Hydrogen production

From Wikipedia, the free encyclopedia
Jump to navigation Jump to search

Hydrogen production is the family of industrial methods for generating hydrogen gas. As of 2018, the majority of hydrogen (∼95%) is produced from fossil fuels by steam reforming of natural gas, partial oxidation of methane, and coal gasification.[1] Other methods of hydrogen production include biomass gasification and electrolysis of water.

The production of hydrogen plays a key role in any industrialized society, since hydrogen is required for many essential chemical processes.[2] As of 2019, roughly 70 million tons of hydrogen are produced annually worldwide for various uses, such as, oil refining, and in the production of ammonia (Haber process) and methanol (reduction of carbon monoxide), and also as a fuel in transportation. The hydrogen generation market is expected to be valued at US$115.25 billion in 2017.[3]

Methods of hydrogen production[edit]

There are four main sources for the commercial production of hydrogen: natural gas, oil, coal, and electrolysis; which account for 48%, 30%, 18% and 4% of the world's hydrogen production respectively.[4] Fossil fuels are the dominant source of industrial hydrogen.[5] Carbon dioxide can be separated from natural gas with a 70-85% efficiency for hydrogen production and from other hydrocarbons to varying degrees of efficiency.[6] Specifically, bulk hydrogen is usually produced by the steam reforming of methane or natural gas.[7]

Steam reforming[edit]

Steam reforming is a hydrogen production process from natural gas. This method is currently the cheapest source of hydrogen. The process consists of heating the gas to between 700-1100 °C in the presence of steam and a nickel catalyst. The resulting endothermic reaction breaks up the methane molecules and forms carbon monoxide CO and hydrogen H2. The carbon monoxide gas can then be passed with steam over iron oxide or other oxides and undergo a water gas shift reaction to obtain further quantities of H2. The downside to this process is that its major byproducts are CO, CO2 and other greenhouse gases.[4] Depending on the quality of the feedstock (natural gas, rich gases, naphtha, etc.), one ton of hydrogen produced will also produce 9 to 12 tons of CO2.[8]

For this process high temperature (700–1100 °C) steam (H2O) reacts with methane (CH4) in an endothermic reaction to yield syngas.[9]

CH4 + H2O → CO + 3 H2

In a second stage, additional hydrogen is generated through the lower-temperature, exothermic, water gas shift reaction, performed at about 360 °C:

CO + H2O → CO2 + H2

Essentially, the oxygen (O) atom is stripped from the additional water (steam) to oxidize CO to CO2. This oxidation also provides energy to maintain the reaction. Additional heat required to drive the process is generally supplied by burning some portion of the methane.

Other production methods from fossil fuels[edit]

Partial oxidation[edit]

Hydrogen production from natural gas or other hydrocarbons is achieved by partial oxidation. A fuel-air or fuel-oxygen mixture is partially combusted resulting in a hydrogen rich syngas. Hydrogen and carbon monoxide are obtained via the water-gas shift reaction.[4] Carbon dioxide can be co-fed to lower the hydrogen to carbon monoxide ratio.

The partial oxidation reaction occurs when a substoichiometric fuel-air mixture or fuel-oxygen is partially combusted in a reformer or partial oxidation reactor. A distinction is made between thermal partial oxidation (TPOX) and catalytic partial oxidation (CPOX). The chemical reaction takes the general form:

CnHm + n/2 O2n CO + m/2 H2

Idealized examples for heating oil and coal, assuming compositions C12H24 and C24H12 respectively, are as follows:

C12H24 + 6 O2 → 12 CO + 12 H2
C24H12 + 12 O2 → 24 CO + 6 H2

Plasma reforming[edit]

The Kværner-process or Kvaerner carbon black & hydrogen process (CB&H)[10] is a plasma reforming method, developed in the 1980s by a Norwegian company of the same name, for the production of hydrogen and carbon black from liquid hydrocarbons (CnHm). Of the available energy of the feed, approximately 48% is contained in the hydrogen, 40% is contained in activated carbon and 10% in superheated steam.[11] CO2 is not produced in the process.

A variation of this process is presented in 2009 using plasma arc waste disposal technology for the production of hydrogen, heat and carbon from methane and natural gas in a plasma converter[12]


For the production of hydrogen from coal, coal gasification is used. The process of coal gasification uses steam and a carefully controlled concentration of gases to break molecular bonds in coal and form a gaseous mix of hydrogen and carbon monoxide.[13] This source of hydrogen is advantageous since its main product is coal-derived gas which can be used for fuel. The gas obtained from coal gasification can later be used to produce electricity more efficiently and allow a better capture of greenhouse gases than the traditional burning of coal.

