John Meurig Thomas

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Sir John Meurig Thomas
Born (1932-12-15) 15 December 1932 (age 82)[1]
Institutions
Alma mater
Notable awards
Website
www-hrem.msm.cam.ac.uk/people/thomas/

Sir John Meurig Thomas FLSW FRS HonFREng[3] (born 15 December 1932) is a Welsh chemist and educator primarily known for his work on heterogeneous catalysis, solid-state chemistry, and surface and materials science.[4][5] Thomas has authored over one thousand scientific articles and several books, including Principles and Practice of Heterogeneous Catalysis (with W. John Thomas)[6] and Michael Faraday and the Royal Institution: The Genius of Man and Place.[7][8]

In 1991 Thomas was knighted "for services to chemistry and the popularisation of science". The mineral meurigite is named after him.[citation needed] Much of his research has involved creating new solid catalysts and trying to understand the structure and activity of existing ones using techniques such as X-ray absorption, NMR spectroscopy, and high resolution transmission electron microscopy. Thomas is one of the most cited authors in the field of heterogeneous catalysis. In recent years, he has focused on designing green chemistry catalysts for clean technology and on developing ways of studying catalysts in situ.

Biography[edit]

Education[edit]

Thomas was born and brought up near the Welsh mining town of Llanelli,[1] South Wales where his father and brother were miners. His interest in science was aroused when as a teenager he heard his physics teacher at Gwendraeth Grammar School talk about the life and work of Michael Faraday. Later in life, Sir John would become the Fullerian Professor of Chemistry at the Royal Institution of Great Britain, in London, a position held by Michael Faraday, who has remained one of his scientific heroes.[citation needed]

Thomas holds BSc (1954) and PhD (1958) degrees from the University of Wales, Swansea, although he completed the work for his PhD at Queen Mary College, University of London, where his advisor, Keble Sykes, had moved.

Early career[edit]

After a year's work for the United Kingdom Atomic Energy Authority as scientific officer he joined the Department of Chemistry at the University of Wales, Bangor where he rose through the ranks from Assistant Lecturer, to Lecturer, and then to Reader. In 1959 he married Margaret Edwards (deceased 2002) with whom he later had two daughters, Lisa and Naomi. While at Bangor, he demonstrated the profound influence that dislocations and other structural imperfections exert upon the chemical, electronic, and surface properties of solids.

In 1969 he became Professor and Head of Chemistry at the University College of Wales, Aberystwyth, where he broadened his interests in solid-state, surface and materials chemistry and pioneered the application of electron microscopy in chemistry. In 1977 he was elected a Fellow of the Royal Society.

From 1978 to 1986, Thomas was at the University of Cambridge as Head of the Department of Physical Chemistry (then a separate department from the Department of Chemistry, which covered Organic, Inorganic and Theoretical Chemistry) and Professorial Fellow at King's College, Cambridge. There he continued developing new techniques in solid-state and materials science, and designing and synthesizing new catalysts. For example, he extended his earlier electron microscopic and surface studies of minerals and intercalates to encompass the synthesis and structural determination of zeolitic materials by a combination of solid-state NMR, neutron scattering, and real-space imaging.

Director of the Royal Institution[edit]

In 1986 he was invited to succeed Sir George Porter as Director of the Royal Institution of Great Britain, London, occupying with his family the same living quarters that Michael Faraday and his wife had occupied at the Royal Institution's building on Albemarle Street. At this time, he began using synchrotron radiation and devised techniques which combine X-ray spectroscopy and high-resolution X-ray diffraction to determine the atomic structure of the active sites of solid catalysts under operating conditions. He also devised new mesoporous, microporous, and molecular sieve catalysts. In 1987 the BBC televised his Royal Institution Christmas Lectures on crystals, continuing the tradition of lectures for children started by Faraday in 1826. He resigned as Director in 1991 owing to his wife's health, but remained associated with the Davy Faraday Research Laboratory of the Royal Institution until 2006. In 1991 he published the book Michael Faraday and the Royal Institution: The Genius of Man and Place, which has since been translated into Japanese (1994) and Italian (2007).

