Nd:YAG (neodymium-doped yttrium aluminium garnet; Nd:Y3Al5O12) is a crystal that is used as a lasing medium for solid-state lasers. The dopant, triply ionized neodymium, Nd(III), typically replaces a small fraction (1%) of the yttrium ions in the host crystal structure of the yttrium aluminium garnet (YAG), since the two ions are of similar size. It is the neodymium ion which provides the lasing activity in the crystal, in the same fashion as red chromium ion in ruby lasers.
- 1 Technology
- 2 Applications
- 3 Additional frequencies
- 4 Physical and chemical properties of Nd:YAG
- 5 References and notes
Nd:YAG lasers are optically pumped using a flashtube or laser diodes. These are one of the most common types of laser, and are used for many different applications. Nd:YAG lasers typically emit light with a wavelength of 1064 nm, in the infrared. However, there are also transitions near 940, 1120, 1320, and 1440 nm. Nd:YAG lasers operate in both pulsed and continuous mode. Pulsed Nd:YAG lasers are typically operated in the so-called Q-switching mode: An optical switch is inserted in the laser cavity waiting for a maximum population inversion in the neodymium ions before it opens. Then the light wave can run through the cavity, depopulating the excited laser medium at maximum population inversion. In this Q-switched mode, output powers of 250 megawatts and pulse durations of 10 to 25 nanoseconds have been achieved. The high-intensity pulses may be efficiently frequency doubled to generate laser light at 532 nm, or higher harmonics at 355, 266 and 213 nm.
Nd:YAG absorbs mostly in the bands between 730–760 nm and 790–820 nm. At low current densities krypton flashlamps have higher output in those bands than do the more common xenon lamps, which produce more light at around 900 nm. The former are therefore more efficient for pumping Nd:YAG lasers.
The amount of the neodymium dopant in the material varies according to its use. For continuous wave output, the doping is significantly lower than for pulsed lasers. The lightly doped CW rods can be optically distinguished by being less colored, almost white, while higher-doped rods are pink-purplish.
Other common host materials for neodymium are: YLF (yttrium lithium fluoride, 1047 and 1053 nm), YVO4 (yttrium orthovanadate, 1064 nm), and glass. A particular host material is chosen in order to obtain a desired combination of optical, mechanical, and thermal properties. Nd:YAG lasers and variants are pumped either by flashtubes, continuous gas discharge lamps, or near-infrared laser diodes (DPSS lasers). Prestabilized laser (PSL) types of Nd:YAG lasers have proved to be particularly useful in providing the main beams for gravitational wave interferometers such as LIGO, VIRGO, GEO600 and TAMA.
Nd:YAG lasers are used in ophthalmology to correct posterior capsular opacification, a condition that may occur after cataract surgery, and for peripheral iridotomy in patients with acute angle-closure glaucoma, where it has superseded surgical iridectomy. Frequency-doubled Nd:YAG lasers (wavelength 532 nm) are used for pan-retinal photocoagulation in patients with diabetic retinopathy. In certain cases these lasers are also used to treat eye floaters.
Nd:YAG lasers emitting light at 1064 nm have been the most widely used laser for laser-induced thermotherapy, in which benign or malignant lesions in various organs are ablated by the beam.
These lasers are also used extensively in the field of cosmetic medicine for laser hair removal and the treatment of minor vascular defects such as spider veins on the face and legs. Recently used for dissecting cellulitis, a rare skin disease usually occurring on the scalp.
In podiatry, the Nd:YAG laser is being used to treat onychomycosis, which is fungus infection of the toenail. The merits of laser treatment of these infections are not yet clear, and research is being done to establish effectiveness.
Nd:YAG lasers are used in manufacturing for engraving, etching, or marking a variety of metals and plastics, or for metal surface enhancement processes like laser peening. They are extensively used in manufacturing for cutting and welding steel, semiconductors and various alloys. For automotive applications (cutting and welding steel) the power levels are typically 1–5 kW. Super alloy drilling (for gas turbine parts) typically uses pulsed Nd:YAG lasers (millisecond pulses, not Q-switched). Nd:YAG lasers are also employed to make subsurface markings in transparent materials such as glass or acrylic glass. Lasers of up to 2 kW are used for selective laser melting of metals in additive layered manufacturing. In aerospace applications, they can be used to drill cooling holes for enhanced air flow/heat exhaust efficiency.
