electrolytically refined cobalt chips
|Name, symbol||cobalt, Co|
|Appearance||hard lustrous bluish gray metal|
|Cobalt in the periodic table|
|Atomic number (Z)||27|
|Group, block||group 9, d-block|
|Element category||transition metal|
|Standard atomic weight (±) (Ar)||58.933194(4)|
|Electron configuration||[Ar] 3d7 4s2|
|2, 8, 15, 2|
|Melting point||1768 K (1495 °C, 2723 °F)|
|Boiling point||3200 K (2927 °C, 5301 °F)|
|Density near r.t.||8.90 g/cm3|
|when liquid, at m.p.||8.86 g/cm3|
|Heat of fusion||16.06 kJ/mol|
|Heat of vaporization||377 kJ/mol|
|Molar heat capacity||24.81 J/(mol·K)|
|Oxidation states||−3, −1, +1, +2, +3, +4, +5 (an amphoteric oxide)|
|Electronegativity||Pauling scale: 1.88|
|Ionization energies||1st: 760.4 kJ/mol
2nd: 1648 kJ/mol
3rd: 3232 kJ/mol
|Atomic radius||empirical: 125 pm|
|Covalent radius||Low spin: 126±3 pm
High spin: 150±7 pm
|Crystal structure||hexagonal close-packed (hcp)|
|Speed of sound thin rod||4720 m/s (at 20 °C)|
|Thermal expansion||13.0 µm/(m·K) (at 25 °C)|
|Thermal conductivity||100 W/(m·K)|
|Electrical resistivity||62.4 nΩ·m (at 20 °C)|
|Young's modulus||209 GPa|
|Shear modulus||75 GPa|
|Bulk modulus||180 GPa|
|Vickers hardness||1043 MPa|
|Brinell hardness||470–3000 MPa|
|Discovery||Georg Brandt (1732)|
|Most stable isotopes of cobalt|
Cobalt is a chemical element with symbol Co and atomic number 27. Like nickel, cobalt is found in the Earth's crust only in chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal.
Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was later thought by alchemists to be due to the known metal bismuth. Miners had long used the name kobold ore (German for goblin ore) for some of the blue-pigment producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes upon smelting. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the kobold.
Today, some cobalt is produced specifically from various metallic-lustered ores, for example cobaltite (CoAsS), but the main source of the element is as a by-product of copper and nickel mining. The copper belt in the Democratic Republic of the Congo, Central African Republic and Zambia yields most of the cobalt mined worldwide.
Cobalt is primarily used in the preparation of magnetic, wear-resistant and high-strength alloys. The compounds, cobalt silicate and cobalt(II) aluminate (CoAl2O4, cobalt blue) give a distinctive deep blue color to glass, ceramics, inks, paints and varnishes. Cobalt occurs naturally as only one stable isotope, cobalt-59. Cobalt-60 is a commercially important radioisotope, used as a radioactive tracer and for the production of high energy gamma rays.
Cobalt is the active center of coenzymes called cobalamins, the most common example of which is vitamin B12. As such, it is an essential trace dietary mineral for all animals. Cobalt in inorganic form is also a micronutrient for bacteria, algae and fungi.
- 1 Characteristics
- 2 Compounds
- 3 Isotopes
- 4 History
- 5 Occurrence
- 6 Production
- 7 Applications
- 8 Biological role
- 9 Precautions
- 10 References
- 11 External links
Cobalt is a ferromagnetic metal with a specific gravity of 8.9. The Curie temperature is 1,115 °C (2,039 °F) and the magnetic moment is 1.6–1.7 Bohr magnetons per atom. Cobalt has a relative permeability two-thirds that of iron. Metallic cobalt occurs as two crystallographic structures: hcp and fcc. The ideal transition temperature between the hcp and fcc structures is 450 °C (842 °F), but in practice, the energy difference is so small that random intergrowth of the two is common.
Cobalt is a weakly reducing metal that is protected from oxidation by a passivating oxide film. It is attacked by halogens and sulfur. Heating in oxygen produces Co3O4 which loses oxygen at 900 °C (1,650 °F) to give the monoxide CoO. The metal reacts with fluorine (F2) at 520 K to give CoF3; with chlorine (Cl2), bromine (Br2) and iodine (I2), producing equivalent binary halides. It does not react with hydrogen gas (H2) or nitrogen gas (N2) even when heated, but it does react with boron, carbon, phosphorus, arsenic and sulfur. At ordinary temperatures, it reacts slowly with mineral acids, and very slowly with moist, but not with dry, air.
Common oxidation states of cobalt include +2 and +3, although compounds with oxidation states ranging from −3 to +5 are also known. A common oxidation state for simple compounds is +2 (cobalt(II)). These salts form the pink-colored metal aquo complex [Co(H2O)6]2+ in water. Addition of chloride gives the intensely blue [CoCl
In a borax bead flame test, cobalt shows deep blue in both oxidizing and reducing flames.
Oxygen and chalcogen compounds
Several oxides of cobalt are known. Green cobalt(II) oxide (CoO) has rocksalt structure. It is readily oxidized with water and oxygen to brown cobalt(III) hydroxide (Co(OH)3). At temperatures of 600–700 °C, CoO oxidizes to the blue cobalt(II,III) oxide (Co3O4), which has a spinel structure. Black cobalt(III) oxide (Co2O3) is also known. Cobalt oxides are antiferromagnetic at low temperature: CoO (Néel temperature 291 K) and Co3O4 (Néel temperature: 40 K), which is analogous to magnetite (Fe3O4), with a mixture of +2 and +3 oxidation states.
