A Gley (Russian: gley is dialectical word глей, literally "clay") is a wetland soil (hydric soil) that, unless drained, is saturated with groundwater for long enough periods to develop a characteristic gleyic colour pattern. This pattern is essentially made up of reddish, brownish or yellowish colours at surfaces of soil particles (peds) and/or in the upper soil horizons mixed with greyish/blueish colours inside the peds and/or deeper in the soil. Gleysols are also known as Gleyzems and meadow soils (Russia), Aqu-suborders of Entisols, Inceptisols and Mollisols (USDA soil taxonomy), or as groundwater soils and hydro-morphic soils.
Gleysols occur on wide range of unconsolidated materials, mainly fluvial, marine and lacustrine sediments of Pleistocene or Holocene age, with basic to acidic mineralogy. They are found in depression areas and low landscape positions with shallow groundwater.
Wetness is the main limitation of virgin Gleysols; these are covered with natural swamp vegetation and lie idle or are used for extensive grazing. Artificially drained Gleysols are used for arable cropping, dairy farming and horticulture. Gleysols in the tropics and subtropics are widely planted to rice.
Gleysols occupy an estimated 720 million hectares worldwide. They are azonal soils and occur in nearly all climates. The largest extent of Gleysols is in northern Russia, Siberia, Canada, Alaska, China and Bangladesh. An estimated 200 million hectares of Gleysols are found in the tropics, mainly in the Amazon region, equatorial Africa and the coastal swamps of Southeast Asia.
Gley soils are grouped under Gleysols in the FAO World Reference Base for Soil Resources. They exhibit a greenish-blue-grey soil color due to anoxic wetland conditions. On exposure, as the iron in the soil oxidizes colors are transformed to a mottled pattern of reddish, yellow or orange patches. During soil formation (gleying), the oxygen supply in the soil profile is restricted due to soil moisture at saturation. Anaerobic micro-organisms support cellular respiration by using alternatives to free oxygen as electron acceptors to support cellular respiration. Where Anaerobic organisms reduce ferric oxide to ferrous oxide, the reduced mineral compounds produce the gley soil typical color. Green rust, a layered double hydroxide (LDH) of Fe(II) and Fe(III) can be found as the mineral fougerite in gley soils.
Gley soils may be sticky and hard to work, especially where the gleying is caused by surface water, held up on a slowly permeable layer. However, some ground-water gley soils have permeable lower horizons, including some sands, for example in hollows within sand dune systems, known as slacks, and in some alluvial situations.
Groundwater gley soils develop where drainage is poor because the water table (phreatic surface) is high, whilst Surface-water gleying occurs when precipitation inputs at the surface do not drain freely through the ground. A reducing environment exists in the saturated layers, which become mottled greyish-blue or brown because of the content of ferrous iron and organic matter. The presence of reddish or orange mottles indicates localised re-oxidation of ferrous salts in the soil matrix, and is often associated with root channels, animal burrows or cracking of the soil material during dry spells.
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- Pedology (soil study)
- Soil classification
- Anaerobic respiration
- Fougerite, the natural form of green rust
- Blue goo
- Trolard F., Bourrié G., Abdelmoula M., Refait P. and Feder F. 2007: Fougerite, a new mineral of the pyroaurite-iowaite group: description and crystal structure. Clays and Clay Minerals, vol. 55, no. 3, p. 323-334; doi:10.1346/CCMN.2007.0550308.
- Génin J.-M. R., Aïssa R., Géhin A., Abdelmoula M., Benali O., Ernstsen V., Ona-Nguema G., Upadhyay Ch. and Ruby Ch. 2005: Fougerite and FeII-III hydroxycarbonate green rust; ordering, deprotonation and/or cation substitution; structure of hydrotalcite-like compounds and mythic ferrosic hydroxide Fe(OH)2+x. Solid State Sciences, vol. 7., no. 5, p. 545-572. doi:10.1016/j.solidstatesciences.2005.02.001.