Electron rest mass

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Values of me Units
9.10938356(11)×10−31 kg
5.485799090(16)×10−4 u
8.18710565(10)×10−14 J/c2
0.5109989461(13) MeV/c2
Values of the energy of me Units
8.18710565(10)×10−14 J
0.5109989461(13) MeV

The electron rest mass (symbol: me) is the mass of a stationary electron. It is one of the fundamental constants of physics and is also very important in chemistry because of its relation[dubious ] to the Avogadro constant. It has a value of about 9.109×10−31 kilograms or about 5.486×10−4 atomic mass units, equivalent to an energy of about 8.187×10−14 joules or about 0.5110 MeV.[1]

Terminology[edit]

The term "rest mass" is used because according to special relativity the mass of an object is increased in a frame of reference that is moving relative to that object. Most practical measurements are carried out on moving electrons. If the electron is moving at a relativistic velocity, the result must therefore be corrected to obtain the rest mass. This correction is only substantial for electrons accelerated by voltages of well over 100 kV.

Determination[edit]

Since the electron mass determines a number of observed effects in atomic physics, there are potentially many ways to determine its mass from an experiment, if the values of other physical constants are already considered known.

Historically, the mass of the electron was determined directly from combining two measurements. The mass-to-charge ratio of the electron was first estimated by Arthur Schuster in 1890 by measuring the deflection of "cathode rays" due to a known magnetic field in a cathode ray tube. This was before it was even known what cathode rays actually were! It was seven years later that J. J. Thomson showed that cathode rays consist of streams of particles, to be called electrons, and made more precise measurements of their mass-to-charge ratio again using a cathode ray tube.

The second measurement was of the charge of the electron. This was determined with a precision of better than 1% by Robert A. Millikan in his famous oil drop experiment in 1909. Together with the mass-to-charge ratio, the electron mass was thereby determined with reasonable precision. The value of mass that was found for the electron was initially met with surprise by physicists, since it was so small (less than .1%) compared to the known mass of a hydrogen atom.

The electron rest mass can be calculated from the Rydberg constant R and the fine structure constant α obtained through spectroscopic measurements. Using the definition of the Rydberg constant:

,

thus

where c is the speed of light and h is the Planck constant.[1] The relative uncertainty, 5×10−8 in the 2006 CODATA recommended value,[2] is due entirely to the uncertainty in the value of the Planck constant.

The electron relative atomic mass can be measured directly in a Penning trap. It can also be inferred from the spectra of antiprotonic helium atoms (helium atoms where one of the electrons has been replaced by an antiproton) or from measurements of the electron g-factor in the hydrogenic ions 12C5+ or 16O7+.

The electron relative atomic mass is an adjusted parameter in the CODATA set of fundamental physical constants, while the electron rest mass in kilograms is calculated from the values of the Planck constant, the fine structure constant and the Rydberg constant, as detailed above.[1] [2]

Relationship to other physical constants[edit]

As mentioned above, the electron mass is used to calculate[citation needed] the Avogadro constant NA:

Hence it is also related to the atomic mass constant mu:

where Mu is molar mass constant (defined in SI) and Ar(e) is a directly measured quantity, the relative mass of electron.

Note that mu is defined in terms of Ar(e), and not the other way round, and so the name "electron mass in atomic mass units" for Ar(e) involves a circular definition (at least in terms of practical measurements).

The electron relative atomic mass also enters into the calculation of all other relative atomic masses. By convention, relative atomic masses are quoted for neutral atoms, but the actual measurements are made on positive ions, either in a mass spectrometer or a Penning trap. Hence the mass of the electrons must be added back on to the measured values before tabulation. A correction must also be made for the mass equivalent of the binding energy Eb. Taking the simplest case of complete ionization of all electrons, for a nuclide X of atomic number Z,[1]

As relative atomic masses are measured as ratios of masses, the corrections must be applied to both ions: fortunately, the uncertainties in the corrections are negligible, as illustrated below for hydrogen 1 and oxygen 16.

  1H 16O
relative atomic mass of the XZ+ ion 1.007 276 466 77(10) 15.990 528 174 45(18)
relative atomic mass of the Z electrons 0.000 548 579 909 43(23) 0.004 388 639 2754(18)
correction for the binding energy −0.000 000 014 5985 −0.000 002 194 1559
relative atomic mass of the neutral atom 1.007 825 032 07(10) 15.994 914 619 57(18)

The principle can be shown by the determination of the electron relative atomic mass by Farnham et al. at the University of Washington (1995).[3] It involves the measurement of the frequencies of the cyclotron radiation emitted by electrons and by 12C6+ ions in a Penning trap. The ratio of the two frequencies is equal to six times the inverse ratio of the masses of the two particles (the heavier the particle, the lower the frequency of the cyclotron radiation; the higher the charge on the particle, the higher the frequency):

As the relative atomic mass of 12C6+ ions is very nearly 12, the ratio of frequencies can be used to calculate a first approximation to Ar(e), 5.486 303 7178×10−4. This approximate value is then used to calculate a first approximation to Ar(12C6+), knowing that Eb(12C)/muc2 (from the sum of the six ionization energies of carbon) is 1.105 8674×10−6: Ar(12C6+) ≈ 11.996 708 723 6367. This value is then used to calculate a new approximation to Ar(e), and the process repeated until the values no longer vary (given the relative uncertainty of the measurement, 2.1×10−9): this happens by the fourth cycle of iterations for these results, giving Ar(e) = 5.485 799 111(12)×10−4 for these data.

References[edit]

  1. ^ a b c d CODATA 2014
  2. ^ a b The NIST reference on Constants, Units, and Uncertainty, National Institute of Standards and Technology 
  3. ^ Farnham, D. L.; Van Dyck, Jr., R. S.; Schwinberg, P. B. (1995), "Determination of the Electron's Atomic Mass and the Proton/Electron Mass Ratio via Penning Trap Mass Spectroscopy", Phys. Rev. Lett., 75 (20): 3598–3601, Bibcode:1995PhRvL..75.3598F, doi:10.1103/PhysRevLett.75.3598