(5) keV||1.64(12) s||IT||123Cs||(11/2)−|
|123m2Cs||231.63+X keV||114(5) ns||(9/2+)|
|124mCs||462.55(17) keV||6.3(2) s||IT||124Cs||(7)+|
|125mCs||266.6(11) keV||900(30) ms||(11/2−)|
|126m1Cs||273.0(7) keV||>1 μs|
|126m2Cs||596.1(11) keV||171(14) μs|
|127mCs||452.23(21) keV||55(3) μs||(11/2)−|
|130Cs||55||75||129.906709(9)||29.21(4) min||β+ (98.4%)||130Xe||1+|
|130mCs||163.25(11) keV||3.46(6) min||IT (99.83%)||130Cs||5−|
|132Cs||55||77||131.9064343(20)||6.480(6) d||β+ (98.13%)||132Xe||2+|
|133Cs[n 9][n 10]||55||78||132.905451933(24)||Stable[n 11]||7/2+||1.0000|
|134Cs[n 10]||55||79||133.906718475(28)||2.0652(4) y||β−||134Ba||4+|
|134mCs||138.7441(26) keV||2.912(2) h||IT||134Cs||8−|
|135Cs[n 10]||55||80||134.9059770(11)||2.3 x106 y||β−||135Ba||7/2+|
|135mCs||1632.9(15) keV||53(2) min||IT||135Cs||19/2−|
|136mCs||518(5) keV||19(2) s||β−||136Ba||8−|
|137Cs[n 10]||55||82||136.9070895(5)||30.1671(13) y||β− (95%)||137mBa||7/2+|
|138mCs||79.9(3) keV||2.91(8) min||IT (81%)||138Cs||6−|
|141Cs||55||86||140.920046(11)||24.84(16) s||β− (99.96%)||141Ba||7/2+|
|β−, n (.0349%)||140Ba|
|142Cs||55||87||141.924299(11)||1.689(11) s||β− (99.9%)||142Ba||0−|
|β−, n (.091%)||141Ba|
|143Cs||55||88||142.927352(25)||1.791(7) s||β− (98.38%)||143Ba||3/2+|
|β−, n (1.62%)||142Ba|
|144Cs||55||89||143.932077(28)||994(4) ms||β− (96.8%)||144Ba||1(−#)|
|β−, n (3.2%)||143Ba|
|144mCs||300(200)# keV||<1 s||β−||144Ba||(>3)|
|145Cs||55||90||144.935526(12)||582(6) ms||β− (85.7%)||145Ba||3/2+|
|β−, n (14.3%)||144Ba|
|146Cs||55||91||145.94029(8)||0.321(2) s||β− (85.8%)||146Ba||1−|
|β−, n (14.2%)||145Ba|
|147Cs||55||92||146.94416(6)||0.235(3) s||β− (71.5%)||147Ba||(3/2+)|
|β−, n (28.49%)||146Ba|
|148Cs||55||93||147.94922(62)||146(6) ms||β− (74.9%)||148Ba|
|β−, n (25.1%)||147Ba|
|149Cs||55||94||148.95293(21)#||150# ms [>50 ms]||β−||149Ba||3/2+#|
|150Cs||55||95||149.95817(32)#||100# ms [>50 ms]||β−||150Ba|
|151Cs||55||96||150.96219(54)#||60# ms [>50 ms]||β−||151Ba||3/2+#|
|This table header & footer:|
- mCs – Excited nuclear isomer.
- ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
Modes of decay:
EC: Electron capture IT: Isomeric transition n: Neutron emission p: Proton emission
- Bold italics symbol as daughter – Daughter product is nearly stable.
- Bold symbol as daughter – Daughter product is stable.
- ( ) spin value – Indicates spin with weak assignment arguments.
- # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- Used to define the second
- Fission product
- Theoretically capable of spontaneous fission
The second, symbol s, is defined by taking the fixed numerical value of the caesium frequency ΔνCs, the unperturbed ground-state hyperfine transition frequency of the caesium-133 atom, to be 9192631770 when expressed in the unit Hz, which is equal to s−1.
Caesium-134 has a half-life of 2.0652 years. It is produced both directly (at a very small yield because 134Xe is stable) as a fission product and via neutron capture from nonradioactive 133Cs (neutron capture cross section 29 barns), which is a common fission product. Caesium-134 is not produced via beta decay of other fission product nuclides of mass 134 since beta decay stops at stable 134Xe. It is also not produced by nuclear weapons because 133Cs is created by beta decay of original fission products only long after the nuclear explosion is over.
The combined yield of 133Cs and 134Cs is given as 6.7896%. The proportion between the two will change with continued neutron irradiation. 134Cs also captures neutrons with a cross section of 140 barns, becoming long-lived radioactive 135Cs.
Caesium-135 is a mildly radioactive isotope of caesium with a half-life of 2.3 million years. It decays via emission of a low-energy beta particle into the stable isotope barium-135. Caesium-135 is one of the 7 long-lived fission products and the only alkaline one. In nuclear reprocessing, it stays with 137Cs and other medium-lived fission products rather than with other long-lived fission products. The low decay energy, lack of gamma radiation, and long half-life of 135Cs make this isotope much less hazardous than 137Cs or 134Cs.
