This page is about types of dental restorative materials. For dental fillings see dental restoration
Dental materials are specially fabricated materials, designed for use in dentistry. There are many different types of dental material, and their characteristics vary according to their intended purpose. Examples include temporary dressings, dental restorations (fillings, crowns, bridges), endodontic materials (used in root canal therapy), impression materials, prosthetic materials (dentures), dental implants, and many others.
- 1 Temporary dressings
- 2 Cements
- 3 Impression materials
- 4 Restorative materials
- 4.1 Direct restorative materials
- 4.2 Indirect Restorative materials
- 4.3 Other historical fillings
- 4.4 Failure of dental restorations
- 4.5 Evaluation and regulation of dental materials
- 5 References
A temporary dressing is a dental filling which is not intended to last in the long term. They are interim materials which may have therapeutic properties. A common use of temporary dressing occurs if root canal therapy is carried out over more than one appointment. In between each visit, the pulp canal system must be protected from contamination from the oral cavity, and a temporary filling is placed in the access cavity. Examples include:
- Zinc oxide eugenol—bactericidal, cheap and easy to remove. Eugenol is derived from oil of Cloves, and has an obtundant effect on the tooth and decreases toothache. It is suitable temporary material providing there are no biting forces on it. It is also contraindicated if the final restorative material is composite because eugenol adversely effects the bond/polymerization process. Examples brands: Kalzinol, Sedanol.
Dental cements are used most often to bond indirect restorations such as crowns to the natural tooth surface. Examples include:
- Zinc oxide cement—self setting and harden when in contact with saliva. Example brands: Cavit, Coltosol.
- Polycarboxylate cement—Adheres to enamel and dentin. Example brands: PolyF.
Dental impressions are negative imprints of teeth and oral soft tissues from which a positive representation can be cast. They are used in prosthodontics (to make dentures), orthodontics, restorative dentistry, dental implantology and oral and maxillofacial surgery.
Impression materials are designed to be liquid or semi-solid when first mixed, then set hard in a few minutes, leaving imprints of oral structures.
Dental restorative materials are used to replace tooth structure loss, usually due to dental caries (dental cavities), but also tooth wear and dental trauma. On other occasions, such materials may be used for cosmetic purposes to alter the appearance of an individual's teeth.
There are many challenges for the physical properties of the ideal dental restorative material. The goal of research and development in restorative materials is to develop the ideal restorative material. The ideal restorative material would be identical to natural tooth structure in strength, adherence, and appearance. The properties of an ideal filling material can be divided into four categories: physical properties, biocompatibility, aesthetics and application.
- Requisite physical properties include low thermal conductivity and expansion, resistance to different categories of forces and wear such as attrition and abrasion, and resistance to chemical erosion. There must also be good bonding strength to the tooth. Everyday masticatory forces and conditions must be withstood without material fatigue.
- Biocompatibility refers to how well the material coexists with the biological equilibrium of the tooth and body systems. Since fillings are in close contact with mucosa, tooth, and pulp, biocompatibility is very important. Common problems with some of the current dental materials include chemical leakage from the material, pulpal irritation and less commonly allergy. Some of the byproducts of the chemical reactions during different stages of material hardening need to be considered.
- Ideally, filling materials should match the surrounding tooth structure in shade, translucency, and texture.
- Dental operators require materials that are easy to manipulate and shape, where the chemistry of any reactions that need to occur are predictable or controllable.
Direct restorative materials
Direct restorations are ones which are placed directly into a cavity on a tooth, and shaped to fit. The chemistry of the setting reaction for direct restorative materials is designed to be more biologically compatible. Heat and byproducts generated cannot damage the tooth or patient, since the reaction needs to take place while in contact with the tooth during restoration. This ultimately limits the strength of the materials, since harder materials need more energy to manipulate. The type of filling (restorative) material used has a minor effect on how long they last. The majority of clinical studies indicate the annual failure rates (AFR’s) are between 1% and 3% with tooth colored fillings on back teeth. Note that root canaled (endodontically) treated teeth have AFR’s between 2% and 12%. The main reasons for failure are cavities that occur around the filling and fracture of the real tooth. These are related to personal cavity risk and factors like grinding teeth (bruxism).
Amalgam is a metallic filling material composed from a mixture of mercury (from 43% to 54%) and powdered alloy made mostly of silver, tin, zinc and copper, commonly called the amalgam alloy. Amalgam does not adhere to tooth structure without the aid of cements or use of techniques which lock in the filling, using the same principles as a dovetail joint.
Amalgam is still used extensively in many parts of the world because of its cost effectiveness, superior strength and longevity. However, the metallic colour is not aesthetically pleasing and tooth coloured alternatives are continually emerging with increasingly comparable properties. Due to the known toxicity of the element mercury, there is some controversy about the use of amalgams. The Swedish government banned the use of mercury amalgam in June 2009. Research has shown that, while amalgam use is controversial and may increase mercury levels in the human body, these levels are below safety threshold levels established by the WHO and the EPA. However, there are certain subpopulations who, due to inherited genetic variabilities, exhibit sensitivity to mercury levels lower than these threshold levels. These particular individuals may experience adverse effects caused by amalgam restoration. These include myriad neural defects, mainly caused by impaired neurotransmitter processing.