Return to Cambridge[edit]

After a period as Deputy Pro-Chancellor of the University of Wales (1991–1994), he returned to Cambridge in 1993 as Master of Peterhouse, Cambridge's oldest college, and as Honorary Distinguished Research Associate in the Department of Material Science, both of which posts he held until 2002, the year his wife died. During his tenure as Master of Peterhouse, Lady Thomas oversaw the magnificent renovation of the Master's Lodge, a 1702 mansion on Trumpington Street.

In 1997 he co-authored with W. John Thomas (no relation) the text Principles and Practice of Heterogeneous Catalysis. In 1999 he was elected Honorary Fellow of the Royal Academy of Engineering for work that "has profoundly added to the science-base of heterogeneous catalysis leading to the commercial exploitation of zeolites through engineering processes".

He is the author of some thirty patents, some of which have made chemical processes more environmentally benign ("greener") by eliminating the use of solvents and reducing the number of manufacturing steps involved. The single-step, solvent-free catalytic synthesis of ethyl acetate that he invented is the basis of a 200,000 ton/year plant in the UK, the largest of its kind in the world. He has recently devised single-step, solvent-free processes for the production of caprolactam (the raw material for nylon-6) and vitamin B3 (niacin).

Awards and honours[edit]

Since 2002 he has been Honorary Professor of Materials Science at the University of Cambridge and Emeritus Professor of Chemistry at the Davy Faraday Research Laboratory of the Royal Institution. He also holds an Honorary Distinguished Professorship of Materials Chemistry at Cardiff University, an Honorary Distinguished Professorship of Materials Chemistry at the University of Southampton, and an Honorary Distinguished Professorship of Chemistry and Nanoscience at the University of York. He is an Advisory Professor at Shanghai Jiao Tong University as well as at the Catalysis Center of Hokkaido University. He was recently appointed to the Advisory Committee on Science, Wales. He is an Honorary Bencher of Gray's Inn.

He is the recipient of twenty honorary degrees from Australian, British, Canadian, Chinese, Dutch, Egyptian, French, Italian, Japanese, Spanish, and U.S. universities, and has been elected to honorary membership in over fifteen foreign academies, including the Royal Swedish Academy of Sciences, the American Philosophical Society, the American Academy of Arts and Sciences, the Accademia dei Lincei (Rome), and the Russian Academy of Sciences.

His recent awards include the Kapitza Gold Medal from the Russian Academy of Natural Sciences (2011), the Jayne Prize Lectureship of the American Philosophical Society (2011), the Bragg Prize Lectureship of the British Crystallographic Association (2010), the Sven Berggren Prize Lectureship, Lund (2010), the Ertl Prize Lectureship of the Max Planck Gesellschaft (2010), the Sir George Stokes Medal from the Royal Society of Chemistry (2005), the Giulio Natta Gold Medal from the Società Chimica Italiana (2004), the Linus Pauling Gold Medal from Stanford University (2003), and the American Chemical Society Annual Award (first recipient) for Creative Research in Heterogeneous and Homogeneous Catalysis (1999). He has won the Davy Medal of the Royal Society and the Faraday Lectureship Prize of the Royal Society of Chemistry. In 1995 he became the first British scientist in 80 years to be awarded the Willard Gibbs Award by the Chicago Section of the American Chemical Society. In recognition of his contributions to geochemistry, a new mineral, meurigite, was named after him in 1995 by the International Mineralogical Association.

