Opalescence

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Rough common opal.
Precious opal showing play of color.

Opalescence refers to the optical phenomena displayed by the mineraloid gemstone opal[1] (hydrated silicon dioxide).[2] However, there are three notable types of opal (precious, common, and fire),[3] each with different optical effects, so the intended meaning varies depending on context. The optical effects seen in various types of opal are a result of refraction (precious and fire) or reflection (common) due to the layering, spacing, and size of the myriad microscopic silicon dioxide spheres and included water (or air) in its physical structure.[2][3] When the size and spacing of the silica spheres are relatively small, refracted blue-green colors are prevalent; when relatively larger, refracted yellow-orange-red colors are seen; and when larger yet, reflection yields a milky-hazy sheen.[2][4]

Precious Opal. The general definition of opalescent is a milky iridescence (play of color) displayed by an opal[5] which describes the visual effect of precious opal very well, and opalescence is commonly used in lay terms as a synonym for iridescence.[6]

Common Opal. In contrast, common opal does not display a play of color but often exhibits a hazy sheen of light from within the stone--the phenomenon that gemologists define strictly as opalescence.[7] This milky sheen displayed by opal is a form of adularescence.[4]

Fire Opal is a relatively transparent gemstone with a vivid yellow-orange-red color and rarely displays iridescence.[2]

Rayleigh scattering in opalescent glass: it appears blue from the side, but orange light shines through.[8]

In a physical sense, some cases of opalescence could be related to a type of dichroism seen in highly dispersed systems with little opacity. Due to Rayleigh scattering, a transparent material appears yellowish-red in transmitted white light and blue in the scattered light perpendicular to the transmitted light.[8] The phenomenon illustrated in the bottom photo is an example of the Tyndall effect.

See also[edit]

References[edit]

  1. ^ opalescent. 2019. In Noah Webster's 1828 American Dictionary of the English Language. Retrieved January 7, 2019, from https://1828.mshaffer.com/d/word/opalescent
  2. ^ a b c d Opal Gemstone Information. 2018. In Gemstone Select. Retrieved January 8, 2019, from https://www.gemselect.com/gem-info/opal/opal-info.php
  3. ^ a b Douma, M., curator. 2008. Opal. In Cause of Color. Retrieved January 8, 2019, from http://www.webexhibits.org/causesofcolor/15F.html
  4. ^ a b Smigel, Barbara W. 2012. Optical Phenomena in Gemstones. In Introduction to Gemology. Retrieved January 8, 2019, from http://www.bwsmigel.info/Lesson6/DE.Optical.Phenomena.html
  5. ^ opalescent. 2017. In Wiktionary, The Free Dictionary. Retrieved January 8, 2019 from https://en.wiktionary.org/w/index.php?title=opalescent&oldid=48339225.
  6. ^ opalescent. 2018. In Merriam-Webster Dictionary. Retrieved January 8, 2019, from https://www.merriam-webster.com/dictionary/opalescent
  7. ^ "Opal Description". 2019. Gemological Institute of America. Retrieved January 8, 2019, from https://www.gia.edu/opal-description.
  8. ^ a b Douma, M., curator. (2008). Blue and Red. In Cause of Color. Retrieved 2005 from http://www.webexhibits.org/causesofcolor/14B.html