Another method for conversion is low temperature and high temperature coal carbonization.[14]

Petroleum coke[edit]

Similarly to coal, petroleum coke can also be converted in hydrogen rich syngas, via coal gasification. The syngas in this case consists mainly of hydrogen, carbon monoxide and H2S, depending on the sulfur content of the coke feed. Gasification is an attractive option for producing hydrogen from almost any carbon source, while providing attractive hydrogen utilization alternatives through process integration.[15]

Natural occurrence[edit]

Deposits of hydrogen arre rare on Earth. As of 2019, there is only one known natural hydrogen gas deposit in the world, and it has been discovered in Mali.[16]

From water[edit]

Methods to produce hydrogen without the use of fossil fuels involve the process of water splitting, or splitting the water molecule H2O into its components oxygen and hydrogen. This conversion can be accomplished in several ways, but the technology remains aspirational and economically uncompetitive.


Around 8 GW of electrolysis capacity is installed worldwide, accounting for around 4% of global hydrogen production.

Electrolysis consists of using electricity to split water into hydrogen and oxygen. Electrolysis of water is 70-80% efficient (a 20-30% conversion loss)[17][18] while steam reforming of natural gas has a thermal efficiency between 70-85%.[19] The (electrical) efficiency of electrolysis is expected to reach 82-86%[20] before 2030, while also maintaining durability as progress in this area continues at a pace.[21] Water electrolysis can operate between 50-80 °C, while steam methane reforming requires temperatures between 700-1100 °C.[22] The difference between the two methods is the primary energy used; either electricity (for electrolysis) or natural gas (for steam methane reforming). Due to their use of water, a readily available resource, electrolysis and similar water-splitting methods have attracted the interest of the scientific community. With the objective of reducing the cost of hydrogen production, renewable sources of energy have been targeted to allow electrolysis.[13] There are three main types of cells, solid oxide electrolyser cells (SOECs), polymer electrolyte membrane cells (PEM) and alkaline electrolysis cells (AECs).[23] SOECs operate at high temperatures, typically around 800 °C. At these high temperatures a significant amount of the energy required can be provided as thermal energy (heat), and as such is termed High temperature electrolysis. The heat energy can be provided from a number of different sources, including waste industrial heat, nuclear power stations or concentrated solar thermal plants. This has the potential to reduce the overall cost of the hydrogen produced by reducing the amount of electrical energy required for electrolysis.[24][25][26][27] PEM electrolysis cells typically operate below 100 °C and are becoming increasingly available commercially.[24] These cells have the advantage of being comparatively simple and can be designed to accept widely varying voltage inputs which makes them ideal for use with renewable sources of energy such as solar PV.[28] AECs optimally operate at high concentrations electrolyte (KOH or potassium carbonate) and at high temperatures, often near 200 °C.

Industrial output and efficiency[edit]

Efficiency of modern hydrogen generators is measured by energy consumed per standard volume of hydrogen (MJ/m3), assuming standard temperature and pressure of the H2. The lower the energy used by a generator, the higher would be its efficiency; a 100%-efficient electrolyser would consume 39.4 kilowatt-hours per kilogram (142 MJ/kg) of hydrogen,[29] 12,749 joules per litre (12.75 MJ/m3). Practical electrolysis (using a rotating electrolyser at 15 bar pressure) may consume 50 kilowatt-hours per kilogram (180 MJ/kg), and a further 15 kilowatt-hours (54 MJ) if the hydrogen is compressed for use in hydrogen cars.[30]

Electrolyser vendors provide efficiencies based on enthalpy. To assess the claimed efficiency of an electrolyser it is important to establish how it was defined by the vendor (i.e. what enthalpy value, what current density, etc.).

There are two main technologies available on the market, alkaline and proton exchange membrane (PEM) electrolysers. Traditionally, alkaline electrolysers are cheaper in terms of investment (they generally use nickel catalysts), but less efficient; PEM electrolysers, conversely, are more expensive (they generally use expensive platinum-group metal catalysts) but are more efficient and can operate at higher current densities, and can therefore be possibly cheaper if the hydrogen production is large enough.

Conventional alkaline electrolysis has an efficiency of about 70%,[31] however thyssenkrupp have recently developed an advanced alkaline water electrolyser with an efficiency of 82%.[32] Accounting for the use of the higher heat value (because inefficiency via heat can be redirected back into the system to create the steam required by the catalyst), average working efficiencies for PEM electrolysis are around 80%, or 82% using the most modern alkaline electrolysers.[33] PEM efficiency is expected to increase to approximately 86%[34] before 2030. Theoretical efficiency for PEM electrolysers are predicted up to 94%.[35]