His 75th birthday (attended by Angela Merkel and Ahmed Zewail) was celebrated with a symposium and several musical and social events at the University of Cambridge. The papers presented at the symposium were published in 2008 by the Royal Society of Chemistry as Turning Points in Solid-State, Materials and Surface Science: A Book in Celebration of the Life and Work of Sir John Meurig Thomas. In 2010 Imperial College Press published 4D Electron Microscopy: Imaging in Space and Time, which he co-authored with Ahmed Zewail (Nobel Laureate, Chemistry, 1999). His most recent publication is Design and Applications of Single-Site Heterogeneous Catalysts: Contributions to Green Chemistry, Clean Technology and Sustainability, which has been praised as follows:

A true marriage of the practical and the fundamental, John Thomas's masterly account of single site heterogeneous catalysts, a remarkably effective form of matter guiding desired chemical transformation, is a sheer joy to read. With the synthetic flair of Humphry Davy and the brilliance of his hero Faraday, we are led by the author to a feast of contemporary masterworks of chemical reactivity, prodded, by design, into the service of humanity.

Roald Hoffmann, Nobel Laureate, Chemistry, 1999

In April 2010 Sir John married Jehane Ragai of the American University in Cairo; the events took place in Cambridge and London. The recreations he lists in Who's Who include ancient civilisations, bird watching, and Welsh literature. In 2003, he was the first scientist to be awarded the Medal of the Honourable Society of Cymmrodorion (London) for services to Welsh culture and British public life. He is also a Founding Fellow of the Learned Society of Wales and a Member of its inaugural Council. Since 2011 he has been a member of the Scientific Advisory Committee for Wales. He is an overseer of the Chemical Heritage Foundation (Philadelphia), and a member of the International Advisory Board of the Zewail City of Science and Technology (Egypt).

He was also appointed as a Honorary Fellow[3] of the Royal Academy of Engineering in 2013.

Selected scientific publications[edit]

Books[edit]

  • Introduction to the Principles of Heterogeneous Catalysis, 1967, Academic Press. (With W.J. Thomas).[6]
  • Selections and Reflections: The Legacy of Sir Lawrence Bragg, 1990, Science Reviews. (With Lord David Phillips, editors).
  • Michael Faraday and the Royal Institution: The Genius of Man and Place, 1991, Institute of Physics Publishing.[7]
  • Perspectives in Catalysis, 1992, Blackwells. (With K.I. Zamaraev, editors).
  • Principles and Practice of Heterogeneous Catalysis, 1997, Wiley. (With W.J. Thomas).
  • 4D Electron Microscopy: Imaging in Space and Time, 2010, Imperial College Press. (With A.H. Zewail).
  • Design and Applications of Single-Site Heterogeneous Catalysts: Contributions to Green Chemistry, Clean Technology and Sustainability, 2012, Imperial College Press.[9]

Part 1: On the design and application of solid catalysts[edit]

  • Sheet silicates: Broad spectrum catalysts for organic synthesis.[10](See also U.S. Patent 4,999,319 (1985), which is the basis of the world's largest solvent-free, single-step production of ethyl acetate.)
  • Uniform heterogeneous catalysts: The role of solid-state chemistry in their development and design.[11]
  • New micro-crystalline catalysts Bakerian Lecture 1990.[2]
  • Solid acid catalysts[12]
  • Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica[13]
  • Design, synthesis and in situ characterisation of new solid catalysts[14](Linus Pauling Lecture, California Institute of Technology, March 1999 and Karl Ziegler Lecture, Max Planck Institute, Mülheim, November 1998.)
  • Molecular sieve catalysts for the regioselective and shape-selective oxyfunctionalization of alkanes in air[15]
  • Solvent-free routes to clean technology[16]
  • Constraining asymmetric organometallic catalysts within mesoporous supports boosts their enantioselectivity[17]
  • Highly efficient, one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts[18]
  • Design of a "green" one-step catalytic production of ε-caprolactam (precursor of nylon-6)[19]See also [20][21]
  • The advantages and future potential of single-site heterogeneous catalysts[22]
  • Single-site photocatalytic solids for the decomposition of undesirable molecules (Focus Article)[23]
  • Innovations in oxidation catalysis leading to a sustainable society[24]
  • Systematic enumeration of microporous solids: Towards designer catalysts[25]
  • Facile, one-step production of niacin (vitamin B3) and other nitrogen-containing pharmaceutical chemicals with a single-site heterogeneous catalyst[26]
  • Nanoporous oxidic solids: The confluence of heterogeneous and homogeneous catalysis[27](Based on a lecture at the Symposium of Molecular Frontiers held at the Swedish Academy of Sciences in May 2008).
  • Heterogeneous catalysis: Enigmas, illusions, challenges, realities, and emergent strategies of design[28]
  • Can a single atom serve as the active site in some heterogeneous catalysts?[29]
  • The principles of solid state chemistry hold the key to the successful design of heterogeneous catalysts for environmentally responsible processes[30]

