|Preferred IUPAC name
|Systematic IUPAC name
3D model (JSmol)
|Molar mass||33.01 g·mol−1|
|Basicity (pKb)||9.12 (basicity of superoxide ion)|
|Conjugate base||Superoxide anion|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
2 + H2O ⇌ HO2 + OH−
Reactive oxygen species
Together with its conjugate base superoxide, hydroperoxyl is an important reactive oxygen species. Unlike O−
2, which has reducing properties, HO2 can act as an oxidant in a number of biologically important reactions, such as the abstraction of hydrogen atoms from tocopherol and polyunstaturated fatty acids in the lipid bilayer. As such, it may be an important initiator of lipid peroxidation.
Importance for atmospheric chemistry
Gaseous hydroperoxyl is involved in reaction cycles that destroy stratospheric ozone. It is also present in the troposphere, where it is essentially a byproduct of the oxidation of carbon monoxide and of hydrocarbons by the hydroxyl radical.
Because dielectric constant has a strong effect on pKa, and the dielectric constant of air is quite low, superoxide produced (photochemically) in the atmosphere is almost exclusively present as HO2. As HO2 is quite reactive, it acts as a "cleanser" of the atmosphere by degrading certain organic pollutants. As such, the chemistry of HO2 is of considerable geochemical importance.
Hydroperoxyl is also known as superoxide.
- "Reactivity of HO2/O−
2 Radicals in Aqueous Solution". J. Phys. Chem. Ref. Data. 14 (4): 1041–1091. 1985.
- "Hydroperoxyl radical". Glossary of Meteorology. American Meteorological Society. 25 April 2012. Retrieved 22 August 2013.
- IUPAC: Red Book. p. 73 and 320.