Four dihalides of cobalt(II) are known: cobalt(II) fluoride (CoF2, pink), cobalt(II) chloride (CoCl2, blue), cobalt(II) bromide (CoBr2, green), cobalt(II) iodide (CoI2, blue-black). These halides exist in anhydrous and hydrated forms. Whereas the anhydrous dichloride is blue, the hydrate is red.
The reduction potential for the reaction Co3+
+ e− → Co2+
is +1.92 V, beyond that for chlorine to chloride, +1.36 V. Consequently, cobalt(III) and chloride would result in the cobalt(III) being reduced to cobalt(II). Because the reduction potential for fluorine to fluoride is so high, +2.87 V, cobalt(III) fluoride is one of the few simple stable cobalt(III) compounds. Cobalt(III) fluoride, which is used in some fluorination reactions, reacts vigorously with water.
As for all metals, molecular compounds and polyatomic ions of cobalt are classified as coordination complexes, that is, molecules or ions that contain cobalt linked to several ligands. The principles of electronegativity and hardness–softness of a series of ligands can be used to explain the usual oxidation state of cobalt. For example, Co+3 complexes tend to have ammine ligands. Because phosphorus is softer than nitrogen, phosphine ligands tend to feature the softer Co2+ and Co+, an example being tris(triphenylphosphine)cobalt(I) chloride ((P(C6H5)3)3CoCl). The more electronegative (and harder) oxide and fluoride can stabilize Co4+ and Co5+ derivatives, e.g. caesium hexafluorocobaltate (Cs2CoF6) and potassium percobaltate (K3CoO4).
Alfred Werner, a Nobel-prize winning pioneer in coordination chemistry, worked with compounds of empirical formula [Co(NH3)6]Cl3. One of the isomers determined was cobalt(III) hexammine chloride. This coordination complex, a typical Werner-type complex, consists of a central cobalt atom coordinated by six ammine orthogonal ligands and three chloride counteranions. Using chelating ethylenediamine ligands in place of ammonia gives tris(ethylenediamine)cobalt(III) chloride ([Co(en)3]Cl3), which was one of the first coordination complexes to be resolved into optical isomers. The complex exists in the right- and left-handed forms of a "three-bladed propeller". This complex was first isolated by Werner as yellow-gold needle-like crystals.
Cobaltocene is a structural analog to ferrocene with cobalt in place of iron. Cobaltocene is much more sensitive to oxidation than ferrocene. Cobalt carbonyl (Co2(CO)8) is a catalyst in carbonylation and hydrosilylation reactions. Vitamin B12 (see below) is an organometallic compound found in nature and is the only vitamin that contains a metal atom.
59Co is the only stable cobalt isotope and the only isotope to exist naturally on Earth. There are 22 radioisotopes that have been characterized, the most stable being 60Co with a half-life of 5.2714 years, 57Co with a half-life of 271.8 days, 56Co with a half-life of 77.27 days, and 58Co with a half-life of 70.86 days. All of the remaining radioactive isotopes have half-lives that are shorter than 18 hours, and the majority of these are shorter than 1 second. This element also has 4 meta states, all of which have half-lives shorter than 15 minutes.
The isotopes of cobalt range in atomic weight from 50 u (50Co) to 73 u (73Co). The primary decay mode for isotopes with atomic mass unit values less than that of the most abundant stable isotope, 59Co, is electron capture and the primary mode of decay for those of greater than 59 atomic mass units is beta decay. The primary decay products before 59Co are element 26 (iron) isotopes and the primary products after are element 28 (nickel) isotopes.
Cobalt compounds have been used for centuries to impart a rich blue color to glass, glazes, and ceramics. Cobalt has been detected in Egyptian sculpture and Persian jewelry from the third millennium BC, in the ruins of Pompeii (destroyed in 79 AD), and in China dating from the Tang dynasty (618–907 AD) and the Ming dynasty (1368–1644 AD).
Cobalt has been used to color glass since the Bronze Age. The excavation of the Uluburun shipwreck yielded an ingot of blue glass, cast during the 14th century BC. Blue glass items from Egypt are colored with copper, iron, or cobalt. The oldest cobalt-colored glass is from the Eighteenth dynasty in Egypt (1550–1292 BC). The source of that cobalt is unknown.
The word cobalt is derived from the German kobalt, from kobold meaning "goblin", a superstitious term used for the ore of cobalt by miners. The first attempts to smelt those ores for copper or nickel failed, yielding simply powder (cobalt(II) oxide) instead. Because the primary ores of cobalt always contain arsenic, smelting the ore oxidized the arsenic into the highly toxic and volatile arsenic oxide, adding to the notoriety of the ore.
Swedish chemist Georg Brandt (1694–1768) is credited with discovering cobalt circa 1735, showing it to be a previously unknown element, different from bismuth and other traditional metals. Brandt called it a new "semi-metal." He showed that compounds of cobalt metal were the source of the blue color in glass, which previously had been attributed to the bismuth found with cobalt. Cobalt became the first metal to be discovered since the pre-historical period, during which all the known metals (iron, copper, silver, gold, zinc, mercury, tin, lead and bismuth) had no recorded discoverers.