Its precursor 135Xe has a high fission product yield (e.g. 6.3333% for 235U and thermal neutrons) but also has the highest known thermal neutron capture cross section of any nuclide. Because of this, much of the 135Xe produced in current thermal reactors (as much as >90% at steady-state full power) will be converted to stable 136Xe before it can decay to 135Cs. Little or no 135Xe will be destroyed by neutron capture after a reactor shutdown, or in a molten salt reactor that continuously removes xenon from its fuel, a fast neutron reactor, or a nuclear weapon.
A nuclear reactor will also produce much smaller amounts of 135Cs from the nonradioactive fission product 133Cs by successive neutron capture to 134Cs and then 135Cs.
The thermal neutron capture cross section and resonance integral of 135Cs are 8.3 ± 0.3 and 38.1 ± 2.6 barns respectively. Disposal of 135Cs by nuclear transmutation is difficult, because of the low cross section as well as because neutron irradiation of mixed-isotope fission caesium produces more 135Cs from stable 133Cs. In addition, the intense medium-term radioactivity of 137Cs makes handling of nuclear waste difficult.
Caesium-136 has a half-life of 13.16 days. It is produced both directly (at a very small yield because 136Xe is beta-stable) as a fission product and via neutron capture from long-lived 135Cs (neutron capture cross section 8.702 barns), which is a common fission product. Caesium-136 is not produced via beta decay of other fission product nuclides of mass 136 since beta decay stops at almost-stable 136Xe. It is also not produced by nuclear weapons because 135Cs is created by beta decay of original fission products only long after the nuclear explosion is over. 136Cs also captures neutrons with a cross section of 13.00 barns, becoming medium-lived radioactive 137Cs. Caesium-136 undergoes beta decay (β−), producing 136Ba directly.
Caesium-137, with a half-life of 30.17 years, is one of the two principal medium-lived fission products, along with 90Sr, which are responsible for most of the radioactivity of spent nuclear fuel after several years of cooling, up to several hundred years after use. It constitutes most of the radioactivity still left from the Chernobyl accident and is a major health concern for decontaminating land near the Fukushima nuclear power plant. 137Cs beta decays to barium-137m (a short-lived nuclear isomer) then to nonradioactive barium-137, and is also a strong emitter of gamma radiation.
137Cs has a very low rate of neutron capture and cannot yet be feasibly disposed of in this way unless advances in neutron beam collimation (not otherwise achievable by magnetic fields), uniquely available only from within muon catalyzed fusion experiments (not in the other forms of Accelerator Transmutation of Nuclear Waste) enables production of neutrons at high enough intensity to offset and overcome these low capture rates; until then, therefore, 137Cs must simply be allowed to decay.
Other isotopes of caesium
The other isotopes have half-lives from a few days to fractions of a second. Almost all caesium produced from nuclear fission comes from beta decay of originally more neutron-rich fission products, passing through isotopes of iodine then isotopes of xenon. Because these elements are volatile and can diffuse through nuclear fuel or air, caesium is often created far from the original site of fission.
- "NIST Radionuclide Half-Life Measurements". NIST. Retrieved 2011-03-13.
- "Standard Atomic Weights: Caesium". CIAAW. 2013.
- Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- "Isotopes". Ptable.
- Isoray. "Why Cesium-131".
- Although the phase used here is more terse than in the previous definition, it still has the same meaning. This is made clear in the 9th SI Brochure, which almost immediately after the definition on p. 130 states: "The effect of this definition is that the second is equal to the duration of 9192631770 periods of the radiation corresponding to the transition between the two hyperfine levels of the unperturbed ground state of the 133Cs atom."
- "Characteristics of Caesium-134 and Caesium-137". Japan Atomic Energy Agency.
- John L. Groh (2004). "Supplement to Chapter 11 of Reactor Physics Fundamentals" (PDF). CANTEACH project. Archived from the original (PDF) on 10 June 2011. Retrieved 14 May 2011.
- Hatsukawa, Y.; Shinohara, N; Hata, K.; et al. (1999). "Thermal neutron cross section and resonance integral of the reaction of135Cs(n,γ)136Cs: Fundamental data for the transmutation of nuclear waste". Journal of Radioanalytical and Nuclear Chemistry. 239 (3): 455–458. doi:10.1007/BF02349050. S2CID 97425651.
- Ohki, Shigeo; Takaki, Naoyuki (2002). "Transmutation of Cesium-135 With Fast Reactors" (PDF). Proceedings of the Seventh Information Exchange Meeting on Actinide and Fission Product Partitioning & Transmutation, Cheju, Korea.
- Dennis (1 March 2013). "Cooling a Hot Zone". Science. 339 (6123): 1028–1029. doi:10.1126/science.339.6123.1028. PMID 23449572.
- Isotope masses from:
- Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051. Lay summary.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.