H2 production cost ($-gge untaxed) at varying natural gas prices

Considering the industrial production of hydrogen, and using current best processes for water electrolysis (PEM or alkaline electrolysis) which have an effective electrical efficiency of 70-82%,[36][37][38] producing 1 kg of hydrogen (which has a specific energy of 143 MJ/kg or about 40 kWh/kg) requires 50–55 kWh of electricity. At an electricity cost of $0.06/kWh, as set out in the Department of Energy hydrogen production targets for 2015,[39] the hydrogen cost is $3/kg. With the range of natural gas prices from 2016 as shown in the graph (Hydrogen Production Tech Team Roadmap, November 2017) putting the cost of SMR hydrogen at between $1.20 and $1.50, the cost price of hydrogen via electrolysis is still over double 2015 DOE hydrogen target prices. The US DOE target price for hydrogen in 2020 is $2.30/kg, requiring an electricity cost of $0.037/kWh, which is achievable given recent PPA tenders[40] for wind and solar in many regions. This puts the $4/gge H2 dispensed objective well within reach, and close to a slightly elevated natural gas production cost for SMR.

In many cases, the advantage of electrolysis over SMR hydrogen is that the hydrogen can be produced on-site, meaning that the costly process of delivery via truck or pipeline is avoided.

In other parts of the world, steam methane reforming is between $1–3/kg on average. This makes production of hydrogen via electrolysis cost competitive in many regions already, as outlined by Nel Hydrogen[41] and others, including an article by the IEA[42] examining the conditions which could lead to a competitive advantage for electrolysis.

Chemically assisted electrolysis[edit]

In addition to reduce the voltage required for electrolysis via the increasing of the temperature of the electrolysis cell it is also possible to electrochemically consume the oxygen produced in an electrolyser by introducing a fuel (such as carbon/coal,[43] methanol,[44][45] ethanol,[46] formic acid,[47] glycerol,[47] etc.) into the oxygen side of the reactor. This reduces the required electrical energy and has the potential to reduce the cost of hydrogen to less than 40~60% with the remaining energy provided in this manner.[48] In addition, carbon/hydrocarbon assisted water electrolysis (CAWE) has the potential to offer a less energy intensive, cleaner method of using chemical energy in various sources of carbon, such as low-rank and high sulfur coals, biomass, alcohols and methane (Natural Gas), where pure CO2 produced can be easily sequestered without the need for separation.[49][50]


Nuclear radiation can break water bonds through radiolysis.[51][52] In the Mponeng gold mine, South Africa, researchers found in a naturally high radiation zone a community dominated by a new phylotype of Desulfotomaculum, feeding on primarily radiolytically produced hydrogen.[53] Spent nuclear fuel is also being looked at as a potential source of hydrogen.


Water spontaneously dissociates at around 2500 °C, but this thermolysis occurs at temperatures too high for usual process piping and equipment. Catalysts are required to reduce the dissociation temperature.

Thermochemical cycle[edit]

Thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components.[54] The term cycle is used because aside from water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled. If electricity is partially used as an input, the resulting thermochemical cycle is defined as a hybrid one.

The sulfur-iodine cycle (S-I cycle) is a thermochemical cycle processes which generates hydrogen from water with an efficiency of approximately 50%. The sulfur and iodine used in the process are recovered and reused, and not consumed by the process. The cycle can be performed with any source of very high temperatures, approximately 950 °C, such as by Concentrating solar power systems (CSP) and is regarded as being well suited to the production of hydrogen by high-temperature nuclear reactors,[55] and as such, is being studied in the High-temperature engineering test reactor in Japan.[56][57][58][59] There are other hybrid cycles that use both high temperatures and some electricity, such as the Copper–chlorine cycle, it is classified as a hybrid thermochemical cycle because it uses an electrochemical reaction in one of the reaction steps, it operates at 530 °C and has an efficiency of 43 percent.[60]

Ferrosilicon method[edit]

Ferrosilicon is used by the military to quickly produce hydrogen for balloons. The chemical reaction uses sodium hydroxide, ferrosilicon, and water. The generator is small enough to fit a truck and requires only a small amount of electric power, the materials are stable and not combustible, and they do not generate hydrogen until mixed.[61] The method has been in use since World War I. A heavy steel pressure vessel is filled with sodium hydroxide and ferrosilicon, closed, and a controlled amount of water is added; the dissolving of the hydroxide heats the mixture to about 93 °C and starts the reaction; sodium silicate, hydrogen and steam are produced.[62]

Photobiological water splitting[edit]

An algae bioreactor for hydrogen production.