Part 2: On new techniques[edit]

  • Tracing the conversion of aurichalcite to a copper catalyst by combined X-ray absorption and diffraction[31]
  • Review lecture: Topography and topology in solid-state chemistry[32]
  • Resolving crystallographically distinct tetrahedral sites in silicalite and ZSM-5 by solid-state NMR[33]
  • Revolutionary developments from atomic to extended structural imaging[34]
  • Nanotomography in the chemical, biological and materials sciences[35] see also[36][37]
  • Mono- bi- and multifunctional single sites: exploring the interface between heterogeneous and homogeneous catalysis[38]
  • The modern electron microscope: A cornucopia of chemico-physical insights[39]

References[edit]

  1. ^ a b THOMAS, Sir John Meurig. Who's Who 2014 (online Oxford University Press ed.). A & C Black, an imprint of Bloomsbury Publishing plc.  (subscription required)
  2. ^ a b Thomas, J. M. (1990). "The Bakerian Lecture, 1990: New Microcrystalline Catalysts". Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 333 (1629): 173. Bibcode:1990RSPTA.333..173T. doi:10.1098/rsta.1990.0158. 
  3. ^ a b "List of Fellows of the Royal Academy of Engineering". 
  4. ^ Somorjai, G. A.; Roberts, M. W. (2003). "A Tribute to John Meurig Thomas: Llongyfarchiadau ar eich penblwydd". Topics in Catalysis 24: 3. doi:10.1023/b:toca.0000003335.51469.58. 
  5. ^ John Meurig Thomas interviewed by Alan Macfarlane 29 November and 5 December 2007 (film)
  6. ^ a b Principles and Practice of Heterogeneous Catalysis (Chemistry) ISBN 352729239X
  7. ^ a b Michael Faraday and the Royal Institution: The Genius of Man and Place ISBN 0750301457
  8. ^ John Meurig Thomas's publications indexed by the Scopus bibliographic database, a service provided by Elsevier.
  9. ^ Catlow, R. (2013). "Design and Applications of Single-Site Heterogeneous Catalysis. Prof. Sir John Meurig Thomas". ChemCatChem 5 (7): 2058. doi:10.1002/cctc.201300368. 
  10. ^ Ballantine, J. A.; Purnell, J. H.; Thomas, J. M. (1984). "Sheet silicates: Broad spectrum catalysts for organic synthesis". Journal of Molecular Catalysis 27: 157. doi:10.1016/0304-5102(84)85077-4. 
  11. ^ Thomas, J. M. (1988). "Uniform Heterogeneous Catalysts: The Role of Solid-State Chemistry in their Development and Design". Angewandte Chemie International Edition in English 27 (12): 1673. doi:10.1002/anie.198816731. 
  12. ^ Thomas, S. J. M. (1992). "Solid Acid Catalysts". Scientific American 266 (4): 112. doi:10.1038/scientificamerican0492-112. 
  13. ^ Maschmeyer, T.; Rey, F.; Sankar, G.; Thomas, J. M. (1995). "Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica". Nature 378 (6553): 159. doi:10.1038/378159a0. 
  14. ^ Thomas, J. M. (1999). "Design, Synthesis, and in Situ Characterization of New Solid Catalysts". Angewandte Chemie International Edition 38 (24): 3588. doi:10.1002/(SICI)1521-3773(19991216)38:24<3588::AID-ANIE3588>3.0.CO;2-4. 
