Renewable Polyethylene

From Wikipedia, the free encyclopedia
Jump to: navigation, search

Biopolyethylene (also known as renewable polyethylene) is polyethylene made out of ethanol, which becomes ethylene after a dehydration process. It can be made from various feedstocks including sugar cane, sugar beet, and wheat grain.[1]

The final product (polyethylene), whose properties are identical to those of conventional polyethylene, physical properties for conversion into plastics products and also its recycling properties, is extremely versatile in terms of applications and is recyclable in the same chain established for conventional PE.

The first plant[edit]

Ethanol-based chemical pole, totally integrated from sugarcane to polyethylene, was recently announced by The Dow Chemical Company, in conjunction with Crystalsev, a large sugar and ethanol producer in Brazil.[2] The pole is said to be projected to produce 770 million pounds per year of renewable LLDPE (linear low-density polyethylene), will begin construction in 2008, and is slated to start production in 2011. The amount of ethanol needed to make one metric ton of polyethylene is roughly two metric tons, as dehydration takes half of the weight in water, from the sugar cane based ethanol, before converting into ethylene (C
). Braskem is the world leader in the production of biopolymer, with the Green Polyethylene – I’m green ™, a thermoplastic resin produced from ethylene made from sugarcane ethanol, a 100% renewable raw material which helps reduce greenhouse gas emissions. The production started in 2010 and is located in Triunfo, South of Brazil.


One of the main environmental benefits of the Green PE is the sequestration of roughly 2,15 ton of CO2 per ton of Green Polyethylene produced, which comes from the CO2 absorbed by the sugar cane while growing, minus the CO2 emitted through the production process. Renewable polyethylene is non-biodegradable and can be recycled in the same waste streams as traditional polyethylenes (HDPE, LDPE, LLDPE) as it is chemically identical.[3]


Producing feedstock for biopolyethylene relies upon intensive agriculture, potentially contributing to deforestation in order to clear land for agricultural use. Large-scale production of feedstock also requires inputs such as fossil fuels, fertilizers, and pesticides. A recent life cycle assessment on biopolymers and fossil-fuel based polymers showed various life cycle impacts associated with bio-PET, including acidification, carcinogens, and fossil fuel depletion.[4]


Today Braskem industrial unit has annual production capacity of 200 kton of Green Polyethylene.[5] Green PE has the same properties, performance and application versatility as fossil-based polyethylene, which makes it a drop-in replacement in the plastic production chain. For these same reasons, it is also recyclable in the same recycling chain used by traditional polyethylene. Because it is part of the portfolio of high-density polyethylene (HDPE) and linear low-density polyethylene (LLDPE) products, Green PE rapidly became an option for applications in rigid and flexible packaging, closures, bags and other products. In January 2014, the family of low-density polyethylene (LDPE) was added to the product portfolio, effectively covering additional applications in packaging and films.