During the 19th century, a significant part of the world's production of cobalt blue (a dye made with cobalt compounds and alumina) and smalt (cobalt glass powdered for use for pigment purposes in ceramics and painting) was carried out at the Norwegian Blaafarveværket. The first mines for the production of smalt in the 16th century were located in Norway, Sweden, Saxony and Hungary. With the discovery of cobalt ore in New Caledonia in 1864, the mining of cobalt in Europe declined. With the discovery of ore deposits in Ontario, Canada in 1904 and the discovery of even larger deposits in the Katanga Province in the Congo in 1914, the mining operations shifted again. When the Shaba conflict started in 1978, the copper mines of Katanga Province nearly stopped production. The impact on the world cobalt economy from this conflict was smaller than expected: cobalt is a rare metal, the pigment is highly toxic, and the industry had already established effective ways for recycling cobalt materials. In some cases, industry was able to change to cobalt-free alternatives.
In 1938, John Livingood and Glenn T. Seaborg discovered the radioisotope cobalt-60. This isotope was famously used at Columbia University in the 1950s to establish parity violation in radioactive beta decay.
After World War II, the US wanted to guaranteed the supply of cobalt ore for military uses (as the Germans had been doing) and prospected for cobalt within the U.S. border. An adequate supply of the ore was found in Idaho near Blackbird canyon in the side of a mountain. The firm Calera Mining Company started production at the site.
Free cobalt (the native metal) is not found on Earth because of oxygen in the atmosphere and chlorine in the ocean. Oxygen and chlorine are abundant enough in the upper layers of the Earth's crust to prevent the formation of native metal cobalt. Except as recently delivered in meteoric iron, pure cobalt in native metal form is unknown on Earth (see below). Though the element is of medium abundance, natural compounds of cobalt are numerous. Small amounts of cobalt compounds are found in most rocks, soil, plants, and animals.
In nature, cobalt is frequently associated with nickel, and both are characteristic components of meteoric iron, though cobalt is much less abundant in iron meteorites than nickel. As with nickel, cobalt in meteoric iron alloys may have been well enough protected from oxygen and moisture to remain as the free (but alloyed) metal, though neither element is seen in that form in the ancient terrestrial crust.
Cobalt in compound form occurs as a minor component of copper and nickel minerals. It is the major metallic component in combination with sulfur and arsenic in the sulfidic cobaltite (CoAsS), safflorite (CoAs2), glaucodot ((Co,Fe)AsS), and skutterudite (CoAs3) minerals. The mineral cattierite is similar to pyrite and occurs together with vaesite in the copper deposits of the Katanga Province. Upon contact with the atmosphere, weathering occurs and the sulfide minerals oxidize to form pink erythrite ("cobalt glance": Co3(AsO4)2·8H2O) and spherocobaltite (CoCO3).
The main ores of cobalt are cobaltite, erythrite, glaucodot and skutterudite (see above), but most cobalt is obtained by reducing the cobalt by-products of nickel and copper mining and smelting.
In 2005, the copper deposits in the Katanga Province (former Shaba province) of the Democratic Republic of the Congo were the top producer of cobalt with almost 40% world share, reports the British Geological Survey. By 2015, DRC supplied 60% of the world production of 32,000 tons at prices of $20,000 to $26,000 per ton, including artisanal mining which supplied 10 to 25%. The political situation in the Congo influences the price of cobalt significantly.
The Mukondo Mountain project, operated by the Central African Mining and Exploration Company in Katanga, may be the richest cobalt reserve in the world. It is estimated able to produce about one third of total global production of cobalt in 2008. In July 2009 CAMEC announced a long term agreement under which CAMEC would deliver its entire annual production of cobalt in concentrate from Mukondo Mountain to Zhejiang Galico Cobalt & Nickel Materials of China.
Several methods exist for the separation of cobalt from copper and nickel. They depend on the concentration of cobalt and the exact composition of the used ore. One separation step involves froth flotation, in which surfactants bind to different ore components, leading to an enrichment of cobalt ores. Subsequent roasting converts the ores to the cobalt sulfate, whereas the copper and the iron are oxidized to the oxide. Leaching with water extracts the sulfate together with the arsenates. The residues are further leached with sulfuric acid, yielding a solution of copper sulfate. Cobalt can also be leached from the slag of copper smelting.
The products of the above-mentioned processes are transformed into the cobalt oxide (Co3O4). This oxide is reduced to the metal by the aluminothermic reaction or reduction with carbon in a blast furnace.
Cobalt-based superalloys consume most of the produced cobalt. The temperature stability of these alloys makes them suitable for turbine blades for gas turbines and jet aircraft engines, though nickel-based single crystal alloys surpass them in performance. Cobalt-based alloys are also corrosion and wear-resistant, making them (along with titanium) useful in medical orthopedic implants that do not wear down over time. The development of wear-resistant cobalt alloys started in the first decade of the 20th century with the stellite alloys, containing chromium with varying quantities of tungsten and carbon. Alloys with chromium and tungsten carbides are very hard and wear resistant. Special cobalt-chromium-molybdenum alloys like Vitallium are used for prosthetic parts (hip and knee replacements). Cobalt alloys are also used for dental prosthetics as a useful substitute for nickel, which may be allergenic. Some high speed steels also contain cobalt for increased heat and wear-resistance. The special alloys of aluminium, nickel, cobalt and iron, known as Alnico, and of samarium and cobalt (samarium-cobalt magnet) are used in permanent magnets. It is also alloyed with 95% platinum for jewelry, yielding an alloy suitable for fine casting and is also slightly magnetic.
