Liquid metal

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A liquid metal is a metal or a metal alloy which is liquid at or near room temperature.[1]

The only stable liquid elemental metal at room temperature is mercury (Hg), which is molten above −38.8 °C (234.3 K, −37.9 °F). Three more stable elemental metals melt just above room temperature: caesium (Cs), which has a melting point of 28.5 °C (83.3 °F); gallium (Ga) (30 °C [86 °F]); and rubidium (Rb) (39 °C [102 °F]). The radioactive metal francium (Fr) is probably liquid close to room temperature as well. Calculations predict that the radioactive metals copernicium (Cn) and flerovium (Fl) should also be liquid at room temperature.[2]

Alloys can be liquid if they form a eutectic, meaning that the alloy's melting point is lower than any of the alloy's constituent metals. The standard metal for creating liquid alloys used to be mercury, but gallium-based alloys, which are lower both in their vapor pressure at room temperature and toxicity, are being used as a replacement in various applications.[3]

Thermal and electrical conductivity[edit]

Alloy systems that are liquid at room temperature have thermal conductivity far superior to ordinary non-metallic liquids,[4] allowing liquid metal to efficiently transfer energy from the heat source to the liquid. They also have a higher electrical conductivity that allows the liquid to be pumped by more efficient, electromagnetic pumps.[5] This results in the use of these materials for specific heat conducting and/or dissipation applications.

Another advantage of liquid alloy systems is their inherent high densities.

Viscosity[edit]

The viscosity of liquid metals can vary greatly depending on the atomic composition of the liquid, especially in the case of alloys. In particular, the temperature dependence of the viscosity of liquid metals may range from the standard Arrhenius law dependence, to a much steeper (non-Arrhenius) dependence such as that given empirically by the Vogel-Fulcher-Tammann equation. A physical model for the viscosity of liquid metals, which captures this great variability in terms of the underlying interatomic interactions, was also developed.[6]

The electrical resistance of a liquid metal can be estimated by means of the Ziman formula, which gives the resistance in terms of the static structure factor of the liquid as can be determined by neutron or X-ray scattering measurements.

Wetting to metallic and non-metallic surfaces[edit]

Once oxides have been removed from the substrate surface, most liquid metals will wet most metallic surfaces. At room-temperature liquid metals are often reactive and soluble to metallic surfaces, though some solid metals are resistant to attack by the common liquid metals. [7] For example gallium is corrosive to all metals except tungsten and tantalum, which have a high resistance to corrosion, more so than niobium, titanium and molybdenum.[8]

Similar to indium, gallium and gallium-containing alloys have the ability to wet to many non-metallic surfaces such as glass and quartz. Gently rubbing the alloy into the surface may help induce wetting. However, this observation of "wetting by rubbing into glass surface" has created a widely spread misconception that the gallium-based liquid metals wet glass surfaces, as if the liquid breaks free of the oxide skin and wets the surface. The reality is the opposite: the oxide makes the liquid wet the glass. In more details: as the liquid is rubbed into and spread onto the glass surface, the liquid oxidizes and coats the glass with a thin layer of oxide (solid) residues, on which the liquid metal wets. In other words, what is seen is a gallium-based liquid metal wetting its solid oxide, not glass. Apparently, the above misconception was caused by the super-fast oxidation of the liquid gallium in even a trace amount of oxygen, i.e., nobody observed the true behavior of a liquid gallium on glass, until research at the UCLA debunked the above myth by testing Galinstan, a gallium-based alloy that is liquid at room temperature, in an oxygen-free environment.[9] Note: These alloys form a thin dull looking oxide skin that is easily dispersed with mild agitation. The oxide-free surfaces are bright and lustrous.

Applications[edit]

Because of their excellent characteristics and manufacturing methods, liquid metals are often used in wearable devices, medical devices, interconnected devices and so on.

Typical uses of liquid metals include thermostats, switches, barometers, heat transfer systems, and thermal cooling and heating designs.[10] Uniquely, they can be used to conduct heat and/or electricity between non-metallic and metallic surfaces.

Thermal interfaces[edit]

Liquid metal is sometimes used as a thermal interface material between coolers and processors because of its high thermal conductivity. The PlayStation 5 video game console uses liquid metal to help cool high temperatures inside the console.[11]

3D printing devices[edit]

Liquid metal can be used for wearable devices. Emerging IoT applications require reliable and effective wireless connectivity. Therefore, it is necessary to make a small flexible antenna.

See also[edit]

References[edit]

  1. ^ Neumann, Taylor V.; Dickey, Michael D. (2020). "Liquid Metal Direct Write and 3D Printing: A Review". Advanced Materials Technologies. 5 (9): 2000070. doi:10.1002/admt.202000070. ISSN 2365-709X.
  2. ^ Mewes, Jan-Michael; Schwerdtfeger, Peter (11 February 2021). "Exclusively Relativistic: Periodic Trends in the Melting and Boiling Points of Group 12". Angewandte Chemie. doi:10.1002/anie.202100486. Retrieved 1 March 2021.
  3. ^ Thermal Interface Materials
  4. ^ Kunquan, Ma; Jing, Liu (October 2007). "Liquid metal management of computer chips". Frontiers of Energy and Power Engineering in China. 1 (4): 384–402. doi:10.1007/s11708-007-0057-3. ISSN 1673-7504.
  5. ^ Miner, A.; Ghoshal, U. (2004-07-19). "Cooling of high-power-density microdevices using liquid metal coolants". Applied Physics Letters. 85 (3): 506–508. Bibcode:2004ApPhL..85..506M. doi:10.1063/1.1772862. ISSN 0003-6951.
  6. ^ Krausser, J.; Samwer, K.; Zaccone, A. (2015). "Interatomic repulsion softness directly controls the fragility of supercooled metallic melts". Proceedings of the National Academy of Sciences of the USA. 112 (45): 13762. doi:10.1073/pnas.1503741112.
  7. ^ Wade, K.; Banister, A. J. (1975). The Chemistry of Aluminum, Gallium, Indium, and Thallium. Pergamon Texts in Inorganic Chemistry. 12. ASIN B0007AXLOA.
  8. ^ Lyon, Richard N., ed. (1952). Liquid Metals Handbook (2 ed.). Washington, D.C.CS1 maint: extra text: authors list (link)
  9. ^ Liu, T.; S., Prosenjit; Kim, C.-J. (April 2012). "Characterization of Nontoxic Liquid-Metal Alloy Galinstan for Applications in Microdevices". Journal of Microelectromechanical Systems. 21 (2): 443–450. CiteSeerX 10.1.1.703.4444. doi:10.1109/JMEMS.2011.2174421.
  10. ^ Liquid Metal Thermal Interface Materials
  11. ^ Grubb, Jeff (October 7, 2020). "PlayStation 5 uses liquid metal — here's why that's cool". VentureBeat. Retrieved December 19, 2020.