Biological hydrogen can be produced in an algae bioreactor.[63] In the late 1990s it was discovered that if the algae are deprived of sulfur it will switch from the production of oxygen, i.e. normal photosynthesis, to the production of hydrogen. It seems that the production is now economically feasible by surpassing the 7–10 percent energy efficiency (the conversion of sunlight into hydrogen) barrier.[64] with a hydrogen production rate of 10-12 ml per liter culture per hour.[65]

Photocatalytic water splitting[edit]

The conversion of solar energy to hydrogen by means of water splitting process is one of the most interesting ways to achieve clean and renewable energy systems. However, if this process is assisted by photocatalysts suspended directly in water instead of using photovoltaic and an electrolytic system the reaction is in just one step, it can be made more efficient.[66][67]

Biohydrogen routes[edit]

Biomass and waste streams can in principle be converted into biohydrogen with biomass gasification, steam reforming, or biological conversion like biocatalysed electrolysis[48] or fermentative hydrogen production.[5]

Among hydrogen production methods such as steam methane reforming, thermal cracking, coal and biomass gasification and pyrolysis, electrolysis, and photolysis, biological ones are more eco-friendly and less energy intensive. In addition, a wide variety of waste and low-value materials such as agricultural biomass as renewable sources can be utilized to produce hydrogen via biochemical pathways. Nevertheless, at present hydrogen is produced mainly from fossil fuels, in particular, natural gas which are non-renewable sources. Hydrogen is not only the cleanest fuel but also widely used in a number of industries, especially fertilizer, petrochemical and food ones. This makes it logical to investigate alternative sources for hydrogen production. The main biochemical technologies to produce hydrogen are dark and photo fermentation processes. In dark fermentation, carbohydrates are converted to hydrogen by fermentative microorganisms including strict anaerobe and facultative anaerobe bacteria. A theoretical maximum of 4 mol H2/mol glucose can be produced and, besides hydrogen, sugars are converted to volatile fatty acids (VFAs) and alcohols as by-products during this process. Photo fermentative bacteria are able to generate hydrogen from VFAs. Hence, metabolites formed in dark fermentation can be used as feedstock in photo fermentation to enhance the overall yield of hydrogen.[68]

Fermentative hydrogen production[edit]

Fermentative hydrogen production is the fermentative conversion of organic substrate to biohydrogen manifested by a diverse group of bacteria using multi enzyme systems involving three steps similar to anaerobic conversion. Dark fermentation reactions do not require light energy, so they are capable of constantly producing hydrogen from organic compounds throughout the day and night. Photofermentation differs from dark fermentation because it only proceeds in the presence of light. For example, photo-fermentation with Rhodobacter sphaeroides SH2C can be employed to convert small molecular fatty acids into hydrogen.[69]

Fermentative hydrogen production can be done using direct biophotolysis by green algae, indirect biophotolysis by cyanobacteria, photo-fermentation by anaerobic photosynthetic bacteria and dark fermentation by anaerobic fermentative bacteria. For example, studies on hydrogen production using H. salinarium, an anaerobic photosynthetic bacteria, coupled to a hydrogenase donor like E. coli, are reported in literature.[70]

Enterobacter aerogenes is an outstanding hydrogen producer. It is an anaerobic facultative and mesophilic bacterium that is able to consume different sugars and in contrast to cultivation of strict anaerobes, no special operation is required to remove all oxygen from the fermenter. E. aerogenes has a short doubling time and high hydrogen productivity and evolution rate. Furthermore, hydrogen production by this bacterium is not inhibited at high hydrogen partial pressures; however, its yield is lower compared to strict anaerobes like Clostridia. A theoretical maximum of 4 mol H2/mol glucose can be produced by strict anaerobic bacteria. Facultative anaerobic bacteria such as E. aerogenes have a theoretical maximum yield of 2 mol H2/mol glucose.[71]

Biohydrogen can be produced in bioreactors that utilize feedstocks, the most common feedstock being waste streams. The process involves bacteria feeding on hydrocarbons and exhaling hydrogen and CO2. The CO2 can be sequestered successfully by several methods, leaving hydrogen gas. In 2006-2007, NanoLogix first demonstrated a prototype hydrogen bioreactor using waste as a feedstock at Welch's grape juice factory in Pennsylvania (U.S.).[72]

Enzymatic hydrogen generation[edit]

Diverse enzymatic pathways have been designed to generate hydrogen from sugars.[73]

Biocatalysed electrolysis[edit]

A microbial electrolysis cell

Besides dark fermentation, electrohydrogenesis (electrolysis using microbes) is another possibility. Using microbial fuel cells, wastewater or plants can be used to generate power. Biocatalysed electrolysis should not be confused with biological hydrogen production, as the latter only uses algae and with the latter, the algae itself generates the hydrogen instantly, where with biocatalysed electrolysis, this happens after running through the microbial fuel cell and a variety of aquatic plants[74] can be used. These include reed sweetgrass, cordgrass, rice, tomatoes, lupines and algae.[75]

Nano-galvanic aluminum-based powder developed by the U.S. Army Research Laboratory

Nanogalvanic aluminum alloy powder[edit]

An aluminum alloy powder invented by the U.S. Army Research Laboratory in 2017 was shown to be capable of producing hydrogen gas upon contact with water or any liquid containing water due to its unique nanoscale galvanic microstructure. It reportedly generates hydrogen at 100 percent of the theoretical yield without the need for any catalysts, chemicals, or externally supplied power.[76][77]

Environmental impact[edit]

Most of hydrogen is produced from fossil fuels, resulting in carbon emissions.

