Dinitrogen trioxide

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Dinitrogen trioxide
Dinitrogen trioxide
Dinitrogen-trioxide-xtal-3D-vdW.png
Names
Other names
Nitrous anhydride, nitrogen sesquioxide
Identifiers
10544-73-7 YesY
ChEBI CHEBI:29799 YesY
ChemSpider 55446 YesY
EC number 234-128-5
Jmol-3D images Image
PubChem 61526
Properties
N2O3
Molar mass 76.01 g/mol
Appearance deep blue liquid
Density 1.447 g/cm3, liquid
1.783 g/cm3 (gas)
Melting point −100.7[1] °C (−149.3 °F; 172.5 K)
Boiling point 3.5 °C (38.3 °F; 276.6 K)(dissociates[1])
very soluble
Solubility soluble in ether
Structure
planar, Cs
2.122 D
Thermochemistry
65.3 J/mol K
314.63 J K−1 mol−1
+91.20 kJ/mol
Hazards
EU classification Highly toxic (T+)
NFPA 704
Flammability code 0: Will not burn. E.g., water Health code 3: Short exposure could cause serious temporary or residual injury. E.g., chlorine gas Reactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogen Special hazard OX: Oxidizer. E.g., potassium perchlorateNFPA 704 four-colored diamond
Flash point Non-flammable
Related compounds
Nitrous oxide
Nitric oxide
Nitrogen dioxide
Dinitrogen tetroxide
Dinitrogen pentoxide
Nitrogen trioxide
Related compounds
Nitrous acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Dinitrogen trioxide is the chemical compound with the formula N2O3. This deep blue solid[1] is one of the binary nitrogen oxides. It forms upon mixing equal parts of nitric oxide and nitrogen dioxide and cooling the mixture below −21 °C (−6 °F):[2]

NO + NO2 is in equilibrium with N2O3

Dinitrogen trioxide is only isolable at low temperatures, i.e. in the liquid and solid phases. At higher temperatures the equilibrium favors the constituent gases, with Kdiss = 193 kPa (25 °C).[3]

Structure and bonding[edit]

Typically, N–N bonds are similar in length to that in hydrazine (145 pm). Dinitrogen trioxide, however, has an unusually long N–N bond at 186 pm. Some other nitrogen oxides do also possess long N–N bonds, including dinitrogen tetroxide (175 pm). The N2O3 molecule is planar and exhibits Cs symmetry. The dimensions displayed below come from microwave spectroscopy of low-temperature, gaseous N2O3:[2]

Dinitrogen-trioxide-2D-geometry.png

It is the anhydride of the unstable nitrous acid (HNO2), and produces it when mixed into water. An alternative structure might be anticipated for the true anhydride, i.e. O=N–O–N=O, but this isomer is not observed. If the nitrous acid is not then used up quickly, it decomposes into nitric oxide and nitric acid. Nitrite salts are sometimes produced by adding N2O3 to solutions of bases:

N2O3 + 2 NaOH → 2 NaNO2 + H2O

References[edit]

  1. ^ a b c Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 444. ISBN 0080379419. 
  2. ^ a b Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. pp. 521–22. ISBN 0-08-022057-6. 
  3. ^ Holleman, A. F.; Wiberg, E. (2001), Inorganic Chemistry, San Diego: Academic Press, ISBN 0-12-352651-5 

External links[edit]