Lithium cobalt oxide (LiCoO2) is widely used in lithium ion battery cathodes. The material is composed of cobalt oxide layers in which the lithium is intercalated. During discharge, the lithium released as lithium ion. Nickel-cadmium (NiCd) and nickel metal hydride (NiMH) batteries also include cobalt to improve the oxidation of nickel in the battery.
Several cobalt compounds are used in chemical reactions as oxidation catalysts. Cobalt acetate is used for the conversion of xylene to terephthalic acid, the precursor to the bulk polymer polyethylene terephthalate. Typical catalysts are the cobalt carboxylates (known as cobalt soaps). They are also used in paints, varnishes, and inks as "drying agents" through the oxidation of drying oils. The same carboxylates are used to improve the adhesion between steel and rubber in steel-belted radial tires.
Cobalt-based catalysts are used in reactions involving carbon monoxide. Steam reforming, useful in hydrogen production, uses cobalt oxide-base catalysts. Cobalt is also a catalyst in the Fischer–Tropsch process for the hydrogenation of carbon monoxide into liquid fuels. Hydroformylation of alkenes often uses cobalt octacarbonyl as a catalyst, although it is often replaced by more efficient iridium- and rhodium-based catalysts, e.g. the Cativa process.
The hydrodesulfurization of petroleum uses a catalyst derived from cobalt and molybdenum. This process helps to clean petroleum of sulfur impurities that interfere with the refining of liquid fuels.
Pigments and coloring
Before the 19th century, cobalt was predominantly used as a pigment. Since the Middle Ages, it has been used in the production of smalt, a blue colored glass. Smalt is produced by melting a mixture of the roasted mineral smaltite, quartz and potassium carbonate, yielding a dark blue silicate glass which is finely ground after the production. Smalt was widely used for the coloration of glass and as pigment for paintings. In 1780, Sven Rinman discovered cobalt green, and in 1802 Louis Jacques Thénard discovered cobalt blue. Cobalt pigments such as cobalt blue (cobalt aluminate), cerulean blue (cobalt(II) stannate), various hues of cobalt green (a mixture of cobalt(II) oxide and zinc oxide), and cobalt violet (cobalt phosphate) are used as artist's pigments because of their superior chromatic stability. Aureolin (cobalt yellow) is now largely replaced by more lightfast yellow pigments.
Cobalt-60 (Co-60 or 60Co) is useful as a gamma ray source because it can be produced in predictable quantity and high activity by bombarding cobalt with neutrons. It produces two gamma rays with energies of 1.17 and 1.33 MeV.
It is used in external beam radiotherapy, sterilization of medical supplies and medical waste, radiation treatment of foods for sterilization (cold pasteurization), industrial radiography (e.g. weld integrity radiographs), density measurements (e.g. concrete density measurements), and tank fill height switches. The metal has the unfortunate property of producing a fine dust, causing problems with radiation protection. Cobalt from radiotherapy machines has been a serious hazard when not discarded properly, and one of the worst radiation contamination accidents in North America occurred in 1984, when a discarded radiotherapy unit containing cobalt-60 was mistakenly disassembled in a junkyard in Juarez, Mexico.
Cobalt-60 has a radioactive half-life of 5.27 years. The loss of potency requires periodic replacement of the source in radiotherapy and is one reason why cobalt machines have been largely replaced by linear accelerators in modern radiation therapy.
Cobalt-57 (Co-57 or 57Co) is a cobalt radioisotope most often used in medical tests, as a radiolabel for vitamin B12 uptake, and for the Schilling test. Cobalt-57 is used as a source in Mössbauer spectroscopy and is one of several possible sources in X-ray fluorescence devices.
Nuclear weapon designs could intentionally incorporate 59Co, some of which would be activated in a nuclear explosion to produce 60Co. The 60Co, dispersed as nuclear fallout, creates what is sometimes called a cobalt bomb.
Cobalt is essential to the metabolism of all animals. It is a key constituent of cobalamin, also known as vitamin B12, the primary biological reservoir of cobalt as an ultratrace element. Bacteria in the guts of ruminant animals convert cobalt salts into vitamin B12, a compound which can only be produced by bacteria or archaea. The minimum presence of cobalt in soils therefore markedly improves the health of grazing animals, and an uptake of 0.20 mg/kg a day is recommended because they have no other source of vitamin B12.
In the early 20th century during the development for farming of the North Island Volcanic Plateau of New Zealand, cattle suffered from what was termed "bush sickness". It was discovered that the volcanic soils lacked the cobalt salts essential for the cattle food chain.
The "coast disease" of sheep in the Ninety Mile Desert of the Southeast of South Australia in the 1930s was found to originate in nutritional deficiencies of the trace elements, cobalt and copper. The cobalt deficiency was overcome by the development of "cobalt bullets", dense pellets of cobalt oxide mixed with clay given orally for lodging in the animal's rumen.
