Polymer-fullerene bulk heterojunction solar cell

From Wikipedia, the free encyclopedia
When electrons of donor molecules are photoexcited, they jump from the HOMO to LUMO energy level. The electrons now in the LUMO energy level can travel to nearby acceptor molecules, which are more electronegative and thus lower in energy. The driving force for the electron transfer between donor and acceptor is the difference in LUMO energy levels.[1]

Polymer-fullerene bulk heterojunction solar cells are a type of solar cell researched in academic laboratories. Photovoltaic cells featuring a polymeric blend of organics have shown promise in a field largely dominated by inorganic (e.g. silicon) solar cells. Specifically, fullerene derivatives act as electron acceptors for donor materials like P3HT (poly-3-hexyl thiophene-2,5-diyl), creating a polymer-fullerene based photovoltaic cell.[2]

Some of the improvements that organic solar cells have over inorganic solar cells are that they are flexible and therefore can be applied to a larger range of surfaces.[3] They can also be produced much more easily via inkjet printing or spray deposition, and therefore are vastly cheaper to manufacture.[4] A downside is that, because they are not crystalline (like silicon), but instead are produced in a purposely disordered blend of electron-acceptor and -donor materials (hence the name bulk heterojunction), they have a limited efficiency of charge transport.[5]

However, the efficiencies of these new types of photovoltaic cells have risen from 2.5% in 2001, to 5% in 2006, to greater than 10% in 2011.[6] This is because improved methods for solution processing of acceptor and donor materials led to more efficient blending of the two materials. Further research can lead to polymer-fullerene based photovoltaic cells that approach the efficiency of current inorganic photovoltaic cells.


Three different schematic representations of blending electron donor and acceptor materials. (a) Bilayer representation, with efficient charge generation but poor charge transport.[10] (b) Solution processed representation, in which rapid drying leads to a randomized network of acceptor/donor blending, currently the most optimal way to blend. (c) Theoretical, ideal representation of acceptor/donor blending.[7]

Materials used in polymer-based photovoltaic cells are characterized by their total electron affinities and absorption power. The electron-rich, donor materials tend to be conjugated polymers with relatively high absorption power, whereas the acceptor in this case is a highly symmetric fullerene molecule with a strong affinity for electrons, ensuring sufficient electron mobility between the two.[3]

The typical structural layout of photovoltaic devices. Transparent, conductive ITO is applied onto glass, and a hole transport layer of PEDOT:PSS (poly(3,4-ethylenedioxythiophene)poly(styrenesulfonate)) on top of that. The photoactive layer is a blend of electron acceptor and donor atoms, and the cathode interlayer is a low work function metal used to lower the work function of the electrode on top to accept electrons.[8][9]

The arrangement of materials essentially determines the overall efficiency of the heterojunction solar cell. There are three donor-acceptor bulk morphologies: (a) the bilayer, (b) the bulk heterojunction, and (c) the “comb” structure. Typically, a polymer-fullerene bulk heterojunction solar cell has a layered structure.


The primary function of a solar cell is the conversion of light energy into electrical energy by means of the photovoltaic effect.[10] In particular, polymer-fullerene bulk heterojunction solar cells are promising because of their potential in low processing costs and mechanical flexibility in comparison to conventional inorganic solar cells.[11][12] Solution processing potentially allows reductions in manufacturing costs through screen printing, doctor blading, inkjet printing, and spray deposition at low temperatures.[13][14] To overcome the narrow spectral overlap of organic polymer absorption bands, experiments have blended conjugated polymer donors with high electron affinity fullerene derivatives as acceptors to extend the spectral sensitivity. Ternary solar cells are a promising approach to increased efficiency and light harvesting properties of organic photovoltaic cells (OPV).[15]