Hydrogen can also be produced from renewable energy sources. In this case, it is often referred to as green hydrogen. There are two practical ways of producing hydrogen from renewable energy sources. One is to use power to gas, in which electric power is used to produce hydrogen from electrolysis, and the other is to use landfill gas to produce hydrogen in a steam reformer. Hydrogen fuel, when produced by renewable sources of energy like wind or solar power, is a renewable fuel.[78]

Use of hydrogen[edit]

Hydrogen is used for the conversion of heavy petroleum fractions into lighter ones via hydrocracking. It is also used in other processes including the aromatization process, hydrodesulfurization and the production of ammonia via the Haber process.

Hydrogen may be used in fuel cells for local electricity generation or potentially as a transportation fuel.

Hydrogen is produced as a by-product of industrial chlorine production by electrolysis. Although requiring expensive technologies, hydrogen can be cooled, compressed and purified for use in other processes on site or sold to a customer via pipeline, cylinders or trucks. The discovery and development of less expensive methods of production of bulk hydrogen is relevant to the establishment of a hydrogen economy.[5]

See also[edit]


  1. ^ Liu, Ke; Song, Chunshan; Subramani, Velu, eds. (2009). Hydrogen and Syngas Production and Purification Technologies. doi:10.1002/9780470561256. ISBN 9780470561256.
  2. ^ Energy, U. S. D. o. The Impact of Increased Use of Hydrogen on Petroleum Consumption and Carbon Dioxide Emissions. 84 (Energy Information Administration, Washington, DC, 2008)
  3. ^ http://ieahydrogen.org/pdfs/Global-Outlook-and-Trends-for-Hydrogen_Dec2017_WEB.aspx
  4. ^ a b c Press, Roman J.; Santhanam, K. S. V.; Miri, Massoud J.; Bailey, Alla V.; Takacs, Gerald A. (2008). Introduction to hydrogen Technology. John Wiley & Sons. ISBN 978-0-471-77985-8.[page needed]
  5. ^ a b c Häussinger, Peter; Lohmüller, Reiner; Watson, Allan M. (2011). "Hydrogen, 1. Properties and Occurrence". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a13_297.pub2. ISBN 978-3-527-30673-2.
  6. ^ https://cleantechnica.com/2014/06/04/hydrogen-fuel-cell-vehicles-about-not-clean/[full citation needed]
  7. ^ Fossil fuel processor
  8. ^ Collodi, Guido (2010-03-11). "Hydrogen Production via Steam Reforming with CO2 Capture" (PDF). CISAP4 4th International Conference on Safety and Environment in the Process Industry. Retrieved 2015-11-28.
  9. ^ "HFCIT Hydrogen Production: Natural Gas Reforming". U.S. Department of Energy. 2008-12-15.
  10. ^ Bellona-HydrogenReport
  11. ^ https://www.hfpeurope.org/infotools/energyinfos__e/hydrogen/main03.html[permanent dead link][full citation needed]
  12. ^ "Kværner-process with plasma arc waste disposal technology". Archived from the original on 2014-03-13. Retrieved 2009-10-13.
  13. ^ a b Hordeski, M. F. Alternative fuels: the future of hydrogen. 171-199 (The Fairmont Press, inc., 2007).
  14. ^ Lee, Woon-Jae; Lee, Yong-Kuk (2001). "Internal Gas Pressure Characteristics Generated during Coal Carbonization in a Coke Oven". Energy & Fuels. 15 (3): 618–23. doi:10.1021/ef990178a.
  15. ^ Gemayel, Jimmy El; MacChi, Arturo; Hughes, Robin; Anthony, Edward John (2014). "Simulation of the integration of a bitumen upgrading facility and an IGCC process with carbon capture". Fuel. 117: 1288–97. doi:10.1016/j.fuel.2013.06.045.
  16. ^ On generating a Geological Model for Hydrogen Gas in the Southern Taoudeni Megabasin (Bourakebougou area, Mali)
  17. ^ "ITM - Hydrogen Refuelling Infrastructure - February 2017" (PDF). level-network.com. Retrieved 17 April 2018.
  18. ^ "Cost reduction and performance increase of PEM electrolysers" (PDF). fch.europa.eu. Fuel Cells and Hydrogen Joint Undertaking. Retrieved 17 April 2018.