Proteins based on cobalamin use corrin to hold the cobalt. Coenzyme B12 features a reactive C-Co bond that participates in the reactions. In humans, B12 has two types of alkyl ligand: methyl and adenosyl. MeB12 promotes methyl (-CH3) group transfers. The adenosyl version of B12 catalyzes rearrangements in which a hydrogen atom is directly transferred between two adjacent atoms with concomitant exchange of the second substituent, X, which may be a carbon atom with substituents, an oxygen atom of an alcohol, or an amine. Methylmalonyl coenzyme A mutase (MUT) converts MMl-CoA to Su-CoA, an important step in the extraction of energy from proteins and fats.
Although far less common than other metalloproteins (e.g. those of zinc and iron), cobaltoproteins are known aside from B12. These proteins include methionine aminopeptidase 2, an enzyme that occurs in humans and other mammals that does not use the corrin ring of B12, but binds cobalt directly. Another non-corrin cobalt enzyme is nitrile hydratase, an enzyme in bacteria that metabolize nitriles.
Cobalt is an essential element for life in minute amounts. The LD50 value for soluble cobalt salts has been estimated to be between 150 and 500 mg/kg. In the US, the Occupational Safety and Health Administration (OSHA) has designated a permissible exposure limit (PEL) in the workplace as a time-weighted average (TWA) of 0.1 mg/m3. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of 0.05 mg/m3, time-weighted average. The IDLH (immediately dangerous to life and health) value is 20 mg/m3.
However, chronic cobalt ingestion has caused serious health problems at doses far less than the lethal dose. In 1966, the addition of cobalt compounds to stabilize beer foam in Canada led to a peculiar form of toxin-induced cardiomyopathy, which came to be known as beer drinker's cardiomyopathy.
Cobalt can be effectively absorbed by charred pigs' bones; however, this process is inhibited by copper and zinc, which have greater affinities to bone char.
- Standard Atomic Weights 2013. Commission on Isotopic Abundances and Atomic Weights
- Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1117–1119. ISBN 0-08-037941-9.
- Enghag, Per (2004). "Cobalt". Encyclopedia of the elements: technical data, history, processing, applications. p. 667. ISBN 978-3-527-30666-4.
- Murthy, V. S. R (2003). "Magnetic Properties of Materials". Structure And Properties Of Engineering Materials. p. 381. ISBN 978-0-07-048287-6.
- Celozzi, Salvatore; Araneo, Rodolfo; Lovat, Giampiero (2008-05-01). Electromagnetic Shielding. p. 27. ISBN 978-0-470-05536-6.
- Lee, B.; Alsenz, R.; Ignatiev, A.; Van Hove, M.; Van Hove, M. A. (1978). "Surface structures of the two allotropic phases of cobalt". Physical Review B. 17 (4): 1510–1520. Bibcode:1978PhRvB..17.1510L. doi:10.1103/PhysRevB.17.1510.
- "Properties and Facts for Cobalt". American Elements. Retrieved 2008-09-19.
- Cobalt, Centre d'Information du Cobalt, Brussels (1966). Cobalt. p. 45.
- Holleman, A. F.; Wiberg, E.; Wiberg, N. (2007). "Cobalt". Lehrbuch der Anorganischen Chemie (in German) (102nd ed.). de Gruyter. pp. 1146–1152. ISBN 978-3-11-017770-1.
- Housecroft, C. E.; Sharpe, A. G. (2008). Inorganic Chemistry (3rd ed.). Prentice Hall. p. 722. ISBN 978-0131755536.
- Rutley, Frank (2012-12-06). Rutley’s Elements of Mineralogy. Springer Science & Business Media. p. 40. ISBN 9789401197694.
- Krebs, Robert E. (2006). The history and use of our earth's chemical elements: a reference guide (2nd ed.). Greenwood Publishing Group. p. 107. ISBN 0-313-33438-2.
- Petitto, Sarah C.; Marsh, Erin M.; Carson, Gregory A.; Langell, Marjorie A. (2008). "Cobalt oxide surface chemistry: The interaction of CoO(100), Co3O4(110) and Co3O4(111) with oxygen and water". Journal of Molecular Catalysis A: Chemical. 281: 49–58. doi:10.1016/j.molcata.2007.08.023.
- Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1119–1120. ISBN 0-08-037941-9.
- Werner, A. (1912). "Zur Kenntnis des asymmetrischen Kobaltatoms. V". Chemische Berichte. 45: 121–130. doi:10.1002/cber.19120450116.
- Gispert, Joan Ribas (2008). "Early Theories of Coordination Chemistry". Coordination chemistry. pp. 31–33. ISBN 978-3-527-31802-5.
- James E. House (2008). Inorganic chemistry. Academic Press. pp. 767–. ISBN 978-0-12-356786-4. Retrieved 2011-05-16.
- Charles M. Starks; Charles Leonard Liotta; Marc Halpern (1994). Phase-transfer catalysis: fundamentals, applications, and industrial perspectives. Springer. pp. 600–. ISBN 978-0-412-04071-9. Retrieved 2011-05-16.
- Sigel, Astrid; Sigel, Helmut; Sigel, Roland, eds. (2010). Organometallics in Environment and Toxicology (Metal Ions in Life Sciences). Cambridge, UK: Royal Society of Chemistry Publishing. p. 75. ISBN 978-1-84755-177-1.
- Audi, G.; Bersillon, O.; Blachot, J.; Wapstra, A.H. (2003). "The NUBASE Evaluation of Nuclear and Decay Properties". Nuclear Physics A. Atomic Mass Data Center. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Cobalt, Encyclopædia Britannica Online.
