Potassium hypochlorite

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Potassium hypochlorite
Potassium hypochlorite
7778-66-7 YesY
ChemSpider 56409 YesY
EC Number 231-909-2
Jmol interactive 3D Image
PubChem 23665762
UN number 1791
Molar mass 90.55 g/mol
Appearance Liquid light grey
Odor Chlorine-like
Density 1.160 g/cm3
Melting point −2 °C (28 °F; 271 K)
Boiling point 102 °C (216 °F; 375 K) (decomposes)
ATC code D08[1]
Safety data sheet MSDS
R-phrases R22, R31
S-phrases (S1/2), S26, S45, S46
Related compounds
Other anions
Potassium chloride
Potassium chlorite
Potassium chlorate
Potassium perchlorate
Other cations
Sodium hypochlorite
Lithium hypochlorite
Calcium hypochlorite
Related compounds
Hypochlorous acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Potassium hypochlorite (chemical formula KClO) is the potassium salt of hypochlorous acid. It is used in variable concentrations, often diluted in water solution. It has a light grey color and a strong chlorine smell. It can be used as a disinfectant.


The compound is produced through the electrolysis of potassium chloride (KCl) salt with water.


Potassium hypochlorite is used for sanitizing surfaces as well as disinfecting drinking water. Because its degradation leaves behind potassium chloride rather than sodium chloride, its use has been promoted in agriculture, where addition of potassium to soil is desired.[1]


Potassium hypochlorite was first produced in 1789 by Claude Louis Berthollet in his laboratory located in Javel in Paris, France, by passing chlorine gas through a solution of potash lye. The resulting liquid, known as "Eau de Javel" ("Javel water"), was a weak solution of potassium hypochlorite. Due to production difficulties, the product was then modified using sodium instead of potassium, giving rise to sodium hypochlorite, widely used today as a disinfectant.

Safety and toxicology[edit]

Like sodium hypochlorite, potassium hypochlorite is an irritant. It can cause severe damage on contact with the skin, eyes, and mucous membranes.[2] Inhalation of a mist of KClO can cause bronchial irritation, difficulty breathing, and in severe cases pulmonary edema. Ingestion of strong concentrations can be lethal.[3]

Potassium hypochlorite is not considered a fire or explosive hazard by itself.[3] However, it can react explosively with numerous chemicals, including urea, ammonium salts, methanol, acetylene, and many organic compounds. Heating and acidification can produce toxic chlorine gas.[4]


  1. ^ "Enviro Klor: 12.5% POTASSIUM HYPOCHLORITE BLEACH ALTERNATIVE" (PDF). Retrieved 14 September 2014. 
  2. ^ , Environmental Protection Agency.2 March 2011.
  3. ^ a b "Material Safety Data Sheet: Potassium Hypochlorite" (PDF). http://www.kasteelchemicals.com/. Retrieved 15 September 2014.  External link in |website= (help)
  4. ^ "Potassium Hypochlorite". Chemical Book. Retrieved 15 September 2014.