Platinum(II) bromide

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Platinum(II) bromide
Names
IUPAC name
Platinum(II) bromide
Other names
Platinous bromide
Platinum dibromide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.033.303
EC Number
  • 236-64-8
Properties
Br2Pt
Molar mass 354.886 g/mol
Appearance Dark green powder
Density 6.65 g/cm3, solid
Melting point 250 °C (482 °F; 523 K) (decomposes)
insol.
Structure
square planar
0 D
Hazards
Main hazards skin irritant
R-phrases (outdated) R36/37/38, R43
S-phrases (outdated) S24, S26, Template:S27/38
Related compounds
Other anions
Platinum(II) chloride
Related compounds
Platinum(IV) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Platinum bromide is the chemical compound with the formula PtBr2. This dark green powder is a common precursor to other platinum-bromide compounds. Like palladium chloride and palladium bromide, it is a compound that dissolves only in coordinating solvents or in the presence of donor ligands.

Illustrative use[edit]

Transition metal carbene complex of platinum can be prepared by heating platinum bromide with the imidazolium salt NHC precursors, and sodium acetate in dimethyl sulfoxide.[1]

References[edit]

  1. ^ Muehlhofer M.; Strassner T.; Herdtweck E.; Herrmann W.A. (2002). "Synthesis and structural characterization of novel bridged platinum(II) biscarbene complexes". Journal of Organometallic Chemistry. 660 (2): 121–126. doi:10.1016/S0022-328X(02)01670-4.