3D model (JSmol)
|Molar mass||176.212 g/mol|
|Melting point||246 °C (475 °F; 519 K)|
|Boiling point||sublimes at 110 to 120 °C (230 to 248 °F; 383 to 393 K)|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Production and properties
Metaldehyde is obtained in moderate yields by treatment of acetaldehyde with various acid catalysts, such as hydrogen bromide. The reaction is reversible; upon heating to about 80 °C, metaldehyde reverts to acetaldehyde. Metaldehyde exists as a mixture of stereoisomers, molecules that differ with respect to the relative orientation of the methyl groups on the 8-membered ring.
As a pesticide
It is sold under various trade names as a molluscicide, including Antimilice, Ariotox, Blitzem (in Australia), Cekumeta, Deadline, Defender (in Australia), Halizan, Limatox, Limeol, Meta, Metason, Mifaslug, Namekil, Slug Fest Colloidel 25, and Slugit. Typically it is applied in the form of slug pellets, which normally include a wheat bait. Metaldehyde acts on the pest by contact or ingestion, and the aqueous environment inside the pest's cells readily hydrolyzes metaldehyde into acetaldehyde, the molecule associated with an alcohol hangover.
Metaldehyde is also used as a camping fuel, also for military purposes, or solid fuel in lamps. It may be purchased in a tablet form to be used in small stoves, and for preheating of Primus type stoves. It is sold under the trade name of "META" by Lonza Group of Switzerland; it can be included in the field ration of some nations.
Safety and Toxicity to Pets
Metaldehyde has a toxicity profile identical to that for acetaldehyde, being mildly toxic and a respiratory irritant at the 50 ppm level. In terms of water safety, during periods of rainfall metaldehyde pellets become agitated and can seep into natural water courses. The European Commission restricts metaldehyde levels to 0.1 ug/L in drinking water.
Metaldehyde-containing slug baits should be used with caution, as they are toxic to dogs and cats. If ingested by dogs or cats, tremors, drooling, and restlessness will proceed to seizures and death within hours to days if treatment is not started quickly. Due to this toxicity, pet owners may want to investigate alternatives which are not as toxic to pets, such as Ferric Sodium EDTA or Iron(III) phosphate. The metaldehyde tablets resemble sweetmeats and do not taste bad, making accidental ingestion possible by children or even by adults unaware of their true nature. Their use was popular during the inter-war period and several cases of poisoning resulted. Baits may contain a bittering agent to prevent accidental consumption by pets or children.
- Marc Eckert, Gerald Fleischmann, Reinhard Jira, Hermann M. Bolt, Klaus Golka "Acetaldehyde" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim. doi:10.1002/14356007.a01_031.pub2.
- Toxicology of metaldehyde
- Maher S; et al. (2016). "Direct Analysis and Quantification of Metaldehyde in Water using Reactive Paper Spray Mass Spectrometry". Nature Scientific Reports. 6: 35643. doi:10.1038/srep35643.
- "Pests in Gardens and Landscapes". University of California, Davis. Retrieved 2010-08-03.
- "Slugging Out Spring". Dr. Heidi Houchen, DVM. Archived from the original on 2012-07-18.
- Miller, Reginald (December 1928). "Poisoning by "Meta Fuel" Tablets (Metacetaldehyde)". Archives of Disease in Childhood. 3 (18): 292–295. doi:10.1136/adc.3.18.292. PMC . PMID 21031743.
- National Pesticide Information Center (NPIC) Information about pesticide-related topics.
- Get Rid of Slugs and Snails, Not Puppy Tails! Case Profile - National Pesticide Information Center
- Slugs and Snails - National Pesticide Information Center
- WHO/FAO Data sheet at inchem.org
- Slug controls (on Wikibooks)
- Metaldehyde in the Pesticide Properties DataBase (PPDB)