3D model (JSmol)
|Appearance||yellow oily liquid|
|Melting point||−40 °C (−40 °F; 233 K)|
|Boiling point||71 °C (160 °F; 344 K)|
|Solubility||soluble in benzene, chloroform, CCl4, CS2, PCl3|
|orthorhombic (below −40 °C)|
Std enthalpy of
|93 °C (199 °F; 366 K)|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
Nitrogen trichloride, also known as trichloramine, is the chemical compound with the formula NCl3. This yellow, oily, pungent-smelling liquid is most commonly encountered as a byproduct of chemical reactions between ammonia-derivatives and chlorine (for example, in swimming pools).
Preparation and structure
The compound is prepared by treatment of ammonium salts, such as ammonium nitrate with chlorine.
Nitrogen trichloride can form in small amounts when public water supplies are disinfected with monochloramine, and in swimming pools by disinfecting chlorine reacting with urea in urine and sweat from bathers. Nitrogen trichloride, trademarked as Agene, was used to artificially bleach and age flour, but was banned in 1949: In humans Agene was found to cause severe and widespread neurological disorders leading to its banning in 1947. Dogs that ate bread made from treated flour suffered epileptic-like fits; the toxic agent was methionine sulfoximine.
The chemistry of NCl3 has been well explored. It is moderately polar with a dipole moment of 0.6 D. The nitrogen center is basic but much less so than ammonia. It is hydrolyzed by hot water to release ammonia and hypochlorous acid.
- NCl3 + 3 H2O → NH3 + 3 HOCl
NCl3 explodes to give N2 and chlorine gas. This reaction is inhibited for dilute gases.
Nitrogen trichloride can irritate mucous membranes—it is a lachrymatory agent, but has never been used as such. The pure substance (rarely encountered) is a dangerous explosive, being sensitive to light, heat, even moderate shock, and organic compounds. Pierre Louis Dulong first prepared it in 1812, and lost two fingers and an eye in two explosions. In 1813, an NCl3 explosion blinded Sir Humphry Davy temporarily, inducing him to hire Michael Faraday as a co-worker. They were both injured in another NCl3 explosion shortly thereafter.
- Holleman, A. F.; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5.
- Shaw, CA; Bains, JS (1998). "Did consumption of flour bleached by the agene process contribute to the incidence of neurological disease?". Medical Hypotheses. 51 (6): 477–81. doi:10.1016/S0306-9877(98)90067-6. PMID 10052866.
- Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9.
- White, G. C. (1999). The Handbook of Chlorination and Alternative Disinfectants (4th ed.). Wiley. p. 322. ISBN 978-0-471-29207-4.
- "Health Hazard Evaluation Report: Investigation of Employee Symptoms at an Indoor Water Park" (pdf). NIOSH eNews. National Institute for Occupational Safety and Health. 6 (4). August 2008. HETA 2007-0163-3062.
- Thénard J. L.; Berthollet C. L. (1813). "Report on the work of Pierre Louis Dulong". Annales de Chimie et de Physique. 86 (6): 37–43.
- Thomas, J.M. (1991). Michael Faraday and The Royal Institution: The Genius of Man and Place (PBK). CRC Press. p. 17. ISBN 978-0-7503-0145-9.
- Jander, J. (1976). "Recent Chemistry and Structure Investigation of Nitrogen Triiodide, Tribromide, Trichloride, and Related Compounds". Advances in Inorganic Chemistry. 19: 1–63. doi:10.1016/S0065-2792(08)60070-9.
- Kovacic, P.; Lowery, M. K.; Field, K. W. (1970). "Chemistry of N-Bromamines and N-Chloramines". Chemical Reviews. 70 (6): 639–665. doi:10.1021/cr60268a002.
- Hartl, H.; Schöner, J.; Jander, J.; Schulz, H. (1975). "Die Struktur des Festen Stickstofftrichlorids (−125 °C)". Zeitschrift für Anorganische und Allgemeine Chemie. 413 (1): 61–71. doi:10.1002/zaac.19754130108.
- Cazzoli, G.; Favero, P. G.; Dal Borgo, A. (1974). "Molecular Structure, Nuclear Quadrupole Coupling Constant and Dipole Moment of Nitrogen Trichloride from Microwave Spectroscopy". Journal of Molecular Spectroscopy. 50 (1–3): 82–89. doi:10.1016/0022-2852(74)90219-7.
- Bayersdorfer, L.; Engelhardt, U.; Fischer, J.; Höhne, K.; Jander, J. (1969). "Untersuchungen an Stickstoff–Chlor-Verbindungen. V. Infrarot- und RAMAN-Spektren von Stickstofftrichlorid". Zeitschrift für Anorganische und Allgemeine Chemie. 366 (3–4): 169–179. doi:10.1002/zaac.19693660308.
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