Composite resin fillings (also called white fillings) are a mixture of powdered glass and plastic resin, and can be made to resemble the appearance of the natural tooth. Although cosmetically superior to amalgam fillings, composite resin fillings are usually more expensive. Bis-GMA based resins contain Bisphenol A, a known endocrine disrupter chemical, and may contribute to the development of breast cancer. However, it has been demonstrated that the extremely low levels of bis-GMA released by composite restorations do not cause a significant increase in markers of renal injury, when compared to amalgam restorations. That is, there is no added risk of renal or endocrine injury in choosing composite restorations over amalgams. PEX-based materials do not contain Bisphenol A and are the least cytotoxic material available.
Most modern composite resins are light-cured photopolymers, meaning that they harden with light exposure. They can then be polished to achieve maximum aesthetic results. Composite resins experience a very small amount of shrinkage upon curing, causing the material to pull away from the walls of the cavity preparation. This makes the tooth slightly more vulnerable to microleakage and recurrent decay. Microleakage can be minimized or eliminated by utilizing proper handling techniques and appropriate material selection.
In some circumstances, less tooth structure can be removed compared to preparation for other dental materials such as amalgam and many of the indirect methods of restoration. This is because composite resins bind to enamel (and dentin too, although not as well) via a micromechanical bond. As conservation of tooth structure is a key ingredient in tooth preservation, many dentists prefer placing materials like composite instead of amalgam fillings whenever possible.
Generally, composite fillings are used to fill a carious lesion involving highly visible areas (such as the central incisors or any other teeth that can be seen when smiling) or when conservation of tooth structure is a top priority.
The bond of composite resin to tooth, is especially affected by moisture contamination and cleanliness of the prepared surface. Other materials can be selected when restoring teeth where moisture control techniques are not effective.
Glass Ionomer Cement
The concept of using “smart” materials in dentistry has attracted a lot of attention in recent years. Conventional glass-ionomer (GI) cements have a large number of applications in dentistry. They are biocompatible with the dental pulp to some extent. Clinically, this material was initially used as a biomaterial to replace the lost osseous tissues in the human body.
These fillings are a mixture of glass and an organic acid. Although they are tooth-colored, glass ionomers vary in translucency. Although glass ionomers can be used to achieve an aesthetic result, their aesthetic potential does not measure up to that provided by composite resins.
The cavity preparation of a glass ionomer filling is the same as a composite resin. However, one of the advantages of GI compared to other restorative materials is that they can be placed in cavities without any need for bonding agents (4).
Conventional glass ionomers are chemically set via an acid-base reaction. Upon mixing of the material components, there is no light cure needed to harden the material once placed in the cavity preparation. After the initial set, glass ionomers still need time to fully set and harden.
1. Glass ionomer can be placed in cavities without any need for bonding agents .
2. They are not subject to shrinkage and microleakage, as the bonding mechanism is an acid-base reaction and not a polymerization reaction.(GICs do not undergo great dimensional changes in a moist environment in response to heat or cold and it appears heating results only in water movement within the structure of the material. These exhibit shrinkage in a dry environment at temperature higher than 50C, which is similar to the behavior of dentin.
3. Glass ionomers contain and release fluoride, which is important to preventing carious lesions. Furthermore, as glass ionomers release their fluoride, they can be "recharged" by the use of fluoride-containing toothpaste. Hence, they can be used as a treatment modality for patients who are at high risk for caries. Newer formulations of glass ionomers that contain light-cured resins can achieve a greater aesthetic result, but do not release fluoride as well as conventional glass ionomers.
The most important disadvantage is lack of adequate strength and toughness. In an attempt to improve the mechanical properties of the conventional GI, resin-modified ionomers have been marketed. GICs are usually weak after setting and are not stable in water; however, they become stronger with the progression of reactions and become more resistant to moisture. New generations: The aim is tissue regeneration and use of biomaterial in the form of a powder or solution is to induce local tissue repair. These bioactive materials release chemical agents in the form of dissolved ions or growth factors such as bone morphogenic protein, which stimulates activate cells.
Glass ionomers are about as expensive as composite resin. The fillings do not wear as well as composite resin fillings. Still, they are generally considered good materials to use for root caries and for sealants.
Resin modified Glass-Ionomer Cement (RMGIC)
A combination of glass-ionomer and composite resin, these fillings are a mixture of glass, an organic acid, and resin polymer that harden when light cured (the light activates a catalyst in the cement that causes it to cure in seconds). The cost is similar to composite resin. It holds up better than glass ionomer, but not as well as composite resin, and is not recommended for biting surfaces of adult teeth.
Generally, resin modified glass-ionomer cements can achieve a better aesthetic result than conventional glass ionomers, but not as good as pure composites. It has its own setting reaction.
