# Density

Density
A test tube holding four non-miscible colored liquids with different densities
Common symbols
ρ, D
SI unitkg/m3
Extensive?No
Intensive?Yes
Conserved?No
Derivations from
other quantities
${\displaystyle \rho ={\frac {m}{V}}}$
Dimension${\displaystyle {\mathsf {L}}^{-3}{\mathsf {M}}}$

Density (volumetric mass density or specific mass) is a substance's mass per unit of volume. The symbol most often used for density is ρ (the lower case Greek letter rho), although the Latin letter D can also be used. Mathematically, density is defined as mass divided by volume:[1] ${\displaystyle \rho ={\frac {m}{V}},}$ where ρ is the density, m is the mass, and V is the volume. In some cases (for instance, in the United States oil and gas industry), density is loosely defined as its weight per unit volume,[2] although this is scientifically inaccurate – this quantity is more specifically called specific weight.

For a pure substance the density has the same numerical value as its mass concentration. Different materials usually have different densities, and density may be relevant to buoyancy, purity and packaging. Osmium is the densest known element at standard conditions for temperature and pressure.

To simplify comparisons of density across different systems of units, it is sometimes replaced by the dimensionless quantity "relative density" or "specific gravity", i.e. the ratio of the density of the material to that of a standard material, usually water. Thus a relative density less than one relative to water means that the substance floats in water.

The density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Increasing the pressure on an object decreases the volume of the object and thus increases its density. Increasing the temperature of a substance (with a few exceptions) decreases its density by increasing its volume. In most materials, heating the bottom of a fluid results in convection of the heat from the bottom to the top, due to the decrease in the density of the heated fluid, which causes it to rise relative to denser unheated material.

The reciprocal of the density of a substance is occasionally called its specific volume, a term sometimes used in thermodynamics. Density is an intensive property in that increasing the amount of a substance does not increase its density; rather it increases its mass.

Other conceptually comparable quantities or ratios include specific density, relative density (specific gravity), and specific weight.

## History

### Density, floating, and sinking

The understanding that different materials have different densities, and of a relationship between density, floating, and sinking must date to prehistoric times. Much later it was put in writing. Aristotle, for example, wrote:[3]

There is so great a difference in density between salt and fresh water that vessels laden with cargoes of the same weight almost sink in rivers, but ride quite easily at sea and are quite seaworthy. And an ignorance of this has sometimes cost people dear who load their ships in rivers. The following is a proof that the density of a fluid is greater when a substance is mixed with it. If you make water very salt by mixing salt in with it, eggs will float on it. ... If there were any truth in the stories they tell about the lake in Palestine it would further bear out what I say. For they say if you bind a man or beast and throw him into it he floats and does not sink beneath the surface.

— Aristotle, Meteorologica, Book II, Chapter III

### Volume vs. density; volume of an irregular shape

In a well-known but probably apocryphal tale, Archimedes was given the task of determining whether King Hiero's goldsmith was embezzling gold during the manufacture of a golden wreath dedicated to the gods and replacing it with another, cheaper alloy.[4] Archimedes knew that the irregularly shaped wreath could be crushed into a cube whose volume could be calculated easily and compared with the mass; but the king did not approve of this. Baffled, Archimedes is said to have taken an immersion bath and observed from the rise of the water upon entering that he could calculate the volume of the gold wreath through the displacement of the water. Upon this discovery, he leapt from his bath and ran naked through the streets shouting, "Eureka! Eureka!" (Ancient Greek: Εύρηκα!, lit.'I have found it'). As a result, the term eureka entered common parlance and is used today to indicate a moment of enlightenment.

