Metals of antiquity

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German amulet to protect against disease (18th century); it is made from an alloy of the seven alchemical metals: lead, tin, iron, gold, copper, mercury and silver.
Metal production in the ancient Middle East

The metals of antiquity are the seven metals which humans had identified and found use for in prehistoric times in Europe and the Middle East:[1] gold, silver, copper, tin, lead, iron, and mercury. These seven are the metals from which the modern world was forged; until the discovery of antimony in the 9th century,[2] and arsenic in the 13th[1] (both now classified as metalloids), these were the only known elemental metals, compared to approximately 90 known today.[3]

Characteristics[edit]

Melting point[edit]

The metals of antiquity generally have low melting points, with iron being the exception.

  • Mercury melts at −38.829 °C (-37.89 °F)[4] (being liquid at room temperature).
  • Tin melts at 231 °C (449 °F)[4]
  • Lead melts at 327 °C (621 °F)[4]
  • Silver at 961 °C (1763 °F)[4]
  • Gold at 1064 °C (1947 °F)[4]
  • Copper at 1084 °C (1984 °F)[4]
  • Iron is the outlier at 1538 °C (2800 °F),[4] making it far more difficult to melt in antiquity. Cultures developed ironworking proficiency at different rates; however, evidence from the Near East suggests that smelting was possible but impractical circa 1500 BC, and relatively commonplace across most of Eurasia by 500 BC.[5] However, until this period, generally known as the Iron Age, ironwork would have been impossible.

Extraction[edit]

While all the metals of antiquity but tin and lead occur natively, only gold and silver are commonly found as the native metal.

  • Gold and silver occur frequently in their native form
  • Mercury compounds are reduced to elemental mercury simply by low-temperature heating (500 °C).
  • Tin and iron occur as oxides and can be reduced with carbon monoxide (produced by, for example, burning charcoal) at 900 °C.
  • Copper and lead compounds can be roasted to produce the oxides, which are then reduced with carbon monoxide at 900 °C.
  • Meteoric iron is often found as the native metal and it was the earliest source for iron objects known to humanity

Rarity[edit]

While widely known during antiquity, most of these metals are by no means common.

  • Iron is the 4th most abundant element in the Earth's crust (approximately 50,000ppm, or 4.1% by mass)
  • Copper is next at 26th (50ppm)
  • Lead is 37th (14ppm)
  • Tin is 49th (2.2ppm)
  • Silver is 65th (70ppb)
  • Mercury is 66th (50ppb)
  • Gold is the 72nd (1.1ppb)

Yet all were known and available in tangible quantities in ancient times.

Additionally, despite being approximately 1,000 times more abundant in the crust than the next most abundant ancient metal, iron was the last to become available due to its melting point (see above), including requiring tools made from alloys such as bronze to work in quantity. Other comparably abundant elements, such as titanium (approximately 4,400ppm) and aluminium (approximately 83,000ppm),[6] were not available until the modern era. This was due almost entirely to the huge quantities of energy required to purify ores of these elements. Energy requirements and tool availability were, therefore, the primary limiting factors affecting an ancient civilisation's ability to access metals, rather than those metals' relative abundances.

See also[edit]

Symbolism[edit]

The practise of alchemy in the Western world, based on a Hellenistic and Babylonian approach to planetary astronomy, often ascribed a symbolic association between the seven then-known celestial bodies and the metals known to the Greeks and Babylonians during antiquity. Additionally, some alchemists and astrologers believed there was an association, sometimes called a rulership, between days of the week, the alchemical metals, and the planets that were said to hold "dominion" over them.[7][8]

Metal Body Day of week
Gold Sun Sunday
Silver Moon Monday
Iron Mars Tuesday
Mercury Mercury Wednesday
Tin Jupiter Thursday
Copper Venus Friday
Lead Saturn Saturday

References[edit]

  1. ^ a b Smith, Cyril Stanley; Forbes, R.J. (1957). "2: Metallurgy and Assaying". In Singer; Holmyard; Hall; Williams (eds.). A History Of Technology. Oxford University Press. p. 29.
  2. ^ George Sarton, Introduction to the History of Science. "We find in his writings [...] preparation of various substances (e.g., basic lead carbonatic, arsenic and antimony from their sulphides)."
  3. ^ Helmenstine, Anne Marie. "A List of All the Elements That Are Metals". ThoughtCo. Retrieved 24 December 2020.
  4. ^ a b c d e f g Winter, Mark. "The periodic table of the elements by WebElements". www.webelements.com.
  5. ^ Erb-Satullo, Nathaniel L. (December 2019). "The Innovation and Adoption of Iron in the Ancient Near East". Journal of Archaeological Research. 27 (4): 557–607. doi:10.1007/s10814-019-09129-6.
  6. ^ Darling, David. "terrestrial abundance of elements". www.daviddarling.info. Retrieved 3 January 2021.
  7. ^ Ball, Philip (2007). The Devil's Doctor: Paracelsus and the World of Renaissance Magic and Science. London: Arrow. ISBN 978-0-09-945787-9.
  8. ^ Kollerstrom, Nick. "The Metal-Planet Relationship: A Study of Celestial Influence". homepages.ihug.com.au. Retrieved 3 January 2021.

Further reading[edit]

  • http://www.webelements.com/ cited from these sources:
    • A.M. James and M.P. Lord in Macmillan's Chemical and Physical Data, Macmillan, London, UK, 1992.
    • G.W.C. Kaye and T.H. Laby in Tables of physical and chemical constants, Longman, London, UK, 15th edition, 1993.