Nd:YAG lasers are also used in the non-conventional rapid prototyping process laser engineered net shaping (LENS).
Laser peening typically uses high energy (10 to 40 Joule), 10 to 30 nanosecond pulse, flashed laser systems to generate gigawatts of power on the surface of a part by focusing the laser beam down to a few millimeters in diameter. Laser peening is unlike the other manufacturing processes in that it neither heats or adds material; it is a mechanical process of cold working the metallic component to impart compressive residual stresses. Laser peening is widely used in gas fired turbine engines in both aerospace and power generation for component damage tolerance improvement and fatigue life and strength increase.
Cavity ring-down spectroscopy (CRDS)
The Nd:YAG may be used in the application of cavity ring-down spectroscopy, which is used to measure the concentration of some light-absorbing substance.
Laser-induced breakdown spectroscopy (LIBS)
A range of Nd:YAG lasers are used in analysis of elements in the periodic table. Though the application by itself is fairly new with respect to conventional methods such as XRF or ICP, it has proven to be less time consuming and a cheaper option to test element concentrations. A high-power Nd:YAG laser is focused onto the sample surface to produce plasma. Light from the plasma is captured by spectrometers and the characteristic spectra of each element can be identified, allowing concentrations of elements in the sample to be measured.
Nd:YAG lasers, mainly via their second and third harmonics, are widely used to excite dye lasers either in the liquid or solid state. They are also used as pump sources for vibronically broadened solid-state lasers such as Cr4+:YAG or via the second harmonic for pumping Ti:sapphire lasers.
Researchers from Japan's National Institutes of Natural Sciences are developing laser igniters that use YAG chips to ignite fuel in an engine, in place of a spark plug. The lasers use several 800 picosecond long pulses to ignite the fuel, producing faster and more uniform ignition. The researchers say that such igniters could yield better performance and fuel economy, with fewer harmful emissions.
For many applications, the infrared light is frequency-doubled or -tripled using nonlinear optical materials such as lithium triborate to obtain visible (532 nm, green) or ultraviolet light. Cesium lithium borate generates the 4th and 5th harmonics of the Nd:YAG 1064 nm fundamental wavelength. A green laser pointer is a frequency doubled Nd:YVO4 diode-pumped solid state laser (DPSS laser). Nd:YAG can be also made to lase at its non-principal wavelength. The line at 946 nm is typically employed in "blue laser pointer" DPSS lasers, where it is doubled to 473 nm.
Physical and chemical properties of Nd:YAG
Properties of YAG crystal
- Formula: Y3Al5O12
- Molecular weight: 596.7
- Crystal structure: Cubic
- Hardness: 8–8.5 (Moh)
- Melting point: 1970 °C (3540 °F)
- Density: 4.55 g/cm3
Refractive index of Nd:YAG
|Wavelength (μm)||Index n (25 °C)|
Properties of Nd:YAG @ 25 °C (with 1% Nd doping)
- Formula: Y2.97Nd0.03Al5O12
- Weight of Nd: 0.725%
- Atoms of Nd per unit volume: 1.38×1020 /cm3
- Charge state of Nd: 3+
- Emission wavelength: 1064 nm
- Transition: 4F3/2 → 4I11/2
- Duration of fluorescence: 230 μs
- Thermal conductivity: 0.14 W·cm−1·K−1
- Specific heat capacity: 0.59 J·g−1·K−1
- Thermal expansion: 6.9×10−6 K−1
- dn/dT: 7.3×10−6 K−1
- Young's modulus: 3.17×104 K·g/mm−2
- Poisson's ratio: 0.25
- Resistance to thermal shock: 790 W·m−1
References and notes
- Koechner §2.3, pp. 48–53.