The story first appeared in written form in Vitruvius' books of architecture, two centuries after it supposedly took place.[5] Some scholars have doubted the accuracy of this tale, saying among other things that the method would have required precise measurements that would have been difficult to make at the time.[6][7]

Nevertheless, in 1586, Galileo Galilei, in one of his first experiments, made a possible reconstruction of how the experiment could have been performed with ancient Greek resources[8]

## Units

From the equation for density (ρ = m/V), mass density has any unit that is mass divided by volume. As there are many units of mass and volume covering many different magnitudes there are a large number of units for mass density in use. The SI unit of kilogram per cubic metre (kg/m3) and the cgs unit of gram per cubic centimetre (g/cm3) are probably the most commonly used units for density. One g/cm3 is equal to 1000 kg/m3. One cubic centimetre (abbreviation cc) is equal to one millilitre. In industry, other larger or smaller units of mass and or volume are often more practical and US customary units may be used. See below for a list of some of the most common units of density.

The litre and tonne are not part of the SI, but are acceptable for use with it, leading to the following units:

Densities using the following metric units all have exactly the same numerical value, one thousandth of the value in (kg/m3). Liquid water has a density of about 1 kg/dm3, making any of these SI units numerically convenient to use as most solids and liquids have densities between 0.1 and 20 kg/dm3.

• kilogram per cubic decimetre (kg/dm3)
• gram per cubic centimetre (g/cm3)
• 1 g/cm3 = 1000 kg/m3
• megagram (metric ton) per cubic metre (Mg/m3)

In US customary units density can be stated in:

Imperial units differing from the above (as the Imperial gallon and bushel differ from the US units) in practice are rarely used, though found in older documents. The Imperial gallon was based on the concept that an Imperial fluid ounce of water would have a mass of one Avoirdupois ounce, and indeed 1 g/cm3 ≈ 1.00224129 ounces per Imperial fluid ounce = 10.0224129 pounds per Imperial gallon. The density of precious metals could conceivably be based on Troy ounces and pounds, a possible cause of confusion.

Knowing the volume of the unit cell of a crystalline material and its formula weight (in daltons), the density can be calculated. One dalton per cubic ångström is equal to a density of 1.660 539 066 60 g/cm3.

## Measurement

A number of techniques as well as standards exist for the measurement of density of materials. Such techniques include the use of a hydrometer (a buoyancy method for liquids), Hydrostatic balance (a buoyancy method for liquids and solids), immersed body method (a buoyancy method for liquids), pycnometer (liquids and solids), air comparison pycnometer (solids), oscillating densitometer (liquids), as well as pour and tap (solids).[9] However, each individual method or technique measures different types of density (e.g. bulk density, skeletal density, etc.), and therefore it is necessary to have an understanding of the type of density being measured as well as the type of material in question.

### Homogeneous materials

The density at all points of a homogeneous object equals its total mass divided by its total volume. The mass is normally measured with a scale or balance; the volume may be measured directly (from the geometry of the object) or by the displacement of a fluid. To determine the density of a liquid or a gas, a hydrometer, a dasymeter or a Coriolis flow meter may be used, respectively. Similarly, hydrostatic weighing uses the displacement of water due to a submerged object to determine the density of the object.

### Heterogeneous materials

If the body is not homogeneous, then its density varies between different regions of the object. In that case the density around any given location is determined by calculating the density of a small volume around that location. In the limit of an infinitesimal volume the density of an inhomogeneous object at a point becomes: ${\displaystyle \rho ({\vec {r}})=dm/dV}$, where ${\displaystyle dV}$ is an elementary volume at position ${\displaystyle {\vec {r}}}$. The mass of the body then can be expressed as ${\displaystyle m=\int _{V}\rho ({\vec {r}})\,dV.}$

### Non-compact materials

In practice, bulk materials such as sugar, sand, or snow contain voids. Many materials exist in nature as flakes, pellets, or granules.

Voids are regions which contain something other than the considered material. Commonly the void is air, but it could also be vacuum, liquid, solid, or a different gas or gaseous mixture.

The bulk volume of a material —inclusive of the void space fraction— is often obtained by a simple measurement (e.g. with a calibrated measuring cup) or geometrically from known dimensions.

