In chemistry and atomic physics, the main group is the group of elements whose lightest members are represented by helium, lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine, and neon as arranged in the periodic table of the elements. The main group includes the elements (except hydrogen, which is sometimes not included) in groups 1 and 2 (s-block), and groups 13 to 18 (p-block). The s-block elements are primarily characterised by one main oxidation state, and the p-block elements, when they have multiple oxidation states, often have common oxidation states separated by two units.
Group 12 elements are often considered to be transition metals; however, zinc (Zn), cadmium (Cd), and mercury (Hg) share some properties of both groups, and many scientists believe they should be included in the main group. Occasionally, even the group 3 elements as well as the lanthanides and actinides have been included, because especially the group 3 elements and lanthanides are electropositive elements with only one main oxidation state like the group 1 and 2 elements. The position of the actinides is more questionable, but the most common and stable of them, thorium (Th) and uranium (U), are similar to main-group elements as thorium is an electropositive element with only one main oxidation state (+4), and uranium has two main ones separated by two oxidation units (+4 and +6).
In older nomenclature the main-group elements are groups IA and IIA, and groups IIIB to 0 (CAS groups IIIA to VIIIA). Group 12 is labelled as group IIB in both systems. Group 3 is labelled as group IIIA in the older nomenclature (CAS group IIIB).
Main-group elements (with some of the lighter transition metals) are the most abundant elements on Earth, in the Solar System, and in the Universe. They are sometimes also called the representative elements.
- "Nomenclature of Inorganic Chemistry". International Union of Pure and Applied Chemistry. Retrieved 27 September 2011.
- Jensen, William B. (2003). "The Place of Zinc, Cadmium, and Mercury in the Periodic Table" (PDF). Journal of Chemical Education. 80 (8): 952. Bibcode:2003JChEd..80..952J. doi:10.1021/ed080p952.
- King, R. Bruce (1995). Inorganic Chemistry of Main Group Elements. Wiley-VCH. ISBN 0-471-18602-3.