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Meisserite

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Meisserite
General
CategorySulfate mineral
Formula
(repeating unit)
Na5(UO2)(SO4)3(SO3OH)(H2O)
Crystal systemTriclinic
Space groupTriclinic - Pinacoidal (1)
Unit cella=5.32, b=11.51, c=13.56 [Å], α=102.96o, β=97.41o, γ=91.46o (approximated)
Identification
ColorPale green to yellowish-green
Crystal habitprismatic
Cleavage{100} and {001}, fair
TenacityVery brittle
Mohs scale hardness2
LusterVitreous
StreakVery pale yellow
DiaphaneityTranslucent to transparent
Density3.21 (calculated) (approximated)
Optical propertiesBiaxal (-)
Refractive indexnα=1.51, nβ=1.55, nγ=1.56 (approximated)
PleochroismColorless (X), pale yellow (Y), pale greenish-yellow (Z)
2V angle60o
DispersionWeak
Other characteristicsRadioactive
References[1][2][3]

Meisserite is a very rare uranium mineral with the formula Na5(UO2)(SO4)3(SO3OH)(H2O).[1][2] It is interesting in being a natural uranyl salt with hydrosulfate (hydroxysulfate) anion, a feature shared with belakovskiite.[4] Other chemically related minerals include fermiite, oppenheimerite, natrozippeite and plášilite.[5][6][7][8] Most of these uranyl sulphate minerals was originally found in the Blue Lizard mine, San Juan County, Utah, USA.[9]The mineral is named after Swiss mineralogist Nicolas Meisser.[3]

Association and origin

Meisserite is associated with other sulfate minerals: belakovskiite, johannite, chalcanthite, copiapite, ferrinatrite, and gypsum.[1]It is resulting from post-mining oxidation of the primary uranium mineral - uraninite.[3]

Crystal structure

The crystal structure of meisserite is unique. The building elements include:[1]

  • pentagonal bypiramids of uranyl groups
  • SO4 groups

These elements link to form chains. Sodium cations are bonded to oxygen atoms in chains, to hydrosulfate groups and water.

References

  1. ^ a b c d Plášil, J., Kampf, A.R., Kasatkin, A.V., and Marty, J., Škoda, R., Silva, S., and Čejka, J., 2013. Meisserite, Na5(UO2)(SO4)3(SO3OH)(H2O), a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine 77(7), 2975-2978
  2. ^ a b "Belakovskiite: Belakovskiite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  3. ^ a b c "Meisserite - Handbook of Mineralogy" (PDF). Handbookofmineralogy.org. Retrieved 2016-03-10.
  4. ^ "Belakovskiite: Belakovskiite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  5. ^ "Fermiite: Fermiite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  6. ^ "Oppenheimerite: Oppenheimerite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  7. ^ "Natrozippeite: Natrozippeite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  8. ^ "Plášilite: Plášilite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  9. ^ "Blue Lizard Mine, Chocolate Drop, Red Canyon, White Canyon District, San Juan Co., Utah, USA - Mindat.org". Mindat.org. Retrieved 2016-03-10.