It is commonly believed that the Crusaders brought Aleppo soap back to Europe in the 11th century, based on the claim that the earliest soap made in Europe was just after the Crusades, but in fact, the Greeks knew about soap in the first century AD and Zosimos of Panopolis described soap and soapmaking in c. 300 AD. Following the Crusades, production of this soap extended to the whole Mediterranean area.
Early soap-makers in the Mediterranean area did not have easy access to laurel oil and therefore dropped it from their formulations, thereby creating an olive-oil soap now known as Castile soap. Castile soap is so called because it was produced on a large scale in the territories of the Crown of Castile, from where it was exported to numerous places in Europe, mainly during the Modern Age. Although the Crown of Castile was not the only producer of this type of soap, it was its producer par excellence.
In the 17th century, the soap caused controversy in England, since it supplanted the unnamed local soap after the Spanish Catholic manufacturers purchased the monopoly on the soap from the cash-strapped Carolinian government. Its ties to Catholicism caused a public-relations campaign to be established, featuring washerwomen showing how much more effective local soaps were than Castile soap. The sale of a monopoly in Protestant England to a Catholic company caused a great uproar, ending with the Castile soap company eventually being stripped of the monopoly.
Importations of "Castile soap" through Antwerp appear in the London port books of 1567–1568, though the Oxford English Dictionary has no references to "Castile soap" earlier than 1616. In his article "A short history of soap", John Hunt maintains that barilla (an impure form of sodium carbonate obtained from halophyte plant ashes that were high in sodium) was boiled with locally available olive oil, rather than tallow.
Adding brine to the boiled liquor made the soap float to the surface, where the soap-boiler could skim it off, leaving the excess lye and impurities to settle out. While Aleppo soap tends to be green, this produced what was probably the first white hard soap, which hardened further as it aged, without losing its whiteness, forming jabón de Castilla.
Some manufacturers have redefined Castile soap to use little to no olive oil. This undercuts the vendors who sell real olive oil soap.
- Soap (data) from Pharmaceutical-journal.com. Retrieved Oct 2014.
- "Aleppo Soap, The True Natural Soap". Natural Cosmetic News. Archived from the original on 2012-09-02. Retrieved 9 July 2012.
- Partington, J. R. (1960). A history of Greek fire and gunpowder (Johns Hopkins paperbacks ed.). Cambridge: Heffer. ISBN 0-8018-5954-9. Retrieved 25 May 2015.
- Gregg, Pauline (1981). King Charles I. London: Dent. p. 218. ISBN 9780460044370. OCLC 9944510.
- Dietz, Brian (ed.). "The Port and Trade of Early Elizabethan London: documents". London Record Society. Retrieved 25 May 2015.
- Hunt, John A. (December 1999). "A Short History of Soap". The Pharmaceutical Journal. 263 (7076): 985–989. Archived from the original on 2015-07-05. Retrieved 24 June 2021.
- Dolen "A Coconut is not an Olive"
- Hunt, John A. (December 1999). "A Short History of Soap". The Pharmaceutical Journal. 263 (7076): 985–989. Archived from the original on 2015-07-05.
- Garzena, Patrizia & Tadiello, Marina (2004). Soap Naturally: ingredients, methods, and recipes for natural handmade soap; 1st ed. Programmer Publishing. ISBN 0-9756764-0-7.