Hexaperchloratoaluminate
The hexaperchloratoaluminate ion is a triple negative complex of perchlorate with aluminium. It is related to hexanitratoaluminate and tetraperchloratoaluminate all of which are highly oxidising energetic materials.[1]
Solid materials that have been produced in this series of hexaperchloratoaluminate salts are lithium hexaperchloratoaluminate, ammoniumhexaperchloratoaluminate, tetramethylammonium hexaperchloratoaluminate, and trinitroniumhexaperchloratoaluminate .[1]
Preparation[edit]
The hexaperchloratoaluminates can be prepared in liquid sulfur dioxide at −10 °C from aluminium trichloride combining with various perchlorates.[1]
- 3 NO2ClO4 + 3 (NH4)ClO4 + AlCl3 → 3 NO2Cl + (NH4)3Al(ClO4)6[1]
- 6 NO2ClO4 + AlCl3 → 3 NO2Cl + (NO2)3Al(ClO4)6[1]
Aluminium nitrate can be heated at 125 °C with nitrosonium or nitronium perchlorate to yield hexaperchloratoaluminates. [1]
- 10–14 NOClO4 + Al(NO3)3 → 3 NO2Cl + (NO2)3Al(ClO4)6[1]
- 6–10 NO2ClO4 + Al(NO3)3 → 3 NO2Cl + (NO2)3Al(ClO4)6[1]
- 3 NO2ClO4 + 3 K3ClO4 + AlCl3 → 3 NO2Cl + K3Al(ClO4)6[1]
Potassium hexaperchloratoaluminate may or may not exist.[1] Hydrazinium hexaperchloratoaluminate can only be made in an impure form with
- 3 NO2ClO4 + 3 (NH2H5)ClO4 + AlCl3 → 3 NO2Cl + (NH2H5)3Al(ClO4)6[1]
Guanidinium hexaperchloratoaluminate can be made via:
- 3 NO2ClO4 + 3 C(NH2)3ClO4 + AlCl3 → 3 NO2Cl + (C(NH2)3)3Al(ClO4)6[1]
References[edit]
| HClO4 | He | ||||||||||||||||
| LiClO4 | Be(ClO4)2 | B(ClO 4)− 4 B(ClO4)3 |
ROClO3 | N(ClO4)3 NH4ClO4 NOClO4 |
H3OClO4 | FClO4 | Ne | ||||||||||
| NaClO4 | Mg(ClO4)2 | Al(ClO4)3 Al(ClO 4)− 4 Al(ClO 4)2− 5 Al(ClO 4)3− 6 |
Si | P | S | ClO− 4 ClOClO3 Cl2O7 |
Ar | ||||||||||
| KClO4 | Ca(ClO4)2 | Sc(ClO4)3 | Ti(ClO4)4 | VO(ClO4)3 VO2(ClO4) |
Cr(ClO4)3 | Mn(ClO4)2 | Fe(ClO4)2 | Co(ClO4)2, Co(ClO4)3 |
Ni(ClO4)2 | Cu(ClO4)2 | Zn(ClO4)2 | Ga(ClO4)3 | Ge | As | Se | Br | Kr |
| RbClO4 | Sr(ClO4)2 | Y(ClO4)3 | Zr(ClO4)4 | Nb(ClO4)5 | Mo | Tc | Ru | Rh(ClO4)3 | Pd(ClO4)2 | AgClO4 | Cd(ClO4)2 | In(ClO4)3 | Sn(ClO4)4 | Sb | TeO(ClO4)2 | I | Xe |
| CsClO4 | Ba(ClO4)2 | Hf(ClO4)4 | Ta(ClO4)5 | W | Re | Os | Ir | Pt | Au | Hg2(ClO4)2, Hg(ClO4)2 |
Tl(ClO4), Tl(ClO4)3 |
Pb(ClO4)2 | Bi(ClO4)3 | Po | At | Rn | |
| FrClO4 | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
| ↓ | |||||||||||||||||
| La | Ce(ClO4)x | Pr(ClO4)3 | Nd(ClO4)3 | Pm | Sm(ClO4)3 | Eu(ClO4)3 | Gd(ClO4)3 | Tb(ClO4)3 | Dy(ClO4)3 | Ho(ClO4)3 | Er(ClO4)3 | Tm(ClO4)3 | Yb(ClO4)3 | Lu(ClO4)3 | |||
| Ac | Th(ClO4)4 | Pa | UO2(ClO4)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||