- Geusic, J. E.; Marcos, H. M.; Van Uitert, L. G. (1964). "Laser oscillations in nd-doped yttrium aluminum, yttrium gallium and gadolinium garnets". Applied Physics Letters. 4 (10): 182. Bibcode:1964ApPhL...4..182G. doi:10.1063/1.1753928.
- Yariv, Amnon (1989). Quantum Electronics (3rd ed.). Wiley. pp. 208–211. ISBN 0-471-60997-8.
- Walter Koechner (1965) Solid-state laser engineering, Springer-Verlag, p. 507
- Koechner §6.1.1, pp. 251–264.
- Moskalik, K; A Kozlov; E Demin; E Boiko (2009). "The Efficacy of Facial Skin Cancer Treatment with High-Energy Pulsed Neodymium and Nd:YAG Lasers". Photomedicine Laser Surgery. 27 (2): 345–9. doi:10.1089/pho.2008.2327. PMID 19382838.
- Valcavi R, Riganti F, Bertani A, Formisano D, Pacella CM (November 2010). "Percutaneous Laser Ablation of Cold Benign Thyroid Nodules: A 3-Year Follow-Up Study in 122 Patients". Thyroid. 20 (11): 1253–61. doi:10.1089/thy.2010.0189. PMID 20929405.
- Pacella CM; Francica G; Di Lascio FM; Arienti V; Antico E; Caspani B; Magnolfi F; Megna AS; Pretolani S; Regine R; Sponza M; Stasi R . (June 2009). "Long-term outcome of cirrhotic patients with early hepatocellular carcinoma treated with ultrasound-guided percutaneous laser ablation: a retrospective analysis". Journal of Clinical Oncology. 27 (16): 2615–21. doi:10.1200/JCO.2008.19.0082. PMID 19332729.
- Pompili M; Pacella CM; Francica G; Angelico M; Tisone G; Craboledda P; Nicolardi E; Rapaccini GL; Gasbarrini G . (June 2010). "Percutaneous laser ablation of hepatocellular carcinoma in patients with liver cirrhosis awaiting liver transplantation". European Journal of Radiology. 74 (3): e6–e11. doi:10.1016/j.ejrad.2009.03.012. PMID 19345541.
- Yang J, Yin TL, Xu WM, Xia LB, Li AB, Hu J (2006). "Reproductive outcome of septate uterus after hysteroscopic treatment with neodymium:YAG laser". Photomedicine Laser Surgery. 24 (5): 625. doi:10.1089/pho.2006.24.625. PMID 17069494.
- Ledon, Jennifer A.; Savas, Jessica; Franca, Katlein; Chacon, Anna; Nouri, Keyvan (2012). "Laser and light therapy for onychomycosis: a systematic review". Lasers in Medical Science. doi:10.1007/s10103-012-1232-y. ISSN 0268-8921.
- Mozena, John; Haverstock, Brent (May 2010). "Laser care for onychomycosis: can it be effective?". Podiatry Today. 23 (5): 54–59.
- Mozena, John D.; Mitnick, Joshua P. (October 2009). "Emerging concepts in treating onychomycosis". Podiatry Today. 22 (10): 46–51.
- Palafox, Gilbert N.; Wicker, Ryan B.; Elkins, Christopher J. (2003). "Rapid in-vitro physiologic flow experimentation using rapid prototyping and particle image velocimetry" (pdf). 2003 Summer Bioengineering Conference: 419. Retrieved 2007-10-10.
- F. P. Schäfer (Ed.), Dye Lasers (Springer-Verlag, Berlin, 1990).
- F. J. Duarte, Tunable Laser Optics (Elsevier-Academic, New York, 2003).
- Coxworth, Ben (April 21, 2011). "Laser igniters could spell the end for the humble spark plug". Gizmag. Retrieved March 30, 2012.
- Pavel, Nicolaie; et al. (2011). "Composite, all-ceramics, high-peak power Nd:YAG/Cr4+:YAG monolithic micro-laser with multiple-beam output for engine ignition". Optics Express. 19 (10): 9378–9384. Bibcode:2011OExpr..19.9378P. doi:10.1364/OE.19.009378. PMID 21643194.