3D model (JSmol)
|Molar mass||438.1850 g mol−1|
|Density||2.044 g cm−3|
|Detonation velocity||9.38 km s−1|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
Hexanitrohexaazaisowurtzitane //, also called HNIW and CL-20, is a nitroamine explosive with the formula C6H6N12O12. The structure of CL-20 was first proposed in 1979 by Dalian Institute of Chemical Physics. In 1980s, CL-20 was developed by the China Lake facility, primarily to be used in propellants. It has a better oxidizer-to-fuel ratio than conventional HMX or RDX. It releases 20% more energy than traditional HMX-based propellants, and is widely superior to conventional high-energy propellants and explosives.
Industrial production of CL-20 was achieved in China in 2011, and it was soon fielded in propellant of solid rockets. While most development of CL-20 has been fielded by the Thiokol Corporation, the US Navy (through ONR) has also been interested in CL-20 for use in rocket propellants, such as for missiles, as it has lower observability characteristics such as less visible smoke.
CL-20 has not yet been fielded in any production weapons system, but is undergoing testing for stability, production capabilities, and other weapons characteristics.
First, benzylamine (1) is condensed with glyoxal (2) under acidic and dehydrating conditions to yield the first intermediate compound.(3). Four benzyl groups selectively undergo hydrogenolysis using palladium on carbon and hydrogen. The amino groups are then acetylated during the same step using acetic anhydride as the solvent. (4). Finally, compound 4 is reacted with nitronium tetrafluoroborate and nitrosonium tetrafluoroborate, resulting in HNIW.
Cocrystal product with HMX
In August 2012, Onas Bolton et al. published results showing that a cocrystal of 2 parts CL-20 and 1 part HMX had similar safety properties to HMX, but with a greater firing power closer to CL-20. 
Cocrystal product with TNT
In August 2011, Adam Matzger and Onas Bolton published results showing that a cocrystal of CL-20 and TNT had twice the stability of CL-20—safe enough to transport, but when heated to 136 C the cocrystal may separate into liquid TNT and a crystal form of CL-20 with structural defects that is somewhat less stable than CL-20.
- 4,4’-Dinitro-3,3’-diazenofuroxan (DDF)
- Heptanitrocubane (HNC)
- Octanitrocubane (ONC)
- Iceane (Wurtzitane)
- RE factor
- 王征, 和霄雯 (2016-04-19). "北理工的爆轰速度 中国力量的可靠基石". 北京理工大学新闻网.
- 黎轩平 (2016-04-23). "“我们要在宇宙空间占一个位置！”". 北京理工大学新闻网.
- Yirka, Bob (9 September 2011). "University chemists devise means to stabilize explosive CL-20". Physorg.com. Retrieved 8 July 2012.
- Nair, U. R.; Sivabalan, R.; Gore, G. M.; Geetha, M.; Asthana, S. N.; Singh, H. (2005). "Hexanitrohexaazaisowurtzitane (CL-20) and CL-20-based formulations (review)". Combust. Explos. Shock Waves. 41 (2): 121–132. doi:10.1007/s10573-005-0014-2.
- High Power Explosive with Good Sensitivity: A 2:1 Cocrystal of CL-20:HMX, Crystal Growth & Design (American Chemical Society), 2012, 12 (9), pp 4311–4314, DOI: 10.1021/cg3010882, Publication Date (Web): August 7, 2012, accessed 7 September 2012
- Powerful new explosive could replace today's state-of-the-art military explosive, SpaceWar.com, 6 September 2012, accessed 7 September 2012
- Angewandte Chemie International Edition
- Things I Won’t Work With: Hexanitrohexaazaisowurtzitane
- Bolton, Onas; Adam J. Matzger (September 12, 2011). "Improved Stability and Smart-Material Functionality Realized in an Energetic Cocrystal". Angewandte Chemie. 123 (38): 9122–9125. doi:10.1002/ange.201104164. Retrieved 8 July 2012.
- Lowe, Derek (11 November 2011) "Things I won't work with: Hexanitrohexaazaisowurtzitane"