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Photographic emulsion is a light-sensitive colloid. Most commonly, in silver-gelatin photography it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films of cellulose nitrate, cellulose acetate or polyester, paper or fabric.
Photographic emulsion is not a true emulsion, but a suspension of solid particles (silver halide) in a fluid (gelatin in solution). However, the word emulsion is customarily used in a photographic context. Gelatin or gum arabic layers sensitized with dichromate used in the dichromated colloid processes carbon and gum bichromate are sometimes called emulsions. Some processes do not have emulsions, such as platinum, cyanotype, salted paper, or kallitype.
Photographic emulsion is a fine suspension of insoluble light-sensitive crystals in a colloid sol, usually consisting of gelatin. The light-sensitive component is one or a mixture of silver halides: silver bromide, chloride and iodide. The gelatin is used as a permeable binder, allowing processing agents (e.g., developer, fixer, toners, etc.) in aqueous solution to enter the colloid without dislodging the crystals. Other polymer macromolecules are often blended, but gelatin has not been entirely replaced. The light-exposed crystals are reduced by the developer to black metallic silver particles that form the image. Colour films and papers usually have multiple layers of emulsion, with dye couplers added. Layers of dye are coated between emulsion layers to act as optical filters.
A solution of silver nitrate is mixed into a warm gelatin solution containing potassium bromide, sodium chloride or other alkali metal halides. A reaction precipitates fine crystals of insoluble silver halides that are light-sensitive. The silver halide is actually being 'peptized' by the gelatin. The type and quantity of gelatin used influences the final emulsion's properties. A pH buffer, crystal habit modifier, metal dopants, ripener, ripening restrainer, surfactants, defoamer, emulsion stabilizer and biocide are also used in emulsion making.
Most modern emulsions are "washed" to remove some of the reaction byproducts (potassium nitrate and excess salts). The "washing" or desalting step can be performed by ultrafiltration, dialysis, coagulation (using acylated gelatin), or a classic noodle washing method.
Emulsion making also incorporates steps to increase sensitivity by using chemical sensitizing agents and sensitizing dyes.
- Reilly, James M. Care and Identification of 19th-Century Photographic Prints. Eastman Kodak, Rochester, NY: 1986.