Mass divided by bulk volume determines bulk density. This is not the same thing as the material volumetric mass density. To determine the material volumetric mass density, one must first discount the volume of the void fraction. Sometimes this can be determined by geometrical reasoning. For the close-packing of equal spheres the non-void fraction can be at most about 74%. It can also be determined empirically. Some bulk materials, however, such as sand, have a variable void fraction which depends on how the material is agitated or poured. It might be loose or compact, with more or less air space depending on handling.

In practice, the void fraction is not necessarily air, or even gaseous. In the case of sand, it could be water, which can be advantageous for measurement as the void fraction for sand saturated in water—once any air bubbles are thoroughly driven out—is potentially more consistent than dry sand measured with an air void.

In the case of non-compact materials, one must also take care in determining the mass of the material sample. If the material is under pressure (commonly ambient air pressure at the earth's surface) the determination of mass from a measured sample weight might need to account for buoyancy effects due to the density of the void constituent, depending on how the measurement was conducted. In the case of dry sand, sand is so much denser than air that the buoyancy effect is commonly neglected (less than one part in one thousand).

Mass change upon displacing one void material with another while maintaining constant volume can be used to estimate the void fraction, if the difference in density of the two voids materials is reliably known.

## Changes of density

In general, density can be changed by changing either the pressure or the temperature. Increasing the pressure always increases the density of a material. Increasing the temperature generally decreases the density, but there are notable exceptions to this generalization. For example, the density of water increases between its melting point at 0 °C and 4 °C; similar behavior is observed in silicon at low temperatures.

The effect of pressure and temperature on the densities of liquids and solids is small. The compressibility for a typical liquid or solid is 10−6 bar−1 (1 bar = 0.1 MPa) and a typical thermal expansivity is 10−5 K−1. This roughly translates into needing around ten thousand times atmospheric pressure to reduce the volume of a substance by one percent. (Although the pressures needed may be around a thousand times smaller for sandy soil and some clays.) A one percent expansion of volume typically requires a temperature increase on the order of thousands of degrees Celsius.

In contrast, the density of gases is strongly affected by pressure. The density of an ideal gas is ${\displaystyle \rho ={\frac {MP}{RT}},}$

where M is the molar mass, P is the pressure, R is the universal gas constant, and T is the absolute temperature. This means that the density of an ideal gas can be doubled by doubling the pressure, or by halving the absolute temperature.

In the case of volumic thermal expansion at constant pressure and small intervals of temperature the temperature dependence of density is ${\displaystyle \rho ={\frac {\rho _{T_{0}}}{1+\alpha \cdot \Delta T}},}$

where ${\displaystyle \rho _{T_{0}}}$ is the density at a reference temperature, ${\displaystyle \alpha }$ is the thermal expansion coefficient of the material at temperatures close to ${\displaystyle T_{0}}$.

## Density of solutions

The density of a solution is the sum of mass (massic) concentrations of the components of that solution.

Mass (massic) concentration of each given component ${\displaystyle \rho _{i}}$ in a solution sums to density of the solution, ${\displaystyle \rho =\sum _{i}\rho _{i}.}$

Expressed as a function of the densities of pure components of the mixture and their volume participation, it allows the determination of excess molar volumes: ${\displaystyle \rho =\sum _{i}\rho _{i}{\frac {V_{i}}{V}}\,=\sum _{i}\rho _{i}\varphi _{i}=\sum _{i}\rho _{i}{\frac {V_{i}}{\sum _{i}V_{i}+\sum _{i}{V^{E}}_{i}}},}$ provided that there is no interaction between the components.

Knowing the relation between excess volumes and activity coefficients of the components, one can determine the activity coefficients: ${\displaystyle {\overline {V^{E}}}_{i}=RT{\frac {\partial \ln \gamma _{i}}{\partial P}}.}$

