Electric field gradient

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In atomic, molecular, and solid-state physics, the electric field gradient (EFG) measures the rate of change of the electric field at an atomic nucleus generated by the electronic charge distribution and the other nuclei. The EFG couples with the nuclear electric quadrupole moment of quadrupolar nuclei (those with spin quantum number greater than one-half) to generate an effect which can be measured using several spectroscopic methods, such as nuclear magnetic resonance (NMR), microwave spectroscopy, electron paramagnetic resonance (EPR, ESR), nuclear quadrupole resonance (NQR), Mössbauer spectroscopy or perturbed angular correlation (PAC). The EFG is non-zero only if the charges surrounding the nucleus violate cubic symmetry and therefore generate an inhomogeneous electric field at the position of the nucleus.

EFGs are highly sensitive to the electronic density in the immediate vicinity of a nucleus. This is because the EFG operator scales as r−3, where r is the distance from a nucleus. This sensitivity has been used to study effects on charge distribution resulting from substitution, weak interactions, and charge transfer.


A given charge distribution of electrons and nuclei, ρ(r), generates an electrostatic potential V(r). The derivative of this potential is the negative of the electric field generated. The first derivatives of the field, or the second derivatives of the potential, is the electric field gradient. The nine components of the EFG are thus defined as the second spatial derivatives of the electrostatic potential, evaluated at the position of a nucleus:

For each nucleus, the components Vij are combined as a symmetric 3 × 3 matrix. Under the assumption that the charge distribution generating the electrostatic potential is external to the nucleus, the matrix is traceless, for in that situation Laplace's equation, ∇2V(r) = 0, holds. Relaxing this assumption, a more general form of the EFG tensor which retains the symmetry and traceless character is

where ∇2V(r) is evaluated at a given nucleus.

As V (and φ) is symmetric it can be diagonalized. The principal tensor components are usually denoted Vzz, Vyy and Vxx in order of decreasing modulus. Given the traceless character, only two of the principal components are independent. Typically these are described by Vzz and the asymmetry parameter, η, defined as

with and , thus .

Electric field gradient as well as the asymmetry parameter can be evaluated numerically for large electric systems as shown in.[1]


  1. ^ Hernandez-Gomez, J J; Marquina, V; Gomez, R W (25 July 2013). "Algorithm to compute the electric field gradient tensor in ionic crystals". Rev. Mex. Fís. Sociedad Mexicana de Física. 58 (1): 13. Retrieved 23 April 2016.