Deborah number

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The Deborah number (De) is a dimensionless number, often used in rheology to characterize the fluidity of materials under specific flow conditions. It is based on the premise that given enough time even a solid-like material will flow. The flow characteristics are not inherent properties of the material alone, but a relative property which depends on two fundamentally different characteristic times.

Definition[edit]

Formally, the Deborah number is defined as the ratio of the relaxation time characterizing the time it takes for a material to adjust to applied stresses or deformations, and the characteristic time scale of an experiment (or a computer simulation) probing the response of the material:

where tc stands for the relaxation time and tp for the "time of observation", typically taken to be the time scale of the process.[1]

This incorporates both the elasticity and viscosity of the material. At lower Deborah numbers, the material behaves in a more fluidlike manner, with an associated Newtonian viscous flow. At higher Deborah numbers, the material behavior enters the non-Newtonian regime, increasingly dominated by elasticity and demonstrating solidlike behavior.[2][3]

For example, for a Hookean elastic solid, the relaxation time tc will be infinite and it will vanish for a Newtonian viscous fluid. For liquid water, tc is typically 10−12 s, for lubricating oils passing through gear teeth at high pressure it is of the order of 10−6 s and for polymers undergoing plastics processing, the relaxation time will be of the order of a few seconds. Therefore, depending on the situation, these liquids may exhibit elastic properties, departing from purely viscous behavior.[4]

While De is similar to the Weissenberg number and is often confused with it in technical literature, they have different physical interpretations. The Weissenberg number indicates the degree of anisotropy or orientation generated by the deformation, and is appropriate to describe flows with a constant stretch history, such as simple shear. In contrast, the Deborah number should be used to describe flows with a non-constant stretch history, and physically represents the rate at which elastic energy is stored or released. [1]

History[edit]

The Deborah number was originally proposed by Markus Reiner, a professor at Technion in Israel, who chose the name inspired by a verse in the Bible, stating "The mountains flowed before the Lord" in a song by the prophet Deborah (Judges 5:5; הָרִ֥ים נָזְל֖וּ מִפְּנֵ֣י יְהוָ֑ה hā-rîm nāzəlū mippənê Yahweh).[2]

Time-temperature superposition[edit]

The Deborah number is particularly useful in conceptualizing the time–temperature superposition principle. Time-temperature superposition has to do with altering experimental time scales using reference temperatures to extrapolate temperature-dependent mechanical properties of polymers. A material at low temperature with a long experimental or relaxation time behaves like the same material at high temperature and short experimental or relaxation time if the Deborah number remains the same. This can be particularly useful when working with materials which relax on a long time scale under a certain temperature. The practical application of this idea arises in the Williams–Landel–Ferry equation. Time-temperature superposition avoids the inefficiency of measuring a polymer’s behavior over long periods of time at a specified temperature by utilizing the Deborah number.[5]

References[edit]

  1. ^ a b Poole, R J (2012). "The Deborah and Weissenberg numbers" (PDF). Rheology Bulletin. 53 (2): 32–39. 
  2. ^ a b Reiner, M. (1964), "The Deborah Number", Physics Today, 17 (1): 62, Bibcode:1964PhT....17a..62R, doi:10.1063/1.3051374 
  3. ^ The Deborah Number Archived 2011-04-13 at the Wayback Machine.
  4. ^ Barnes, H.A.; Hutton, J.F.; Walters, K. (1989). An introduction to rheology (5. impr. ed.). Amsterdam: Elsevier. pp. 5–6. ISBN 0-444-87140-3. 
  5. ^ Rudin, Alfred, and Phillip Choi. The Elements of Polymer Science and Engineering. 3rd. Oxford: Academic Press, 2013. Print. Page 221.