## List of densities

### Various materials

Densities of various materials covering a range of values
Material ρ (kg/m3)[note 1] Notes
Hydrogen 0.0898
Helium 0.179
Aerographite 0.2 [note 2][10][11]
Metallic microlattice 0.9 [note 2]
Aerogel 1.0 [note 2]
Air 1.2 At sea level
Tungsten hexafluoride 12.4 One of the heaviest known gases at standard conditions
Liquid hydrogen 70 At approximately −255 °C
Styrofoam 75 Approximate[12]
Cork 240 Approximate[12]
Pine 373 [13]
Lithium 535 Least dense metal
Wood 700 Seasoned, typical[14][15]
Oak 710 [13]
Potassium 860 [16]
Ice 916.7 At temperature < 0 °C
Cooking oil 910–930
Sodium 970
Water (fresh) 1,000 At 4 °C, the temperature of its maximum density
Water (salt) 1,030 3%
Liquid oxygen 1,141 At approximately −219 °C
Nylon 1,150
Plastics 1,175 Approximate; for polypropylene and PETE/PVC
Glycerol 1,261 [17]
Tetrachloroethene 1,622
Sand 1,600 Between 1,600 and 2,000 [18]
Magnesium 1,740
Beryllium 1,850
Silicon 2,330
Concrete 2,400 [19][20]
Glass 2,500 [21]
Quartzite 2,600 [18]
Granite 2,700 [18]
Gneiss 2,700 [18]
Aluminium 2,700
Limestone 2,750 Compact[18]
Basalt 3,000 [18]
Diiodomethane 3,325 Liquid at room temperature
Diamond 3,500
Titanium 4,540
Selenium 4,800
Antimony 6,690
Zinc 7,000
Chromium 7,200
Tin 7,310
Manganese 7,325 Approximate
Mild steel 7,850
Iron 7,870
Niobium 8,570
Brass 8,600 [20]
Cobalt 8,900
Nickel 8,900
Copper 8,940
Bismuth 9,750
Molybdenum 10,220
Silver 10,500
Thorium 11,700
Rhodium 12,410
Mercury 13,546
Tantalum 16,600
Uranium 19,100
Tungsten 19,300
Gold 19,320
Plutonium 19,840
Rhenium 21,020
Platinum 21,450
Iridium 22,420
Osmium 22,570 Densest natural element on Earth
1. ^ Unless otherwise noted, all densities given are at standard conditions for temperature and pressure,
that is, 273.15 K (0.00 °C) and 100 kPa (0.987 atm).
2. ^ a b c Air contained in material excluded when calculating density

### Others

Entity ρ (kg/m3) Notes
Interstellar medium 1.7×10−26 Based on 10−5 hydrogen atoms per cubic centimetre[22]
Local Interstellar Cloud 5×10−22 Based on 0.3 hydrogen atoms per cubic centimetre[22]
Interstellar medium 1.7×10−16 Based on 105 hydrogen atoms per cubic centimetre[22]
The Earth 5,515 Mean density.[23]
Earth's inner core 13,000 Approx., as listed in Earth.[24]
The core of the Sun 33,000–160,000 Approx.[25]
White dwarf star 2.1×109 Approx.[26]
Atomic nuclei 2.3×1017 Does not depend strongly on size of nucleus[27]
Neutron star 1×1018

### Water

Density of liquid water at 1 atm pressure
Temp. (°C)[note 1] Density (kg/m3)
−30 983.854
−20 993.547
−10 998.117
0 999.8395
4 999.9720
10 999.7026
15 999.1026
20 998.2071
22 997.7735
25 997.0479
30 995.6502
40 992.2
60 983.2
80 971.8
100 958.4
Notes:
1. ^ Values below 0 °C refer to supercooled water.

### Air

Density of air at 1 atm pressure
T (°C) ρ (kg/m3)
−25 1.423
−20 1.395
−15 1.368
−10 1.342
−5 1.316
0 1.293
5 1.269
10 1.247
15 1.225
20 1.204
25 1.184
30 1.164
35 1.146

