The Chapman–Jouguet condition holds approximately in detonation waves in high explosives. It states that the detonation propagates at a velocity at which the reacting gases just reach sonic velocity (in the frame of the leading shock wave) as the reaction ceases.
David Chapman and Émile Jouguet originally (c. 1900) stated the condition for an infinitesimally thin detonation. A physical interpretation of the condition is usually based on the later modelling (c. 1943) by Yakov Borisovich Zel'dovich, John von Neumann, and Werner Döring (the so-called ZND detonation model).
In more detail (in the ZND model) in the frame of the leading shock of the detonation wave, gases enter at supersonic velocity and are compressed through the shock to a high-density, subsonic flow. This sudden change in pressure initiates the chemical (or sometimes, as in steam explosions, physical) energy release. The energy release re-accelerates the flow back to the local speed of sound. It can be shown fairly simply, from the one-dimensional gas equations for steady flow, that the reaction must cease at the sonic ("CJ") plane, or there would be discontinuously large pressure gradients at that point.
The sonic plane forms a so-called choke point that enables the lead shock, and reaction zone, to travel at a constant velocity, undisturbed by the expansion of gases in the rarefaction region beyond the CJ plane.
This simple one-dimensional model is quite successful in explaining detonations. However, observations of the structure of real chemical detonations show a complex three-dimensional structure, with parts of the wave traveling faster than average, and others slower. Indeed, such waves are quenched as their structure is destroyed. The Wood–Kirkwood detonation theory can correct for some of these limitations.
The Rayleigh line equation and the Hugoniot curve equation obtained from the Rankine–Hugoniot relations for an ideal gas, with the assumption of constant specific heat and constant molecular weight, respectively are
where is the specific heat ratio and
Here the subscript 1 and 2 identifies flow properties (pressure , density ) upstream and downstream of the wave and is the constant mass flux and is the heat released in the wave. The slopes of Rayleigh line and Hugoniot curve are
At the Chapman-Jouguet point, both slopes are equal, leading the condition that
Substituting this back into the Rayleigh equation, we find
Using the definition of mass flux , where denotes the flow velocity, we find
The upper sign applies for the Upper Chapman-Jouguet point (detonation) and the lower sign applies for the Lower Chapman-Jouguet point (deflagration). Similarly, the upstream Mach number can be found from
and the temperature ratio can be found from the relation .
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