Flame ionization detector
A flame ionization detector (FID) is a scientific instrument that measures the concentration of organic species in a gas stream. It is frequently used as a detector in gas chromatography. Standalone FIDs can also be used in applications such as landfill gas monitoring, fugitive emissions monitoring and internal combustion engine emissions measurement in stationary or portable instruments.
The first flame ionization detectors were developed simultaneously and independently in 1957 by scientists working for the Commonwealth Scientific and Industrial Research Organisation (CSIRO) in Melbourne, Australia. and at the University of Pretoria in Pretoria, South Africa.
In 1959, Perkin Elmer Corp. included a flame ionization detector in its Vapor Fractometer
The operation of the FID is based on the detection of ions formed during combustion of organic compounds in a hydrogen flame. The generation of these ions is proportional to the concentration of organic species in the sample gas stream. Hydrocarbons generally have molar response factors that are equal to number of carbon atoms in their molecule, while oxygenates and other species that contain heteroatoms tend to have a lower response factor. Carbon monoxide and carbon dioxide are not detectable by FID.
Advantages and disadvantages
Flame ionization detectors are used very widely in gas chromatography because of a number of advantages.
- Cost: Flame ionization detectors are relatively inexpensive to acquire and operate.
- Low maintenance requirements: Apart from cleaning or replacing the FID jet, these detectors require no maintenance.
- Rugged construction: FIDs are relatively resistant to misuse.
- Linearity and detection ranges: FIDs can measure organic substance concentration at very low and very high levels, having a linear response of 10^6.
Flame ionization detectors cannot detect inorganic substances. In some systems, CO and CO2 can be detected in the FID using a methanizer, which is a bed of Ni catalyst that reduces CO and CO2 to methane, which can be in turn detected by the FID.
Methanizers, however, are limited to just carbon monoxide and dioxide- there are many more compounds that an FID cannot quantify well or at all. All of the remaining compounds that contain carbon can be detected and quantified by integrating a Polyarc reactor. The Polyarc reactor converts all carbon containing species to methane molecules right before reaching the detector through a two-step catalytic reaction, allowing things like CO, CO2, alcohols, acids, and other compounds that elicit a low signal from the detector to be quantified. A Polyarc reactor also removes the need to use internal standards and calibration curves because every compound's response factor becomes unity. Complex mixtures with unique compounds to which no commercial standards are available can also be accurately quantified because no standards are needed.
Another important disadvantage is that the FID flame oxidizes all compounds that pass through it; all hydrocarbons and oxygenates are oxidized to carbon dioxide and water and other heteroatoms are oxidized according to thermodynamics. For this reason, FIDs tend to be the last in a detector train and also cannot be used for preparatory work.
In order to detect these ions, two electrodes are used to provide a potential difference. The positive electrode doubles as the nozzle head where the flame is produced. The other, negative electrode is positioned above the flame. When first designed, the negative electrode was either tear-drop shaped or angular piece of platinum. Today, the design has been modified into a tubular electrode, commonly referred to as a collector plate. The ions thus are attracted to the collector plate and upon hitting the plate, induce a current. This current is measured with a high-impedance picoammeter and fed into an integrator. The manner in which the final data is displayed is based on the computer and software. In general, a graph is displayed that has time on the x-axis and total ion on the y-axis.
The current measured corresponds roughly to the proportion of reduced carbon atoms in the flame. Specifically how the ions are produced is not necessarily understood, but the response of the detector is determined by the number of carbon atoms (ions) hitting the detector per unit time. This makes the detector sensitive to the mass rather than the concentration, which is useful because the response of the detector is not greatly affected by changes in the carrier gas flow rate.
Description of a generic detector
The design of the flame ionization detector varies from manufacturer to manufacturer, but the principles are the same. Most commonly, the FID is attached to a gas chromatography system.
The eluent exits the GC column (A) and enters the FID detector’s oven (B). The oven is needed to make sure that as soon as the eluent exits the column, it does not come out of the gaseous phase and deposit on the interface between the column and FID. This deposition would result in loss of eluent and errors in detection. As the eluent travels up the FID, it is first mixed with the hydrogen fuel (C) and then with the oxidant (D). The eluent/fuel/oxidant mixture continues to travel up to the nozzle head where a positive bias voltage exists (E). This positive bias helps to repel the reduced carbon ions created by the flame (F) pyrolyzing the eluent. The ions are repelled up toward the collector plates (G) which are connected to a very sensitive ammeter, which detects the ions hitting the plates, then feeds that signal (H) to an amplifier, integrator, and display system. The products of the flame are finally vented out of the detector through the exhaust port (J).
- Flame detector
- Thermal Conductivity Detector
- Gas Chromatography
- Active fire protection
- Photoionization detector
- Photoelectric flame photometer
- "Flame Ionisation Detector Principles". www.cambustion.com. Retrieved 3 December 2014.
- Scott, R. P. W., 1957, Vapour Phase Chromatography, Ed. D. H. Desty (London: Butterworths), p. 131.
- McWilliam, I. G.; Dewar, R. A. "Flame Ionization Detector for Gas Chromatography". Nature 181 (4611): 760. Bibcode:1958Natur.181..760M. doi:10.1038/181760a0.
- Morgan, D J (1961). "Construction and operation of a simple flame-ionization detector for gas chromatography". J. Sci. Instrum. 38 (12): 501. Bibcode:1961JScI...38..501M. doi:10.1088/0950-7671/38/12/321. Retrieved 2009-03-18.
- Harley, J.; Nel, W.; Pretorius, V. (January 18, 1958). "Flame Ionization Detector for Gas Chromatography". Nature. doi:10.1038/1781244b0.
- "Timeline". Perkinelmer.com. Retrieved 12 Dec 2014.
- Skoog, Douglas A., F. James Holler, & Stanley R. Crouch. Principles of Instrumental Analysis. 6th Edition. United States: Thomson Brooks/Cole, 2007.
- Halász, I. & W. Schneider. “Quantitative Gas Chromatographic Analysis of Hydrocarbons with Capillary Column and Flame Ionization Detector.” Analytical Chemistry. 33, 8 (July 1961): 978-982
- G.H. JEFFERY, J.BASSET, J.MENDHAM, R.C.DENNEY, "VOGEL'S TEXTBOOK OF QUANTITATIVE CHEMICAL ANALYSIS."