Another combination of composite resin and glass ionomer technology, with focus lying towards the composite resin end of the spectrum. Although compomers have better mechanical and aesthetic properties than RMGIC, they have worse wear properties and require bonding materials. Although compomers release fluoride, they do so at such a low level that it is not deemed effective, and unlike glass ionomer and RMIC, cannot act as a fluoride reservoir.
Indirect Restorative materials
Indirect restorations are ones where the tooth or teeth to receive the restoration are first prepared, then a dental impression is taken and sent to a dental technician who fabricates the restoration according to the dentist's prescription.
Nano-ceramic particles embedded in a resin matrix, they are less brittle and therefore less likely to crack, or chip, than all-ceramic indirect fillings; they absorb the shock of chewing more like natural teeth, and more like resin or gold fillings, than do ceramic fillings; and at the same time more resistant to wear than all-resin indirect fillings. These are available in blocks for use with CAD-CAM systems.
Gold fillings have excellent durability, wear well, and do not cause excessive wear to the opposing teeth, but they do conduct heat and cold, which can be irritating. There are two categories of gold fillings, cast gold fillings (gold inlays and onlays) made with 14 or 18 kt gold, and gold foil made with pure 24 kt gold that is burnished layer by layer. For years, they have been considered the benchmark of restorative dental materials. Recent advances in dental porcelains and consumer focus on aesthetic results have caused demand for gold fillings to drop in favor of advanced composites and porcelain veneers and crowns. Gold fillings are sometimes quite expensive; yet, they do last a very long time - which can mean gold restorations are less costly and painful in the long run. It is not uncommon for a gold crown to last 30 years.
Other historical fillings
Lead fillings were used in the 18th century, but became unpopular in the 19th century because of their softness. This was before lead poisoning was understood.
According to American Civil War-era dental handbooks from the mid-19th century, since the early 19th century metallic fillings had been used, made of lead, gold, tin, platinum, silver, aluminum, or amalgam. A pellet was rolled slightly larger than the cavity, condensed into place with instruments, then shaped and polished in the patient's mouth. The filling was usually left "high", with final condensation — "tamping down" — occurring while the patient chewed food. Gold foil was the most popular and preferred filling material during the Civil War. Tin and amalgam were also popular due to lower cost, but were held in lower regard.
One survey of dental practices in the mid-19th century catalogued dental fillings found in the remains of seven Confederate soldiers from the U.S. Civil War; they were made of:
- Gold foil: Preferred because of its durability and safety.
- Platinum: Was rarely used because it was too hard, inflexible and difficult to form into foil.
- Aluminum: A material which failed because of its lack of malleability but has been added to some amalgams.
- Tin and iron: Believed to have been a very popular filling material during the Civil War. Tin foil was recommended when a cheaper material than gold was requested by the patient, however tin wore down rapidly and even if it could be replaced cheaply and quickly, there was a concern, specifically from Harris, that it would oxidise in the mouth and thus cause a recurrence of caries. Due to the blackening, tin was only recommended for posterior teeth.
- Thorium: Radioactivity was unknown at that time, and the dentist probably thought he was working with tin.
- Lead and tungsten mixture, probably coming from shotgun pellets. Lead was rarely used in the 19th century, it is soft and quickly worn down by mastication, and had known harmful health effects.
Failure of dental restorations
Fillings have a finite lifespan: an average of 12.8 years for amalgam and 7.8 years for composite resins. However, the lifespan of a restoration also depends upon how the patient takes care of the damaged tooth. 
Evaluation and regulation of dental materials
The Nordic Institute of Dental Materials (NIOM) evaluates dental materials in the Nordic countries. This research and testing institution are accredited to perform several test procedures for dental products. In Europe, dental materials are classified as medical devices according to the Medical Devices Directive. In USA, the U.S. Food and Drug Administration is the regulatory body for dental products.
- Demarco, F; et al. (March 2014). "Longevity of posterior composite restorations: Not only a matter of materials". Dental Materials: 87–101.
- WHO - Mercury in Health Care :Amalgam is a mixture of mercury and a metal alloy page 1 item # 2, third paragraph.
- "Sweden will ban the use of mercury on 1 juni 2009". Regeringskansliet.
- Woods, JS; et al. (2014). "Genetic polymorphisms of catechol-O-methltransferase modify the neurobehavioral effects of mercury in children". J Toxicol Environ Health A. 77 (6): 293–312. doi:10.1080/15287394.2014.867210. PMC . PMID 24593143.
- Woods, JS; et al. (2014). "Genetic polymorphisms of catechol-O-methyltransferase modify the neurobehabioral effects of mercury in children". J Toxicol Environ Health. 6 (77): 293–312.
- Composite resin fillings and inlays. An 11-year evaluation.; U Pallesen, V Qvist; (2003) Clin Oral Invest 7:71–79 doi:10.1007/s00784-003-0201-z
- Van Nieuwenhuysen JP, D'Hoore W, Carvalho J, Qvist V (August 2003). "Long-term evaluation of extensive restorations in permanent teeth". J Dent. 31 (6): 395–405. doi:10.1016/S0300-5712(03)00084-8. PMID 12878022.
- Dental Materials Fact Sheet, Dental Board of California, May 2004