  1. ^ Dennler, Gilles; Scharber, Markus C.; Brabec, Christoph J. (6 April 2009). "Polymer-Fullerene Bulk-Heterojunction Solar Cells". Advanced Materials. 21 (13): 1323–1338. Bibcode:2009AdM....21.1323D. doi:10.1002/adma.200801283.
  2. ^ Kennedy, Robert D.; Ayzner, Alexander L.; Wanger, Darcy D.; Day, Christopher T; Halim, Merissa; Khan, Saeed I.; Tolbert, Sarah H.; Schwartz, Benjamin J.; Rubin, Yves (24 December 2008). "Self-Assembling Fullerenes for Improved Bulk-Heterojunction Photovoltaic Devices". Journal of the American Chemical Society. 130 (51): 17290–17292. doi:10.1021/ja807627u. PMID 19053441.
  3. ^ a b Mayer, Alex C.; Scully, Shawn R.; Hardin, Brian E.; Rowell, Michael W.; McGehee, Michael D. (November 2007). "Polymer-based solar cells". Materials Today. 10 (11): 28–33. doi:10.1016/S1369-7021(07)70276-6.
  4. ^ Nelson, Jenny (October 2011). "Polymer:fullerene bulk heterojunction solar cells". Materials Today. 14 (10): 462–470. doi:10.1016/S1369-7021(11)70210-3.
  5. ^ Deibel, Carsten; Dyakonov, Vladimir (1 September 2010). "Polymer–fullerene bulk heterojunction solar cells". Reports on Progress in Physics. 73 (9): 096401. arXiv:1003.0359. Bibcode:2010RPPh...73i6401D. doi:10.1088/0034-4885/73/9/096401. S2CID 118855668.
  6. ^ Scharber, M.C.; Sariciftci, N.S. (December 2013). "Efficiency of bulk-heterojunction organic solar cells". Progress in Polymer Science. 38 (12): 1929–1940. doi:10.1016/j.progpolymsci.2013.05.001. PMC 3837184. PMID 24302787.
  7. ^ Yang, Xiaoniu; Loos, Joachim; Veenstra, Sjoerd C.; Verhees, Wiljan J. H.; Wienk, Martijn M.; Kroon, Jan M.; Michels, Matthias A. J.; Janssen, René A. J. (April 2005). "Nanoscale Morphology of High-Performance Polymer Solar Cells". Nano Letters. 5 (4): 579–583. Bibcode:2005NanoL...5..579Y. doi:10.1021/nl048120i. PMID 15826090.
  8. ^ Zheng, Liping; Zhou, Qingmei; Deng, Xianyu; Yuan, Min; Yu, Gang; Cao, Yong (August 2004). "Methanofullerenes Used as Electron Acceptors in Polymer Photovoltaic Devices". The Journal of Physical Chemistry B. 108 (32): 11921–11926. doi:10.1021/jp048890i.
  9. ^ Kooistra, Floris B.; Knol, Joop; Kastenberg, Fredrik; Popescu, Lacramioara M.; Verhees, Wiljan J. H.; Kroon, Jan M.; Hummelen, Jan C. (February 2007). "Increasing the Open Circuit Voltage of Bulk-Heterojunction Solar Cells by Raising the LUMO Level of the Acceptor". Organic Letters. 9 (4): 551–554. doi:10.1021/ol062666p. PMID 17253699.
  10. ^ Scharber, M. C.; Mühlbacher, D.; Koppe, M.; Denk, P.; Waldauf, C.; Heeger, A. J.; Brabec, C. J. (17 March 2006). "Design Rules for Donors in Bulk-Heterojunction Solar Cells—Towards 10 % Energy-Conversion Efficiency". Advanced Materials. 18 (6): 789–794. Bibcode:2006AdM....18..789S. doi:10.1002/adma.200501717. S2CID 13842344.
  11. ^ Robaeys, Pieter; Bonaccorso, Francesco; Bourgeois, Emilie; D'Haen, Jan; Dierckx, Wouter; Dexters, Wim; Spoltore, Donato; Drijkoningen, Jeroen; Liesenborgs, Jori; Lombardo, Antonio; Ferrari, Andrea C.; Van Reeth, Frank; Haenen, Ken; Manca, Jean V.; Nesladek, Milos (25 August 2014). "Enhanced performance of polymer:fullerene bulk heterojunction solar cells upon graphene addition". Applied Physics Letters. 105 (8): 083306. Bibcode:2014ApPhL.105h3306R. doi:10.1063/1.4893777.
  12. ^ Cates, Nichole C.; Gysel, Roman; Beiley, Zach; Miller, Chad E.; Toney, Michael F.; Heeney, Martin; McCulloch, Iain; McGehee, Michael D. (9 December 2009). "Tuning the Properties of Polymer Bulk Heterojunction Solar Cells by Adjusting Fullerene Size to Control Intercalation". Nano Letters. 9 (12): 4153–4157. Bibcode:2009NanoL...9.4153C. doi:10.1021/nl9023808. PMID 19780570.
  13. ^ Li, G.; Yao, Y.; Yang, H.; Shrotriya, V.; Yang, G.; Yang, Y. (9 July 2007). ""Solvent Annealing" Effect in Polymer Solar Cells Based on Poly(3-hexylthiophene) and Methanofullerenes". Advanced Functional Materials. 17 (10): 1636–1644. doi:10.1002/adfm.200600624. S2CID 30133192.
  14. ^ Ma, W.; Yang, C.; Gong, X.; Lee, K.; Heeger, A. J. (October 2005). "Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology". Advanced Functional Materials. 15 (10): 1617–1622. doi:10.1002/adfm.200500211. S2CID 135626155.
  15. ^ Lee, Jae Kwan; Ma, Wan Li; Brabec, Christoph J.; Yuen, Jonathan; Moon, Ji Sun; Kim, Jin Young; Lee, Kwanghee; Bazan, Guillermo C.; Heeger, Alan J. (March 2008). "Processing Additives for Improved Efficiency from Bulk Heterojunction Solar Cells". Journal of the American Chemical Society. 130 (11): 3619–3623. doi:10.1021/ja710079w. PMID 18288842.