Cyclopentadienyliron dicarbonyl iodide

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Cyclopentadienyliron dicarbonyl iodide
Cp2Fe(CO)2I-2D-skeletal.png
Cp2Fe(CO)2I-from-xtal-2003-Mercury-3D-balls.png
Identifiers
ECHA InfoCard 100.155.006
Properties
C7H5FeIO2
Molar mass 303.86 g·mol−1
Appearance Black crystaline solid (density = 2.374 g/cm3)
Melting point 119 °C (246 °F; 392 K)
Structure
Cs
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Cyclopentadienyliron dicarbonyl iodide is an organoiron compound with the formula (C5H5)Fe(CO)2I. It is a dark brown solid that is soluble in common organic solvents. (C5H5)Fe(CO)2I, or FpI as it is often known, is an intermediate for the preparation of other organoiron compounds such as in ferraboranes.

Preparation[edit]

Cyclopentadienyliron dicarbonyl iodide is synthesized by the reaction of cyclopentadienyliron dicarbonyl dimer with I2:[1]

Cp2Fe2(CO)4 + I2 → 2 CpFe(CO)2I

It was first reported by Paulson and Hallam.[2]

Structure[edit]

The compound has Cs symmetry, with a mirror plane intersecting one carbon of the Cp ring as well as the iron and iodide centre. The compound adopts a piano stool structure: the cyclopentadienyl ligand is the "seat" and three other ligands are "legs". Such compounds are members of the half-sandwich family of compounds, which is a subgroup of the metallocenes. X-ray crystallography shows the following features: Fe-Cp centroid = 1.72, Fe-I = 2.61, and Fe-CO = 1.78 Å.[3]

Electron counting of this ferrous complex indicates 5 electrons from the cyclopentadienyl anion, 2 electrons from each of the carbonyls, and 1 electron from the iodide.

References[edit]

  1. ^ King, R. B.; Stone, F. G. A "Cyclopentadienyl Metal Carbonyls and some Derivatives" Inorg. Syn. 1963, volume 7, pp. 99-115. doi:10.1002/9780470132388.ch31
  2. ^ B. F. Hallam, P. L. Paulson "Ferrocene Derivatives. Part III. Cyclopentadienyliron Carbonyls" J. Chem. Soc. 1956, pp. 3031-3037.
  3. ^ Zeller, M.; Lazich, E.; Hunter, A. D. (2003). "Dicarbonyl(η5-cyclopentadienyl)iodoiron(II)". Acta Crystallographica Section E. 59: m914–m915. doi:10.1107/S1600536803019950.