  19. ^ "Hydrogen Production Technologies: Current State and Future Developments". hindawi.com. Retrieved 17 April 2018.
  20. ^ "Cost reduction and performance increase of PEM electrolysers" (PDF). fch.europa.eu. Fuel Cell and Hydrogen Joint Undertaking. Retrieved 17 April 2018.
  21. ^ "Report and Financial Statements 30 April 2016" (PDF). itm-power.com. Retrieved 17 April 2018.
  22. ^ "Hydrogen Production: Natural Gas Reforming". energy.gov. US Department of Energy. Retrieved 17 April 2018.
  23. ^ Badwal, Sukhvinder P.S.; Giddey, Sarbjit; Munnings, Christopher (2013). "Hydrogen production via solid electrolytic routes". Wiley Interdisciplinary Reviews: Energy and Environment. 2 (5): 473–487. doi:10.1002/wene.50.
  24. ^ a b Ogden, J.M. (1999). "Prospects for building a hydrogen energy infrastructure". Annual Review of Energy and the Environment. 24: 227–279. doi:10.1146/annurev.energy.24.1.227.
  25. ^ Hauch, Anne; Ebbesen, Sune Dalgaard; Jensen, Søren Højgaard; Mogensen, Mogens (2008). "Highly efficient high temperature electrolysis". Journal of Materials Chemistry. 18 (20): 2331–40. doi:10.1039/b718822f.
  26. ^ In the laboratory, water electrolysis can be done with a simple apparatus like a Hofmann voltameter:"Electrolysis of water and the concept of charge". Archived from the original on 2010-06-13.
  27. ^ "Nuclear power plants can produce hydrogen to fuel the 'hydrogen economy'" (Press release). American Chemical Society. March 25, 2012. Retrieved March 9, 2013.
  28. ^ Clarke, R.E.; Giddey, S.; Ciacchi, F.T.; Badwal, S.P.S.; Paul, B.; Andrews, J. (2009). "Direct coupling of an electrolyser to a solar PV system for generating hydrogen". International Journal of Hydrogen Energy. 34 (6): 2531–42. doi:10.1016/j.ijhydene.2009.01.053.
  29. ^ Luca Bertuccioli; et al. (7 February 2014). "Development of water electrolysis in the European Union" (PDF). Client Fuel Cells and Hydrogen Joint Undertaking.
  30. ^ Stensvold, Tore (26 January 2016). «Coca-Cola-oppskrift» kan gjøre hydrogen til nytt norsk industrieventyr. Teknisk Ukeblad, .
  31. ^ Stolten, Detlef (Jan 4, 2016). Hydrogen Science and Engineering: Materials, Processes, Systems and Technology. John Wiley & Sons. p. 898. ISBN 9783527674299. Retrieved 22 April 2018.
  32. ^ thyssenkrupp. "Hydrogen from water electrolysis - solutions for sustainability". https://www.thyssenkrupp-uhde-chlorine-engineers.com. Retrieved 28 July 2018. External link in |website= (help)
  33. ^ "ITM - Hydrogen Refuelling Infrastructure - February 2017" (PDF). level-network.com. Retrieved 17 April 2018.
  34. ^ "Cost reduction and performance increase of PEM electrolysers" (PDF). fch.europa.eu. Fuel Cells and Hydrogen Joint Undertaking. Retrieved 17 April 2018.
  35. ^ Bjørnar Kruse; Sondre Grinna; Cato Buch (13 February 2002). "Hydrogen—Status and Possibilities" (PDF). The Bellona Foundation. p. 20. Archived from the original on 16 September 2013.CS1 maint: unfit url (link)
  36. ^ Werner Zittel; Reinhold Wurster (1996-07-08). "Chapter 3: Production of Hydrogen. Part 4: Production from electricity by means of electrolysis". HyWeb: Knowledge - Hydrogen in the Energy Sector. Ludwig-Bölkow-Systemtechnik GmbH.
  37. ^ Bjørnar Kruse; Sondre Grinna; Cato Buch (2002-02-13). "Hydrogen—Status and Possibilities". The Bellona Foundation. Archived from the original (PDF) on 2011-07-02. Efficiency factors for PEM electrolysers up to 94% are predicted, but this is only theoretical at this time.
  38. ^ "high-rate and high efficiency 3D water electrolysis". Grid-shift.com. Archived from the original on 2012-03-22. Retrieved 2011-12-13.
  39. ^ "DOE Technical Targets for Hydrogen Production from Electrolysis". energy.gov. US Department of Energy. Retrieved 22 April 2018.
  40. ^ Deign, Jason. "Xcel Attracts 'Unprecedented' Low Prices for Solar and Wind Paired With Storage". greentechmedia.com. Wood MacKenzie. Retrieved 22 April 2018.