- Pulak, Cemal (1998). "The Uluburun shipwreck: an overview". International Journal of Nautical Archaeology. 27 (3): 188–224. doi:10.1111/j.1095-9270.1998.tb00803.x.
- Henderson, Julian (2000). "Glass". The Science and Archaeology of Materials: An Investigation of Inorganic Materials. Routledge. p. 60. ISBN 978-0-415-19933-9.
- Rehren, Th. (2003). "Aspects of the Production of Cobalt-blue Glass in Egypt". Archaeometry. 43 (4): 483–489. doi:10.1111/1475-4754.00031.
- Lucas, A. (2003). Ancient Egyptian Materials and Industries. Kessinger Publishing. p. 217. ISBN 978-0-7661-5141-3.
- Dennis, W. H (2010). "Cobalt". Metallurgy: 1863–1963. pp. 254–256. ISBN 978-0-202-36361-5.
- Georg Brandt first showed cobalt to be a new metal in: G. Brandt (1735) "Dissertatio de semimetallis" (Dissertation on semi-metals), Acta Literaria et Scientiarum Sveciae (Journal of Swedish literature and sciences), vol. 4, pages 1–10.
See also: (1) G. Brandt (1746) "Rön och anmärkningar angäende en synnerlig färg — cobolt" (Observations and remarks concerning an extraordinary pigment — cobalt), Kongliga Svenska vetenskapsakademiens handlingar (Transactions of the Royal Swedish Academy of Science), vol. 7, pages 119–130; (2) G. Brandt (1748) "Cobalti nova species examinata et descripta" (Cobalt, a new element examined and described), Acta Regiae Societatis Scientiarum Upsaliensis (Journal of the Royal Scientific Society of Uppsala), 1st series, vol. 3 , pages 33–41; (3) James L. Marshall and Virginia R. Marshall (Spring 2003) "Rediscovery of the Elements: Riddarhyttan, Sweden," Archived July 3, 2010, at the Wayback Machine. The Hexagon (official journal of the Alpha Chi Sigma fraternity of chemists), vol. 94, no. 1, pages 3–8.
- Wang, Shijie (2006). "Cobalt—Its recovery, recycling, and application". Journal of the Minerals, Metals and Materials Society. 58 (10): 47–50. Bibcode:2006JOM....58j..47W. doi:10.1007/s11837-006-0201-y.
- Weeks, Mary Elvira (1932). "The discovery of the elements. III. Some eighteenth-century metals". Journal of Chemical Education. 9: 22. Bibcode:1932JChEd...9...22W. doi:10.1021/ed009p22.
- Ivar B. Ramberg (2008). The making of a land: geology of Norway. Geological Society. pp. 98–. ISBN 978-82-92394-42-7. Retrieved 2011-04-30.
- Cyclopaedia (1852). C. Tomlinson. 9 divs, ed. Cyclopædia of useful arts & manufactures. pp. 400–. Retrieved 2011-04-30.
- Wellmer, Friedrich-Wilhelm; Becker-Platen, Jens Dieter. "Global Nonfuel Mineral Resources and Sustainability". United States Geological Survey.
- Westing, Arthur H; Stockholm International Peace Research Institute (1986). "cobalt". Global resources and international conflict: environmental factors in strategic policy and action. pp. 75–78. ISBN 978-0-19-829104-6.
- Livingood, J.; Seaborg, G. (1938). "Long-Lived Radio Cobalt Isotopes". Physical Review. 53 (10): 847–848. Bibcode:1938PhRv...53..847L. doi:10.1103/PhysRev.53.847.
- Wu, C. S. (1957). "Experimental Test of Parity Conservation in Beta Decay". Physical Review. 105 (4): 1413–1415. Bibcode:1957PhRv..105.1413W. doi:10.1103/PhysRev.105.1413.
- Wróblewski, A.K. (2008). "The Downfall of Parity – the Revolution That Happened Fifty Years Ago" (PDF). Acta Physica Polonica B. 39 (2): 251. Bibcode:2008AcPPB..39..251W.
- "Richest Hole In The Mountain" Popular Mechanics, May 1952, pp. 65–69.
- Ptitsyn, D. A.; Chechetkin, V. M. (1980). "Creation of the Iron-Group Elements in a Supernova Explosion". Soviet Astronomy Letters. 6: 61–64. Bibcode:1980SvAL....6...61P.
- Metallic Co in meteorites
- Kerr, Paul F. (1945). "Cattierite and Vaesite: New Co-Ni Minerals from the Belgian Kongo" (PDF). American Mineralogist. 30: 483–492.
- Buckley, A.N. (1987). "The Surface Oxidation of Cobaltite". Australian Journal of Chemistry. 40 (2): 231. doi:10.1071/CH9870231.
- Young, R (1957). "The geochemistry of cobalt". Geochimica et Cosmochimica Acta. 13: 28–41. Bibcode:1957GeCoA..13...28Y. doi:10.1016/0016-7037(57)90056-X.
- Shedd, Kim B. "Mineral Yearbook 2006: Cobalt" (PDF). United States Geological Survey. Retrieved 2008-10-26.
- Shedd, Kim B. "Commodity Report 2008: Cobalt" (PDF). United States Geological Survey. Retrieved 2008-10-26.
- "African Mineral Production" (PDF). British Geological Survey. Retrieved 2009-06-06.
