Hexamine fuel tablet
|This article needs additional citations for verification. (July 2007)|
A hexamine fuel tablet is a form of solid fuel in tablet form. The tablets burn smokelessly, have a high energy density, do not liquefy while burning and leave no ashes. Invented in Murrhardt, Germany, in 1936, the main component is hexamine, which was discovered by Aleksandr Butlerov in 1859. Some fuel tablets use 1,3,5-trioxane as another ingredient.
A number of alternative names are in use, including heat tablet and Esbit. Esbit is a genericized trademark as it is used to refer to similar products made by other companies.
The tablets are used for cooking by campers, the military and relief organizations. They are often used with disposable metal stoves that are included with field ration packs. Backpackers concerned with ultra light gear tend to buy or make their own much lighter stove. An Esbit beverage-can stove can be made by cutting off the bottom of an aluminum soft drink can, and turning it upside down to support the fuel tablet. A pot can be supported above this with a circle of chicken wire or metal tent pegs. The burning tablets are sensitive to wind, so a simple windscreen should be used, such as a strip of aluminum foil curved in a circle around the pot and stove. If necessary, the fuel tablet can be placed on a rock or on the dirt, with a pot supported above it by rocks, but this is less than ideal.
Another common use is to provide a relatively safe (see disadvantages below) heat source for model steam engines, such as those manufactured by Wilesco and Mamod, and other external combustion engines such as Stirling engines and pop pop boats.
Advantages and disadvantages
Hexamine is prepared by the reaction of formaldehyde and ammonia. In an acid environment hexamine is converted to toxic formaldehyde, which is their main hazard for toxicity by ingestion.
Fuel tablets are simple, ultra-lightweight compared to other stove options, and compact; the entire stove system and fuel can be stored inside a small 850ml cooking pot. As with trioxane, hexamine has an almost infinite shelf life if stored properly.[how?] However, the heat given off cannot be easily adjusted, so water can be boiled, but cooking requiring simmering is more difficult. Tablets are a powerful stove fuel (30.0 MJ/kg), and are sensitive to wind and dampness. Fuel tablets are expensive - but cookers next to free, unlike gas cookers - and are not as widely available compared to alternatives such as alcohol or petrol.
Esbit's Material Safety Data Sheet states combustion can create formaldehyde, ammonia, nitrogen oxide, hydrogen cyanide and ingestion may cause nausea, vomiting, gastrointestinal disturbances, and kidney damage.  When burned, the chemical oxidation of the fuel yields noxious fumes, requiring foods being cooked to be contained in a receptacle such as a pot or pan, and burned tablets will leave a sticky dark residue on the bottom of pots. If they are stored or used under damp conditions then they can break up while burning and shed burning fragments, although this claim is hard to verify or reproduce.
Hexamine is a precursor for the simplest synthesis of the chemical explosive RDX; in many areas its availability is tightly regulated due to this.