Caesium cadmium bromide

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Caesium cadmium bromide
CsCdBr3
Names
IUPAC name
Caesium cadmium bromide
Other names
  • Caesium tribromocadmate
Identifiers
Properties
CsCdBr3
Molar mass 485.028 g/mol
Appearance white or colourless solid
Density 4.53 g/cm3[1]
Melting point 450 °C (842 °F; 723 K)
Structure
cubic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Caesium cadmium bromide (CsCdBr3) is a synthetic crystalline material. It belongs to the AMX3 group (where A = alkali metal, M = bivalent metal, X = halogen ion). Unlike most other bromides, CsCdBr3 is non-hygroscopic,[2] giving it applications as an efficient upconversion material in solar cells.[3] As a single crystal structure doped with rare-earth ions, it can be also used as active laser medium. It is highly transparent in the visible and infrared regions and can be used as a nonlinear optical crystal.[4]

Caesium cadmium bromide with the formula Cs2CdBr4 has also been synthesized.[5]

References[edit]

  1. ^ Persson, Kristin (2014). "36 Materials Science". Materials Data on CsCdBr3 (SG:221) by Materials Project (Data Set). LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). doi:10.17188/1275593.
  2. ^ Barthem, R. B.; Buisson, R.; Vial, JC.; Chaminade, JP. (1985). "ENERGY TRANSFER IN CsCdBr3 : Nd3+SYSTEM" (PDF). Le Journal de Physique Colloques. 46: C7–113–C7–117. doi:10.1051/jphyscol:1985722.
  3. ^ Cockroft, Nigel J.; Jones, Glynn D.; Nguyen, Dinh C. (1992). "Dynamics and spectroscopy of infrared-to-visible upconversion in erbium-doped cesium cadmium bromide (CsCdBr3:Er3+)". Physical Review B. 45 (10): 5187–5198. doi:10.1103/PhysRevB.45.5187.
  4. ^ Ren, Peng; Qin, Jingui; Chen, Chuangtian (2003). "A Novel Nonlinear Optical Crystal for the IR Region:  Noncentrosymmetrically Crystalline CsCdBr3and its Properties". Inorganic Chemistry. 42 (1): 8–10. doi:10.1021/ic025813y. PMID 12513072.
  5. ^ Altermatt, D.; Arend, H.; Gramlich, V.; Niggli, A.; Petter, W. (1984). "Low-temperature phases in Cs2CdBr4and Cs2HgBr4". Acta Crystallographica Section B. 40 (4): 347–350. doi:10.1107/S0108768184002275.