Laue equations

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Laue equation

In crystallography, the Laue equations relate the incoming waves to the outcoming waves in the process of diffraction by a crystal lattice. They are named after physicist Max von Laue (1879–1960). They reduce to Bragg's law.

The Laue equations[edit]

Let to be the primitive vectors of the crystal lattice , whose atoms are located at the points that are integer linear combinations of the primitive vectors.

Let be the wavevector of the incoming (incident) beam, and let be the wavevector of the outgoing (diffracted) beam. Then the vector is called the scattering vector (also called transferred wavevector) and measures the change between the two wavevectors.

The three conditions that the scattering vector must satisfy, called the Laue equations, are the following: the numbers determined by the equations

must be integer numbers. Each choice of the integers , called Miller indices, determines a scattering vector . Hence there are infinitely many scattering vectors that satisfy the Laue equations. They form a lattice , called the reciprocal lattice of the crystal lattice. This condition allows a single incident beam to be diffracted in infinitely many directions. However, the beams that correspond to high Miller indices are very weak and can't be observed. Anyway, it is enough to find a basis of the reciprocal lattice, from which the crystal lattice can be determined. This is the principle of x-ray crystallography.

Mathematical derivation[edit]

The incident and diffracted beams are planar wave excitations

of a field that for simplicity we take as scalar, even though the main case of interest is the electromagnetic field, which is vectorial.

The two waves propagate through space independently, except at the points of the lattice, where they resonate with the oscillators, so their phase must coincide.[1] Hence for each point of the lattice we have

or equivalently, we must have

for some integer , that depends on the point . Simplifying we get

Now, it is enough to check that this condition is satisfied at the primitive vectors (which is exactly what the Laue equations say), because then for the other points we have

where is the integer .

This ensures that if the Laue equations are satisfied, then the incoming and outgoing wave have the same phase at all points of the crystal lattice, so the oscillation of the atoms, that follows the incoming wave, can at the same time generate the outgoing wave.

Relation to Bragg Law[edit]

If is the reciprocal lattice vector, we know . The Laue equations specify . Hence we have or .

From this we get the diffraction condition:

Since (considering elastic scattering) and (a negative reciprocal lattice vector is still a reciprocal lattice vector):

.

The diffraction condition reduces to the Bragg law .

References[edit]

  • Kittel, C. (1976). Introduction to Solid State Physics, New York: John Wiley & Sons. ISBN 0-471-49024-5
Notes
  1. ^ More realistically, the oscillators of the lattice should lag behind the incoming wave, and the outcoming wave should lag behind the oscillator. But since the lag is the same at all point of the lattice, the only effect of this correction would be global shift of phase of the outcoming wave, which we are not taking into consideration.