Mechanical properties of carbon nanotubes
The mechanical properties of carbon nanotubes reveal them as one of the strongest materials in nature. Carbon nanotubes (CNTs) are long hollow cylinders of graphene. Although graphene sheets have 2D symmetry, carbon nanotubes by geometry have different properties in axial and radial directions. It has been shown that CNTs are very strong in the axial direction. Young's modulus on the order of 270 - 950 GPa and tensile strength of 11 - 63 GPa were obtained.
Carbon nanotubes are the strongest and stiffest materials yet discovered in terms of tensile strength and elastic modulus respectively. This strength results from the covalent sp2 bonds formed between the individual carbon atoms. In 2000, a multi-walled carbon nanotube was tested to have a tensile strength of 63 gigapascals (9,100,000 psi). (For illustration, this translates into the ability to endure tension of a weight equivalent to 6,422 kilograms-force (62,980 N; 14,160 lbf) on a cable with cross-section of 1 square millimetre (0.0016 sq in).) Further studies, such as one conducted in 2008, revealed that individual CNT shells have strengths of up to ≈100 gigapascals (15,000,000 psi), which is in agreement with quantum/atomistic models. Since carbon nanotubes have a low density for a solid of 1.3 to 1.4 g/cm3, its specific strength of up to 48,000 kN·m·kg−1 is the best of known materials, compared to high-carbon steel's 154 kN·m·kg−1.
Under excessive tensile strain, the tubes will undergo plastic deformation, which means the deformation is permanent. This deformation begins at strains of approximately 5% and can increase the maximum strain the tubes undergo before fracture by releasing strain energy.
Although the strength of individual CNT shells is extremely high, weak shear interactions between adjacent shells and tubes lead to significant reduction in the effective strength of multi-walled carbon nanotubes and carbon nanotube bundles down to only a few GPa. This limitation has been recently addressed by applying high-energy electron irradiation, which crosslinks inner shells and tubes, and effectively increases the strength of these materials to ≈60 GPa for multi-walled carbon nanotubes and ≈17 GPa for double-walled carbon nanotube bundles.
|Material||Young's modulus (TPa)||Tensile strength (GPa)||Elongation at break (%)|
|SWNTE||≈1 (from 1 to 5)||13–53||16|
EExperimental observation; TTheoretical prediction
On the other hand, there was evidence that in the radial direction they are rather soft. The first transmission electron microscope observation of radial elasticity suggested that even the van der Waals forces can deform two adjacent nanotubes. Later, nanoindentations with atomic force microscope were performed by several groups to quantitatively measure radial elasticity of multiwalled carbon nanotubes and tapping/contact mode atomic force microscopy was also performed on single-walled carbon nanotubes. Young's modulus of on the order of several GPa showed that CNTs are in fact very soft in the radial direction.
Radial direction elasticity of CNTs is important especially for carbon nanotube composites where the embedded tubes are subjected to large deformation in the transverse direction under the applied load on the composite structure.
One of the main problems in characterizing the radial elasticity of CNTs is the knowledge about the internal radius of the CNT; carbon nanotubes with identical outer diameter may have different internal diameter (or the number of walls). In 2008, a method using an atomic force microscope was introduced to determine the exact number of layers and hence the internal diameter of the CNT. In this way, mechanical characterization is more accurate.
Standard single-walled carbon nanotubes can withstand a pressure up to 25 GPa without [plastic/permanent] deformation. They then undergo a transformation to superhard phase nanotubes. Maximum pressures measured using current experimental techniques are around 55 GPa. However, these new superhard phase nanotubes collapse at an even higher, albeit unknown, pressure.
The bulk modulus of superhard phase nanotubes is 462 to 546 GPa, even higher than that of diamond (420 GPa for single diamond crystal).
The surface wettability of CNT is of importance for its applications in various settings. Although the intrinsic contact angle of graphite is around 90°, the contact angles of most as-synthesized CNT arrays are over 160°, exhibiting a superhydrophobic property. By applying a voltage as low as 1.3V, the extreme water repellant surface can be switched to a superhydrophilic one.
Multi-walled nanotubes are multiple concentric nanotubes precisely nested within one another. These exhibit a striking telescoping property whereby an inner nanotube core may slide, almost without friction, within its outer nanotube shell, thus creating an atomically perfect linear or rotational bearing. This is one of the first true examples of molecular nanotechnology, the precise positioning of atoms to create useful machines. Already, this property has been utilized to create the world's smallest rotational motor. Future applications such as a gigahertz mechanical oscillator are also envisioned.
As with any material, the existence of a crystallographic defect affects the material properties. Defects can occur in the form of atomic vacancies. High levels of such defects can lower the tensile strength by up to 85%. An important example is the Stone Wales defect, which creates a pentagon and heptagon pair by rearrangement of the bonds. Because of the very small structure of CNTs, the tensile strength of the tube is dependent on its weakest segment in a similar manner to a chain, where the strength of the weakest link becomes the maximum strength of the chain.
- M.-F. Yu; et al. (2000). "Strength and Breaking Mechanism of Multiwalled Carbon Nanotubes Under Tensile Load". Science. 287 (5453): 637–40. Bibcode:2000Sci...287..637Y. doi:10.1126/science.287.5453.637. PMID 10649994.
- R. S. Ruoff; et al. (1993). "Radial deformation of carbon nanotubes by van der Waals forces". Nature. 364 (6437): 514. Bibcode:1993Natur.364..514R. doi:10.1038/364514a0.
- I. Palaci; et al. (2005). "Radial Elasticity of Multiwalled Carbon Nanotubes". Physical Review Letters. 94: 175502. arXiv:1201.5501. Bibcode:2005PhRvL..94q5502P. doi:10.1103/PhysRevLett.94.175502.
- M.-F. Yu; et al. (2000). "Investigation of the Radial Deformability of Individual Carbon Nanotubes under Controlled Indentation Force". Physical Review Letters. 85 (7): 1456–9. Bibcode:2000PhRvL..85.1456Y. doi:10.1103/PhysRevLett.85.1456. PMID 10970528.
- Y.H.Yang; et al. (2011). "Radial elasticity of single-walled carbon nanotube measured by atomic force microscopy". Applied Physics Letters. 98: 041901. doi:10.1063/ApplPhysLett.98.041901.
- M. Minary-Jolandan, M.-F. Yu (2008). "Reversible radial deformation up to the complete flattening of carbon nanotubes in nanoindentation". Journal of Applied Physics. 103: 073516. Bibcode:2008JAP...103g3516M. doi:10.1063/1.2903438.