  15. ^ Thomas, J. M.; Raja, R; Sankar, G; Bell, R. G. (2001). "Molecular sieve catalysts for the regioselective and shape- selective oxyfunctionalization of alkanes in air". Accounts of chemical research 34 (3): 191–200. PMID 11263877. 
  16. ^ Thomas, J. M.; Raja, R.; Sankar, G.; Johnson, B. F. G.; Lewis, D. W. (2001). "Solvent-Free Routes to Clean Technology". Chemistry - A European Journal 7 (14): 2972. doi:10.1002/1521-3765(20010716)7:14<2972::AID-CHEM2972>3.0.CO;2-Z. 
  17. ^ Raja, R; Thomas, J. M.; Jones, M. D.; Johnson, B. F.; Vaughan, D. E. (2003). "Constraining asymmetric organometallic catalysts within mesoporous supports boosts their enantioselectivity". Journal of the American Chemical Society 125 (49): 14982–3. doi:10.1021/ja030381r. PMID 14653721. 
  18. ^ Raja, R; Thomas, J. M.; Xu, M; Harris, K. D.; Greenhill-Hooper, M; Quill, K (2006). "Highly efficient one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts". Chemical communications (Cambridge, England) (4): 448–50. PMID 16493832. 
  19. ^ Thomas, J. M.; Raja, R. (2005). "Design of a "green" one-step catalytic production of  -caprolactam (precursor of nylon-6)". Proceedings of the National Academy of Sciences 102 (39): 13732. doi:10.1073/pnas.0506907102. 
  20. ^ Raja, R.; Sankar, G.; Thomas, J. M. (2001). "Bifunctional Molecular Sieve Catalysts for the Benign Ammoximation of Cyclohexanone:  One-Step, Solvent-Free Production of Oxime and ε-Caprolactam with a Mixture of Air and Ammonia". Journal of the American Chemical Society 123 (33): 8153. doi:10.1021/ja011001. 
  21. ^ Mokaya, R.; Poliakoff, M. (2005). "Chemistry: A cleaner way to nylon?". Nature 437 (7063): 1243. doi:10.1038/4371243a. 
  22. ^ Thomas, J. M.; Raja, R. (2006). "The advantages and future potential of single-site heterogeneous catalysts". Topics in Catalysis 40: 3. doi:10.1007/s11244-006-0105-7. 
  23. ^ Anpo, M; Thomas, J. M. (2006). "Single-site photocatalytic solids for the decomposition of undesirable molecules". Chemical Communications (31): 3273–8. doi:10.1039/b606738g. PMID 16883411. 
  24. ^ Thomas, J.; Raja, R. (2006). "Innovations in oxidation catalysis leading to a sustainable society☆". Catalysis Today 117: 22. doi:10.1016/j.cattod.2006.05.003. 
  25. ^ Thomas, J. M.; Klinowski, J. (2007). "Systematic Enumeration of Microporous Solids: Towards Designer Catalysts". Angewandte Chemie International Edition 46 (38): 7160. doi:10.1002/anie.200700666. 
  26. ^ Raja, R; Thomas, J. M.; Greenhill-Hooper, M; Ley, S. V.; Almeida Paz, F. A. (2008). "Facile, one-step production of niacin (vitamin B3) and other nitrogen-containing pharmaceutical chemicals with a single-site heterogeneous catalyst". Chemistry - A European Journal 14 (8): 2340–8. doi:10.1002/chem.200701679. PMID 18228543. 
  27. ^ Thomas, J. M.; Hernandez-Garrido, J. C.; Raja, R; Bell, R. G. (2009). "Nanoporous oxidic solids: The confluence of heterogeneous and homogeneous catalysis". Physical Chemistry Chemical Physics 11 (16): 2799–825. doi:10.1039/b819249a. PMID 19421495. 