- Frankel, Todd C. (2016-09-30). "Cobalt mining for lithium ion batteries has a high human cost". Washington Post. Retrieved 2016-10-18.
- Wellmer, Friedrich-Wilhelm; Becker-Platen, Jens Dieter. "Global Nonfuel Mineral Resources and Sustainability". Retrieved 2009-05-16.
- "CAMEC – The Cobalt Champion" (PDF). International Mining. July 2008. Retrieved 2011-11-18.
- Amy Witherden (6 July 2009). "Daily podcast – July 6, 2009". Mining weekly. Retrieved 2011-11-15.
- Davis, Joseph R. (2000). ASM specialty handbook: nickel, cobalt, and their alloys. ASM International. p. 347. ISBN 0-87170-685-7.
- Child labour behind smart phone and electric car batteries | Amnesty International
- Donachie, Matthew J. (2002). Superalloys: A Technical Guide. ASM International. ISBN 978-0-87170-749-9.
- Campbell, Flake C (2008-06-30). "Cobalt and Cobalt Alloys". Elements of metallurgy and engineering alloys. pp. 557–558. ISBN 978-0-87170-867-0.
- Michel, R.; Nolte, M.; Reich M.; Löer, F. (1991). "Systemic effects of implanted prostheses made of cobalt-chromium alloys". Archives of Orthopaedic and Trauma Surgery. 110 (2): 61–74. doi:10.1007/BF00393876. PMID 2015136.
- Disegi, John A. (1999). Cobalt-base Aloys for Biomedical Applications. ASTM International. p. 34. ISBN 0-8031-2608-5.
- Luborsky, F. E.; Mendelsohn, L. I.; Paine, T. O. (1957). "Reproducing the Properties of Alnico Permanent Magnet Alloys with Elongated Single-Domain Cobalt-Iron Particles". Journal of Applied Physics. 28 (344): 344. Bibcode:1957JAP....28..344L. doi:10.1063/1.1722744.
- Biggs, T.; Taylor, S. S.; Van Der Lingen, E. (2005). "The Hardening of Platinum Alloys for Potential Jewellery Application". Platinum Metals Review. 49: 2–15. doi:10.1595/147106705X24409.
- Hawkins, M. (2001). "Why we need cobalt". Applied Earth Science: Transactions of the Institution of Mining & Metallurgy, Section B. 110 (2): 66–71. doi:10.1179/aes.2001.110.2.66.
- Armstrong, R. D.; Briggs, G. W. D.; Charles, E. A. (1988). "Some effects of the addition of cobalt to the nickel hydroxide electrode". Journal of Applied Electrochemistry. 18 (2): 215–219. doi:10.1007/BF01009266.
- Zhang, P; Yokoyama, Toshiro; Itabashi, Osamu; Wakui, Yoshito; Suzuki, Toshishige M.; Inoue, Katsutoshi (1999). "Recovery of metal values from spent nickel–metal hydride rechargeable batteries". Journal of Power Sources. 77 (2): 116–122. Bibcode:1999JPS....77..116Z. doi:10.1016/S0378-7753(98)00182-7.
- Khodakov, Andrei Y.; Chu, Wei & Fongarland, Pascal (2007). "Advances in the Development of Novel Cobalt Fischer-Tropsch Catalysts for Synthesis of Long-Chain Hydrocarbons and Clean Fuels". Chemical Reviews. 107 (5): 1692–1744. doi:10.1021/cr050972v.
- Hebrard, Frédéric & Kalck, Philippe (2009). "Cobalt-Catalyzed Hydroformylation of Alkenes: Generation and Recycling of the Carbonyl Species, and Catalytic Cycle". Chemical Reviews. 109 (9): 4272–4282. doi:10.1021/cr8002533. PMID 19572688.
- Overman, Frederick (1852). A treatise on metallurgy. D. Appleton & company. pp. 631–637.
- Muhlethaler, Bruno; Thissen, Jean; Muhlethaler, Bruno (1969). "Smalt". Studies in Conservation. 14 (2): 47–61. doi:10.2307/1505347. JSTOR 1505347.
- Gehlen, A.F. (1803). "Ueber die Bereitung einer blauen Farbe aus Kobalt, die eben so schön ist wie Ultramarin. Vom Bürger Thenard". Neues allgemeines Journal der Chemie, Band 2. H. Frölich. (German translation from L. J. Thénard; Journal des Mines; Brumaire 12 1802; p 128–136)
- Witteveen, H. J.; Farnau, E. F. (1921). "Colors Developed by Cobalt Oxides". Industrial & Engineering Chemistry. 13 (11): 1061–1066. doi:10.1021/ie50143a048.
- Venetskii, S. (1970). "The charge of the guns of peace". Metallurgist. 14 (5): 334–336. doi:10.1007/BF00739447.
- Mandeville, C.; Fulbright, H. (1943). "The Energies of the γ-Rays from Sb122, Cd115, Ir192, Mn54, Zn65, and Co60". Physical Review. 64 (9–10): 265–267. Bibcode:1943PhRv...64..265M. doi:10.1103/PhysRev.64.265.
- Wilkinson, V. M; Gould, G (1998). Food irradiation: a reference guide. p. 53. ISBN 978-1-85573-359-6.
- Blakeslee, Sandra (1984-05-01). "The Juarez accident". New York Times. Retrieved 2009-06-06.
- "Ciudad Juarez orphaned source dispersal, 1983". Wm. Robert Johnston. 2005-11-23. Retrieved 2009-10-24.