  41. ^ "Wide Spread Adaption of Competitive Hydrogen Solution" (PDF). nelhydrogen.com. Nel ASA. Retrieved 22 April 2018.
  42. ^ Philibert, Cédric. "Commentary: Producing industrial hydrogen from renewable energy". iea.org. International Energy Agency. Retrieved 22 April 2018.
  43. ^ Giddey, S; Kulkarni, A; Badwal, S.P.S (2015). "Low emission hydrogen generation through carbon assisted electrolysis". International Journal of Hydrogen Energy. 40 (1): 70–4. doi:10.1016/j.ijhydene.2014.11.033.
  44. ^ Uhm, Sunghyun; Jeon, Hongrae; Kim, Tae Jin; Lee, Jaeyoung (2012). "Clean hydrogen production from methanol–water solutions via power-saved electrolytic reforming process". Journal of Power Sources. 198: 218–22. doi:10.1016/j.jpowsour.2011.09.083.
  45. ^ Ju, Hyungkuk; Giddey, Sarbjit; Badwal, Sukhvinder P.S (2017). "The role of nanosized SnO2 in Pt-based electrocatalysts for hydrogen production in methanol assisted water electrolysis". Electrochimica Acta. 229: 39–47. doi:10.1016/j.electacta.2017.01.106.
  46. ^ Ju, Hyungkuk; Giddey, Sarbjit; Badwal, Sukhvinder P.S; Mulder, Roger J (2016). "Electro-catalytic conversion of ethanol in solid electrolyte cells for distributed hydrogen generation". Electrochimica Acta. 212: 744–57. doi:10.1016/j.electacta.2016.07.062.
  47. ^ a b Lamy, Claude; Devadas, Abirami; Simoes, Mario; Coutanceau, Christophe (2012). "Clean hydrogen generation through the electrocatalytic oxidation of formic acid in a Proton Exchange Membrane Electrolysis Cell (PEMEC)". Electrochimica Acta. 60: 112–20. doi:10.1016/j.electacta.2011.11.006.
  48. ^ a b Badwal, Sukhvinder P. S; Giddey, Sarbjit S; Munnings, Christopher; Bhatt, Anand I; Hollenkamp, Anthony F (2014). "Emerging electrochemical energy conversion and storage technologies". Frontiers in Chemistry. 2: 79. Bibcode:2014FrCh....2...79B. doi:10.3389/fchem.2014.00079. PMC 4174133. PMID 25309898.
  49. ^ Ju, H; Badwal, S.P.S; Giddey, S (2018). "A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production". Applied Energy. 231: 502–533. doi:10.1016/j.apenergy.2018.09.125.
  50. ^ Ju, Hyungkuk; Badwal, Sukhvinder; Giddey, Sarbjit (2018). "A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production". Applied Energy. 231: 502–533. doi:10.1016/j.apenergy.2018.09.125.
  51. ^ An Introduction to Radiation Chemistry Chapter 7
  52. ^ Nuclear Hydrogen Production Handbook Chapter 8
  53. ^ Li-Hung Lin; Pei-Ling Wang; Douglas Rumble; Johanna Lippmann-Pipke; Erik Boice; Lisa M. Pratt; Barbara Sherwood Lollar; Eoin L. Brodie; Terry C. Hazen; Gary L. Andersen; Todd Z. DeSantis; Duane P. Moser; Dave Kershaw; T. C. Onstott (2006). "Long-Term Sustainability of a High-Energy, Low-Diversity Crustal Biome". Science. 314 (5798): 479–82. Bibcode:2006Sci...314..479L. doi:10.1126/science.1127376. PMID 17053150.
  54. ^ Producing hydrogen: The Thermochemical cycles
  55. ^ IEA Energy Technology Essentials - Hydrogen Production & Distribution, April 2007
  56. ^ "HTTR High Temperature engineering Test Reactor". Httr.jaea.go.jp. Retrieved 2014-01-23.
  57. ^ https://smr.inl.gov/Document.ashx?path=DOCS%2FGCR-Int%2FNHDDELDER.pdf. Progress in Nuclear Energy Nuclear heat for hydrogen production: Coupling a very high/high temperature reactor to a hydrogen production plant. 2009
  58. ^ Status report 101 - Gas Turbine High Temperature Reactor (GTHTR300C)
  59. ^ "JAEA'S VHTR FOR HYDROGEN AND ELECTRICITY COGENERATION : GTHTR300C" (PDF). Archived from the original (PDF) on 2017-08-10. Retrieved 2013-12-04.
  60. ^ Chukwu, C., Naterer, G. F., Rosen, M. A., "Process Simulation of Nuclear-Produced Hydrogen with a Cu-Cl Cycle", 29th Conference of the Canadian Nuclear Society, Toronto, Ontario, Canada, June 1–4, 2008. "Archived copy" (PDF). Archived from the original (PDF) on 2012-02-20. Retrieved 2013-12-04.CS1 maint: archived copy as title (link)
  61. ^ Report No 40: The ferrosilicon process for the generation of hydrogen
