Ionized-air glow

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Nitrogen glow
Oxygen glow
Particle beam from a cyclotron

Ionized-air glow is the fluorescent emission of characteristic blue–purple–violet light, often of a color called electric blue, by air subjected to an energy flux.


When energy is deposited to air, the air molecules become excited. As air is composed primarily of nitrogen and oxygen, excited N2 and O2 molecules are produced. These can react with other molecules, forming mainly ozone and nitrogen(II) oxide. Water vapor, when present, may also play a role; its presence is characterized by the hydrogen emission lines. The reactive species present in the plasma can readily react with other chemicals present in the air or on nearby surfaces.

Deexcitation of nitrogen[edit]

The excited nitrogen deexcites primarily by emission of a photon, with emission lines in ultraviolet, visible, and infrared band:

N2* → N2 +

The blue light observed is produced primarily by this process.[1] The spectrum is dominated by lines of single-ionized nitrogen, with presence of neutral nitrogen lines.

Deexcitation of oxygen[edit]

The excited state of oxygen is somewhat more stable than nitrogen. While deexcitation can occur by emission of photons, more probable mechanism at atmospheric pressure is a chemical reaction with other oxygen molecules, forming ozone:[1]

O2* + 2 O2 → 2 O3

This reaction is responsible for the production of ozone in the vicinity of strongly radioactive materials and electrical discharges.


Excitation energy can be deposited in air by a number of different mechanisms:


Emission spectrum of nitrogen
Emission spectrum of oxygen
Emission spectrum of hydrogen (water vapor is similar but dimmer)

In dry air, the color of produced light (e.g. by lightning) is dominated by the emission lines of nitrogen, yielding the spectrum with primarily blue emission lines. The lines of neutral nitrogen (NI), neutral oxygen (OI), singly ionized nitrogen (NII) and singly ionized oxygen (OII) are the most prominent features of a lightning emission spectrum.[14]

Neutral nitrogen radiates primarily at one line in red part of the spectrum. Ionized nitrogen radiates primarily as a set of lines in blue part of the spectrum.[15] The strongest signals are the 443.3, 444.7, and 463.0 nm lines of singly ionized nitrogen.[16]

Violet hue can occur when the spectrum contains emission lines of atomic hydrogen. This may happen when the air contains high amount of water, e.g. with lightnings in low altitudes passing through rain thunderstorms. Water vapor and small water droplets ionize and dissociate easier than large droplets, therefore have higher impact on color.[17]

The hydrogen emission lines at 656.3 nm (the strong H-alpha line) and at 486.1 nm (H-beta) are characteristic for lightnings.[18]

Rydberg atoms, generated by low-frequency lightnings, emit at red to orange color and can give the lightning a yellowish to greenish tint.[17]

Generally, the radiant species present in atmospheric plasma are N2, N2+, O2, NO (in dry air) and OH (in humid air). The temperature, electron density, and electron temperature of the plasma can be inferred from the distribution of rotational lines of these species. At higher temperatures, atomic emission lines of N and O, and (in presence of water) H, are present. Other molecular lines, e.g. CO and CN, mark presence of contaminants in the air.[19]

Ionized air glow vs Cherenkov radiation[edit]

Cherenkov radiation is produced by charged particles which are traveling through a dielectric substance at a speed greater than the speed of light in that medium. Despite the similarity of light color produced and similar association with high-energy particles, Cherenkov radiation is generated by a fundamentally different mechanism.

See also[edit]


  1. ^ a b Inorganic chemistry by Egon Wiberg, Nils Wiberg, Arnold Frederick Holleman, p. 1655, Academic Press, 2001, ISBN 0-12-352651-5
  2. ^ "The Trinity Test: 'An eery and awesome sight' by Robert Christy". Archived from the original on 2014-03-07. Retrieved 2014-11-08.
  3. ^ National Academy of Sciences, Robert F. Christy by Goldstein pg 7
  4. ^ "Eyewitnesses to Trinity" (PDF). Nuclear Weapons Journal, Issue 2 2005. Los Alamos National Laboratory. 2005. p. 45. Retrieved 18 February 2014.
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  7. ^ a b Cherokee Field Report Bikini Operations, page 10, quoted in Chuck Hansen, The swords of Armageddon: U.S. nuclear weapons development since 1945 (Sunnyvale, CA : Chukelea Publications, 1995), 1307
  8. ^ Camera-man Yoshitake -"For several minutes after the blast, you could see this eerie ultraviolet glow high up in the sky. And I thought that was so spectacular, so meaningful."
  9. ^ Operation Upshot-Knothole Shot Annie,, retrieved October 27, 2013
  10. ^ "Cheating Chernobyl This interview was first published in New Scientist print edition Source : New Scientist web site".
  11. ^ "Chernobyl 20 years on".
  12. ^ "Chernobyl: what happened and why? by CM Meyer, technical journalist" (PDF). Archived from the original (PDF) on 2013-12-11.
  13. ^ The Becquerel Rays and the Properties of Radium by R. J. Strutt, p. 20, Courier Dover Publications, 2004 ISBN 0-486-43875-9
  14. ^ Lightning by Martin A. Uman, p. 139, Courier Dover Publications, 1984 ISBN 0-486-64575-4
  15. ^ All about lightning by Martin A. Uman, p. 96, Courier Dover Publications, 1986 ISBN 0-486-25237-X
  16. ^ [2][dead link]
  17. ^ a b PhysForum Science, Physics and Technology Discussion Forums -> Colours of electiricy. Retrieved on 2010-06-05.
  18. ^ AMS Journals Online – Daylight Spectra of Individual Lightning Flashes in the 370–690 nm Region. Retrieved on 2010-06-05.
  19. ^ Laux, C O; Spence, T G; Kruger, C H; Zare, R N (2003). "Optical diagnostics of atmospheric pressure air plasmas" (PDF). Plasma Sources Science and Technology. 12 (2): 125. Bibcode:2003PSST...12..125L. doi:10.1088/0963-0252/12/2/301. Archived from the original (PDF) on 2011-07-16. Retrieved 2010-05-27.