## References

1. ^ "Gas Density". Glenn Research Center. National Aeronautic and Space Administration. Archived from the original on April 14, 2013. Retrieved April 9, 2013.
2. ^ "Density definition". Oil Gas Glossary. Archived from the original on August 5, 2010. Retrieved September 14, 2010.
3. ^ Aristotle. (1952) [c. 340 BC]. Meteorologica (in Ancient Greek and English). Translated by Lee, H. D. P. Harvard University Press. pp. 2.3, 359a.
4. ^ Archimedes, A Gold Thief and Buoyancy Archived August 27, 2007, at the Wayback Machine – by Larry "Harris" Taylor, Ph.D.
5. ^ Vitruvius on Architecture, Book IX, paragraphs 9–12, translated into English and in the original Latin.
6. ^ "EXHIBIT: The First Eureka Moment". Science. 305 (5688): 1219e. 2004. doi:10.1126/science.305.5688.1219e.
7. ^ Biello, David (December 8, 2006). "Fact or Fiction?: Archimedes Coined the Term "Eureka!" in the Bath". Scientific American.
8. ^ La Bilancetta, Complete text of Galileo's treatise in the original Italian together with a modern English translation [1]
9. ^ "Test No. 109: Density of Liquids and Solids". OECD Guidelines for the Testing of Chemicals, Section 1: 6. October 2, 2012. doi:10.1787/9789264123298-en. ISBN 9789264123298. ISSN 2074-5753.
10. ^ New carbon nanotube struructure aerographite is lightest material champ Archived October 17, 2013, at the Wayback Machine. Phys.org (July 13, 2012). Retrieved on July 14, 2012.
11. ^ Aerographit: Leichtestes Material der Welt entwickelt – SPIEGEL ONLINE Archived October 17, 2013, at the Wayback Machine. Spiegel.de (July 11, 2012). Retrieved on July 14, 2012.
12. ^ a b "Re: which is more bouyant [sic] styrofoam or cork". Madsci.org. Archived from the original on February 14, 2011. Retrieved September 14, 2010.
13. ^ a b Serway, Raymond; Jewett, John (2005), Principles of Physics: A Calculus-Based Text, Cengage Learning, p. 467, ISBN 0-534-49143-X, archived from the original on May 17, 2016
14. ^ "Wood Densities". www.engineeringtoolbox.com. Archived from the original on October 20, 2012. Retrieved October 15, 2012.
15. ^ "Density of Wood". www.simetric.co.uk. Archived from the original on October 26, 2012. Retrieved October 15, 2012.
16. ^ Bolz, Ray E.; Tuve, George L., eds. (1970). "§1.3 Solids—Metals: Table 1-59 Metals and Alloys—Miscellaneous Properties". CRC Handbook of tables for Applied Engineering Science (2nd ed.). CRC Press. p. 117. ISBN 9781315214092.
17. ^ glycerol composition at Archived February 28, 2013, at the Wayback Machine. Physics.nist.gov. Retrieved on July 14, 2012.
18. Sharma, P.V. (1997), Environmental and Engineering Geophysics, Cambridge University Press, p. 17, doi:10.1017/CBO9781139171168, ISBN 9781139171168
19. ^ "Density of Concrete - The Physics Factbook". hypertextbook.com.
20. ^ a b Young, Hugh D.; Freedman, Roger A. (2012). University Physics with Modern Physics. Addison-Wesley. p. 374. ISBN 978-0-321-69686-1.
21. ^ "Density of Glass - The Physics Factbook". hypertextbook.com.
22. ^ a b c "Our Local Galactic Neighborhood". Interstellar Probe Project. NASA. 2000. Archived from the original on November 21, 2013. Retrieved August 8, 2012.
23. ^ Density of the Earth, wolframalpha.com, archived from the original on October 17, 2013
24. ^ Density of Earth's core, wolframalpha.com, archived from the original on October 17, 2013
25. ^ Density of the Sun's core, wolframalpha.com, archived from the original on October 17, 2013
26. ^ Johnson, Jennifer. "Extreme Stars: White Dwarfs & Neutron Stars]" (PDF). lecture notes, Astronomy 162. Ohio State University. Archived from the original (PDF) on September 25, 2007.
27. ^ "Nuclear Size and Density". HyperPhysics. Georgia State University. Archived from the original on July 6, 2009.