- National Research Council (U.S.). Committee on Radiation Source Use and Replacement; National Research Council (U.S.). Nuclear and Radiation Studies Board (January 2008). Radiation source use and replacement: abbreviated version. National Academies Press. pp. 35–. ISBN 978-0-309-11014-3. Retrieved 2011-04-29.
- Meyer, Theresa (2001-11-30). Physical Therapist Examination Review. p. 368. ISBN 978-1-55642-588-2.
- Kalnicky, D; Singhvi, R (2001). "Field portable XRF analysis of environmental samples". Journal of Hazardous Materials. 83 (1–2): 93–122. doi:10.1016/S0304-3894(00)00330-7. PMID 11267748.
- Payne, L.R. (1977). "The Hazards of Cobalt". Occupational Medicine. 27 (1): 20–25. doi:10.1093/occmed/27.1.20.
- Davis, Joseph R; Handbook Committee, ASM International (2000-05-01). "Cobalt". Nickel, cobalt, and their alloys. p. 354. ISBN 978-0-87170-685-0.
- Committee On Technological Alternatives For Cobalt Conservation, National Research Council (U.S.); National Materials Advisory Board, National Research Council (U.S.) (1983). "Ground–Coat Frit". Cobalt conservation through technological alternatives. p. 129.
- Yamada, Kazuhiro (2013). "Chapter 9. Cobalt: Its Role in Health and Disease". In Astrid Sigel; Helmut Sigel; Roland K. O. Sigel. Interrelations between Essential Metal Ions and Human Diseases. Metal Ions in Life Sciences. 13. Springer. pp. 295–320. doi:10.1007/978-94-007-7500-8_9.
- Cracan, Valentin; Banerjee, Ruma (2013). "Chapter 10 Cobalt and Corrinoid Transport and Biochemistry". In Banci, Lucia. Metallomics and the Cell. Metal Ions in Life Sciences. 12. Springer. doi:10.1007/978-94-007-5561-10_10. ISBN 978-94-007-5560-4. electronic-book ISBN 978-94-007-5561-1 ISSN 1559-0836 electronic-ISSN 1868-0402
- Schwarz, F. J.; Kirchgessner, M.; Stangl, G. I. (2000). "Cobalt requirement of beef cattle – feed intake and growth at different levels of cobalt supply". Journal of Animal Physiology and Animal Nutrition. 83 (3): 121–131. doi:10.1046/j.1439-0396.2000.00258.x.
- "Soils". Waikato University. Retrieved 2012-01-16.
- McDowell, Lee Russell (2008). Vitamins in Animal and Human Nutrition. (2nd ed. ed.). Hoboken: John Wiley & Sons. p. 525. ISBN 9780470376683.
- Australian Academy of Science > Deceased Fellows > Hedley Ralph Marston 1900–1965 Accessed 12 May 2013.
- Voet, Judith G.; Voet, Donald (1995). Biochemistry. New York: J. Wiley & Sons. p. 675. ISBN 0-471-58651-X. OCLC 31819701.
- Smith, David M.; Golding, Bernard T.; Radom, Leo (1999). "Understanding the Mechanism of B12-Dependent Methylmalonyl-CoA Mutase: Partial Proton Transfer in Action". Journal of the American Chemical Society. 121 (40): 9388–9399. doi:10.1021/ja991649a.
- Kobayashi, Michihiko; Shimizu, Sakayu (1999). "Cobalt proteins". European Journal of Biochemistry. 261 (1): 1–9. doi:10.1046/j.1432-1327.1999.00186.x. PMID 10103026.
- Donaldson, John D. and Beyersmann, Detmar "Cobalt and Cobalt Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a07_281.pub2
- "NIOSH Pocket Guide to Chemical Hazards #0146". National Institute for Occupational Safety and Health (NIOSH).
- Morin Y; Tětu A; Mercier G (1969). "Quebec beer-drinkers' cardiomyopathy: Clinical and hemodynamic aspects". Annals of the New York Academy of Sciences. 156 (1): 566–576. Bibcode:1969NYASA.156..566M. doi:10.1111/j.1749-6632.1969.tb16751.x. PMID 5291148.
- Barceloux, Donald G. & Barceloux, Donald (1999). "Cobalt". Clinical Toxicology. 37 (2): 201–216. doi:10.1081/CLT-100102420.
- Basketter, David A.; Angelini, Gianni; Ingber, Arieh; Kern, Petra S.; Menné, Torkil (2003). "Nickel, chromium and cobalt in consumer products: revisiting safe levels in the new millennium". Contact Dermatitis. 49 (1): 1–7. doi:10.1111/j.0105-1873.2003.00149.x. PMID 14641113.
- Xiangliang, Pan; Jianlong, Wang; Daoyong, Zhang (January 2009). "Sorption of cobalt to bone char: Kinetics, competitive sorption and mechanism". Salination. 249: 609–614.
|Wikimedia Commons has media related to Cobalt.|
|Look up cobalt in Wiktionary, the free dictionary.|
- National Pollutant Inventory (Australia)– Cobalt fact sheet
- London celebrates 50 years of Cobalt-60 Radiotherapy
- Cobalt at The Periodic Table of Videos (University of Nottingham)
- Centers for Disease and Prevention – Cobalt
- The Cobalt Development Institute
|Periodic table (Large cells)|