Iron nitrides

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Iron nitride is an inorganical chemical compound.

Physical properties

Both iron nitrides are gray powders.

Chemical properties

Iron has four nitrides, Fe2N, Fe3N1+x, Fe4N, and Fe16N2. They are crystalline, metallic solids. Group VII and group VIII transition metals form nitrides that decompose at relatively low temperatures - iron nitride, Fe2N decomposes under loss of molecular nitrogen at about above 400 °C and formation of lower-nitrogen content iron nitrides. They are insoluble in water.

Health hazards

When heated to decomposition, or exposed to humidity, iron nitride may emit toxic fumes of ammonia. It is considered a moderate explosion hazard. Inhalation of iron nitride dust or powder may cause irritation to the respiratory system and possibly acute iron poisoning or iron pneumoconiosis.

Research applications

Colloidal solution of magnetic iron nitride nanoparticles is a way to create ferrofluids.

References