  62. ^ Candid science: conversations with famous chemists, István Hargittai, Magdolna Hargittai, p. 261, Imperial College Press (2000) ISBN 1-86094-228-8
  63. ^ Hemschemeier, Anja; Melis, Anastasios; Happe, Thomas (2009). "Analytical approaches to photobiological hydrogen production in unicellular green algae". Photosynthesis Research. 102 (2–3): 523–40. doi:10.1007/s11120-009-9415-5. PMC 2777220. PMID 19291418.
  64. ^ DOE 2008 Report 25 %
  65. ^ Jenvanitpanjakul, Peesamai (February 3–4, 2010). Renewable Energy Technology And Prospect On Biohydrogen Study In Thailand (PDF). Steering Committee Meeting and Workshop of APEC Research Network for Advanced Biohydrogen Technology. Taichung: Feng Chia University. Archived from the original (PDF) on July 4, 2013.
  66. ^ Navarro Yerga, Rufino M.; Álvarez Galván, M. Consuelo; Del Valle, F.; Villoria De La Mano, José A.; Fierro, José L. G. (2009). "Water Splitting on Semiconductor Catalysts under Visible-Light Irradiation". ChemSusChem. 2 (6): 471–85. doi:10.1002/cssc.200900018. PMID 19536754.
  67. ^ Navarro, R.M.; Del Valle, F.; Villoria De La Mano, J.A.; Álvarez-Galván, M.C.; Fierro, J.L.G. (2009). "Photocatalytic Water Splitting Under Visible Light: Concept and Catalysts Development". Photocatalytic Technologies. Advances in Chemical Engineering. 36. pp. 111–43. doi:10.1016/S0065-2377(09)00404-9. ISBN 978-0-12-374763-1.
  68. ^ Asadi, Nooshin; Karimi Alavijeh, Masih; Zilouei, Hamid (2017). "Development of a mathematical methodology to investigate biohydrogen production from regional and national agricultural crop residues: A case study of Iran". International Journal of Hydrogen Energy. 42 (4): 1989–2007. doi:10.1016/j.ijhydene.2016.10.021.
  69. ^ Tao, Y; Chen, Y; Wu, Y; He, Y; Zhou, Z (2007). "High hydrogen yield from a two-step process of dark- and photo-fermentation of sucrose". International Journal of Hydrogen Energy. 32 (2): 200–6. doi:10.1016/j.ijhydene.2006.06.034.
  70. ^ Rajanandam, Brijesh; Kiran, Siva (2011). "Optimization of hydrogen production by Halobacterium salinarium coupled with E coli using milk plasma as fermentative substrate". Journal of Biochemical Technology. 3 (2): 242–4.
  71. ^ Asadi, Nooshin; Zilouei, Hamid (March 2017). "Optimization of organosolv pretreatment of rice straw for enhanced biohydrogen production using Enterobacter aerogenes". Bioresource Technology. 227: 335–344. doi:10.1016/j.biortech.2016.12.073. PMID 28042989.
  72. ^ "NanoLogix generates energy on-site with bioreactor-produced hydrogen". Solid State Technology. 20 September 2007. Archived from the original on 15 May 2018. Retrieved 14 May 2018.
  73. ^ Percival Zhang, Y-H; Sun, Jibin; Zhong, Jian-Jiang (2010). "Biofuel production by in vitro synthetic enzymatic pathway biotransformation". Current Opinion in Biotechnology. 21 (5): 663–9. doi:10.1016/j.copbio.2010.05.005. PMID 20566280.
  74. ^ Strik, David P. B. T. B.; Hamelers (Bert), H. V. M.; Snel, Jan F. H.; Buisman, Cees J. N. (2008). "Green electricity production with living plants and bacteria in a fuel cell". International Journal of Energy Research. 32 (9): 870–6. doi:10.1002/er.1397. Lay summaryWageningen University and Research Centre.
  75. ^ Timmers, Ruud (2012). Electricity generation by living plants in a plant microbial fuel cell (PhD Thesis). ISBN 978-94-6191-282-4.[page needed]
  76. ^ "Aluminum Based Nanogalvanic Alloys for Hydrogen Generation". U.S. Army Combat Capabilities Development Command Army Research Laboratory. Retrieved January 6, 2020.
  77. ^ McNally, David (July 25, 2017). "Army discovery may offer new energy source". U.S. Army. Retrieved January 6, 2020.
  78. ^ "New Horizons for Hydrogen" (PDF). Research Review. National Renewable Energy Laboratory (2): 2–9. April 2004.

External links[edit]

Further reading[edit]

  • Francesco Calise et al. editors (2019). Solar Hydrogen Production. Academic Press. ISBN 978-0-12-814853-2.