When energy is deposited to air, the air molecules become excited. As air is composed primarily of nitrogen and oxygen, excited N2 and O2 molecules are produced. These can react with other molecules, forming mainly ozone and nitrogen(II) oxide. Water vapor, when present, may also play a role; its presence is characterized by the hydrogen emission lines. The reactive species present in the plasma can readily react with other chemicals present in the air or on nearby surfaces.
Deexcitation of nitrogen
The excited nitrogen deexcites primarily by emission of a photon, with emission lines in ultraviolet, visible, and infrared band:
- N2* → N2 + hν
The blue light observed is produced primarily by this process. The spectrum is dominated by lines of single-ionized nitrogen, with presence of neutral nitrogen lines.
Deexcitation of oxygen
The excited state of oxygen is somewhat more stable than nitrogen. While deexcitation can occur by emission of photons, more probable mechanism at atmospheric pressure is a chemical reaction with other oxygen molecules, forming ozone:
- O2* + 2 O2 → 2 O3
This reaction is responsible for the production of ozone in the vicinity of strongly radioactive materials and electrical discharges.
Excitation energy can be deposited in air by a number of different mechanisms:
- Ionizing radiation is the cause of blue glow surrounding sufficient quantities of strongly radioactive materials in air, e.g. some radioisotope specimens (e.g. radium or polonium), particle beams (e.g. from particle accelerators) in air, the blue flashes during criticality accidents, and the eerie/low brightness "purple" to "blue" glow enveloping the mushroom cloud during the first several dozen seconds after nuclear explosions near sea level. An effect that has been observed only at night from atmospheric nuclear tests owing to its low brightness, with observers noticing it following the pre-dawn Trinity (test), Upshot-Knothole Annie, and the Cherokee shot of Operation Redwing.Cherenkov radiation. For more on ionized air glow by nuclear explosions see the near local midnight, high altitude test shot, Bluegill Triple Prime.
- Within minutes after the steam explosion that caused the Chernobyl accident at 01:23 local time, a number of employees at the power station went outside to get a clearer view of the extent of the damage. One such survivor, Alexander Yuvchenko, recounts that once he stopped outside and looked up towards the reactor hall he saw a "very beautiful" LASER-like beam of light bluish light, caused by the ionization of air, that appeared to flood up into infinity.
- Cathode rays in air produce this blue glow.
- Electrical discharge in air is the cause of blue light emitted by electric sparks, lightning, and corona discharges (e.g. St. Elmo's fire).
- Auroras, the sometimes observable blue-violet hues emitted by nitrogen at lower altitudes
In dry air, the color of produced light (e.g. by lightning) is dominated by the emission lines of nitrogen, yielding the spectrum with primarily blue emission lines. The lines of neutral nitrogen (NI), neutral oxygen (OI), singly ionized nitrogen (NII) and singly ionized oxygen (OII) are the most prominent features of a lightning emission spectrum.
Neutral nitrogen radiates primarily at one line in red part of the spectrum. Ionized nitrogen radiates primarily as a set of lines in blue part of the spectrum. The strongest signals are the 443.3, 444.7, and 463.0 nm lines of singly ionized nitrogen.
Violet hue can occur when the spectrum contains emission lines of atomic hydrogen. This may happen when the air contains high amount of water, e.g. with lightnings in low altitudes passing through rain thunderstorms. Water vapor and small water droplets ionize and dissociate easier than large droplets, therefore have higher impact on color.
Generally, the radiant species present in atmospheric plasma are N2, N2+, O2, NO (in dry air) and OH (in humid air). The temperature, electron density, and electron temperature of the plasma can be inferred from the distribution of rotational lines of these species. At higher temperatures, atomic emission lines of N and O, and (in presence of water) H, are present. Other molecular lines, e.g. CO and CN, mark presence of contaminants in the air.
Ionized air glow vs Čerenkov radiation
Despite the similarity of light color produced, the Čerenkov radiation is generated by a fundamentally different mechanism.
Čerenkov radiation is produced by charged particles which are traveling through a dielectric substance at a speed greater than the speed of light in that medium. The only types of charged particle radiation produced in the process of a criticality accident (fission reactions) are alpha particles, beta particles, positrons (which all come from the radioactive decay of unstable daughter products of the fission reaction) and energetic ions which are the daughter products themselves. Of these, only beta particles have sufficient penetrating power to travel more than a few centimeters in air. Since air is a very low density material, its index of refraction (around n=1.0002926) differs very little from that of a vacuum (n=1) and consequently the speed of light in air is only about 0.03% slower than its speed in a vacuum. Therefore, a beta particle emitted from decaying fission products would need to have a velocity greater than 99.97% c in order to produce Čerenkov radiation. Because the energy of beta particles produced during nuclear decay do not exceed energies of about 20 MeV (20.6 MeV for 14B is likely the most energetic with 17.9 MeV for 23Na being the next highest energy beta emitter) and the energy needed for a beta particle to attain 99.97% c is 21.1 MeV , the possibility of Čerenkov radiation produced in air via a fission criticality or a radioactive decay is virtually eliminated.
Čerenkov radiation can be however readily observed in more optically dense environments, e.g. in water or in transparent solids.
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