  28. ^ Thomas, J. M. (2008). "Heterogeneous catalysis: Enigmas, illusions, challenges, realities, and emergent strategies of design". The Journal of Chemical Physics 128 (18): 182502. doi:10.1063/1.2832309. PMID 18532787. 
  29. ^ Thomas, J. M.; Saghi, Z.; Gai, P. L. (2011). "Can a Single Atom Serve as the Active Site in Some Heterogeneous Catalysts?". Topics in Catalysis 54 (10–12): 588. doi:10.1007/s11244-011-9677-y. 
  30. ^ Thomas, J. M. (2011). "The principles of solid state chemistry hold the key to the successful design of heterogeneous catalysts for environmentally responsible processes". Microporous and Mesoporous Materials 146: 3. doi:10.1016/j.micromeso.2011.05.025. 
  31. ^ Couves, J. W.; Thomas, J. M.; Waller, D.; Jones, R. H.; Dent, A. J.; Derbyshire, G. E.; Greaves, G. N. (1991). "Tracing the conversion of aurichalcite to a copper catalyst by combined X-ray absorption and diffraction". Nature 354 (6353): 465. doi:10.1038/354465a0. 
  32. ^ Thomas, J. M. (1974). "Review Lecture: Topography and Topology in Solid-State Chemistry". Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 277 (1268): 251. Bibcode:1974RSPTA.277..251T. doi:10.1098/rsta.1974.0051. 
  33. ^ Fyfe, C. A.; Gobbi, G. C.; Klinowski, J.; Thomas, J. M.; Ramdas, S. (1982). "Resolving crystallographically distinct tetrahedral sites in silicalite and ZSM-5 by solid-state NMR". Nature 296 (5857): 530. doi:10.1038/296530a0. 
  34. ^ Thomas, J. M. (2008). "Revolutionary Developments from Atomic to Extended Structural Imaging". Physical Biology. pp. 51–114. doi:10.1142/9781848162013_0004. ISBN 978-1-84816-199-3. 
  35. ^ Midgley, P. A.; Ward, E. P. W.; Hungría, A. B.; Thomas, J. M. (2007). "Nanotomography in the chemical, biological and materials sciences". Chemical Society Reviews 36 (9): 1477. doi:10.1039/B701569K. 
  36. ^ Midgley, P. A.; Weyland, M.; Thomas, J. M.; Johnson, B. F. G. (2001). "Z-Contrast tomography: A technique in three-dimensional nanostructural analysis based on Rutherford scattering". Chemical Communications (10): 907. doi:10.1039/B101819C. 
  37. ^ Thomas, J. M.; Johnson, B. F. G.; Raja, R.; Sankar, G.; Midgley, P. A. (2003). "High-Performance Nanocatalysts for Single-Step Hydrogenations". Accounts of Chemical Research 36: 20. doi:10.1021/ar990017q. 
  38. ^ Thomas, J. M.; Raja, R. (2010). "Mono-, Bi- and Multifunctional Single-Sites: Exploring the Interface Between Heterogeneous and Homogeneous Catalysis". Topics in Catalysis 53 (13–14): 848. doi:10.1007/s11244-010-9517-5. 
  39. ^ Thomas, J. M.; Midgley, P. A. (2011). "The modern electron microscope: A cornucopia of chemico-physical insights". Chemical Physics 385: 1. doi:10.1016/j.chemphys.2011.04.023. 
Cultural offices
Preceded by
Sir George Porter
Director of the Royal Institution
1986–1991
Succeeded by
Peter Day
Academic offices
Preceded by
The Very Rev'd Henry Chadwick
Master of Peterhouse, Cambridge
1993–2002
Succeeded by
Lord Wilson of Tillyorn