|Molar mass||245.88 g/mol|
|Melting point||295 to 296 °C (563 to 565 °F; 568 to 569 K)|
|S-phrases||S37 S60 S61|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is: / ?)(|
Chloranil is a quinone with the molecular formula C6Cl4O2. Also known as tetrachloro-1,4-benzoquinone, it is a yellow solid. Like the parent benzoquinone, chloranil is a planar molecule that functions as a mild oxidant.
Chloranil is used to test for free secondary amines. This test is useful for checking for the presence of proline derivatives. It is also a good test for the successful deprotection of a secondary amine. Secondary amines react with p-chloranil to give a brown/red/orange derivative, the colour depending on the amine. In these reactions, the amine displaces chloride from the ring of the quinone.
- Chloranilic acid
- Chloranil in the Pesticide Properties DataBase (PPDB)
- Used as starting material to make diaziquone (AZQ), a cancer chemotherapeutic agent.
- Chloranil at Sigma-Aldrich
- J.-M. Lü, S. V. Rosokha, I. S. Neretin and J. K. Kochi, "Quinones as Electron Acceptors. X-Ray Structures, Spectral (EPR, UV-vis) Characteristics and Electron-Transfer Reactivities of Their Reduced Anion Radicals as Separated vs Contact Ion Pairs" Journal of the American Chemical Society 2006 128, 16708-16719.doi:10.1021/ja066471o
- Derek R. Buckle "Chloranil" in Encyclopedia of Reagents for Organic Synthesis 2001, John Wiley. doi:10.1002/047084289X.rc057
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