Roald Hoffmann

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Roald Hoffmann
Roald Hoffmann.jpg
Roald Hoffmann
Born Roald Safran
(1937-07-18) July 18, 1937 (age 78)
Złoczów, Poland (now Ukraine)
Citizenship United States
Nationality American
Fields Chemistry
Institutions Cornell University
Alma mater Stuyvesant High School
Columbia University
Harvard University
Doctoral advisor William N. Lipscomb, Jr., Martin Gouterman
Known for reaction mechanisms
Notable awards Nobel Prize in Chemistry (1981)
National Medal of Science (1983)
NAS Award in Chemical Sciences (1986)
Priestley Medal (1990)
Lomonosov Gold Medal (2011)
Spouse Eva Börjesson (m. 1960; 2 children)

Roald Hoffmann (born Roald Safran; July 18, 1937)[1] is an American theoretical chemist who won the 1981 Nobel Prize in Chemistry. He has also published plays and poetry. He is the Frank H. T. Rhodes Professor of Humane Letters, Emeritus, at Cornell University, in Ithaca, New York.[2]

Early life[edit]

Escape from the Holocaust[edit]

Roald Hoffmann (2015)

Hoffmann was born in Złoczów, Poland (now Ukraine), to a Jewish family, and was named in honor of the Norwegian explorer Roald Amundsen. His parents were Clara (Rosen), a teacher, and Hillel Safran, a civil engineer.[3] After Germany invaded Poland and occupied the town, his family was placed in a labor camp where his father, who was familiar with much of the local infrastructure, was a valued prisoner. As the situation grew more dangerous, with prisoners being transferred to liquidation camps, the family bribed guards to allow an escape and arranged with a Ukrainian neighbor named Mikola Dyuk for Hoffman, his mother, two uncles and an aunt to hide in the attic and a storeroom of the local schoolhouse, where they remained for eighteen months, from January 1943 to June 1944, while Hoffmann was aged 5 to 7.

His father remained at the labor camp, but was able to occasionally visit, until he was tortured and killed by the Germans for his involvement in a plot to arm the camp prisoners. When she received the news, his mother attempted to contain her sorrow by writing down her feelings in a notebook her husband had been using to take notes on a relativity textbook he had been reading. While in hiding his mother kept Hoffmann entertained by teaching him to read and having him memorize geography from textbooks stored in the attic, then quizzing him on it. He referred to the experience as having been enveloped in a cocoon of love.[4]

Most of the rest of the family perished in the Holocaust, though one grandmother and a few others survived.[5] They migrated to the United States on the troop carrier Ernie Pyle in 1949.[6]

Hoffmann married Eva Börjesson in 1960. They have two children, Hillel Jan and Ingrid Helena.[7] Hoffmann visited Zolochiv with his adult son (by then a parent of a five-year-old) in 2006 and found that the attic where he had hidden was still intact, but the storeroom had been incorporated, ironically enough, into a chemistry classroom. In 2009, a monument to Holocaust victims was built in Zolochiv on Hoffmann's initiative.[8]

Academic credentials[edit]

Hoffmann graduated in 1955 from New York City's Stuyvesant High School,[9][10] where he won a Westinghouse science scholarship. He received his Bachelor of Arts degree at Columbia University (Columbia College) in 1958. He earned his Master of Arts degree in 1960 from Harvard University. He earned his Doctor of Philosophy degree from Harvard University while working[11][12][13][14][15] under joint supervision of Martin Gouterman and subsequent 1976 Nobel Prize in Chemistry winner William N. Lipscomb, Jr. Hoffman worked on the molecular orbital theory of polyhedral molecules.[9] Under Lipscomb's direction the Extended Hückel method was developed by Lawrence Lohr and by Roald Hoffmann.[12][16] This method was later extended by Hoffmann.[17] He went to Cornell in 1965 and has remained there, becoming professor emeritus.

Chemistry interests[edit]

External video
Buckminsterfullerene animated.gif
“Chemistry's Essential Tension”, Roald Hoffman, Dartmouth College
“Roald Hoffmann Shares Discovery Through Chemistry”, Roald Hoffman, National Science Foundation

Hoffmann is interested in the electronic structure of stable and unstable molecules, and in the study of transition states in reactions. He has investigated the structure and reactivity of both organic and inorganic molecules, and examined problems in organo-metallic and solid-state chemistry.[6] Hoffman has developed semiempirical and nonempirical computational tools and methods such as the extended Hückel method for determining molecular orbitals, which he proposed in 1963.[7]

With Robert Burns Woodward he developed rules for elucidating reaction mechanisms (the Woodward–Hoffmann rules). They realized that chemical transformations could be approximately predicted from subtle symmetries and asymmetries in the electron "orbitals" of complex molecules.[18] Their rules predict differing outcomes, such as the types of products that will be formed when two compounds are activated by heat compared with those produced under activation by light.[19] Hoffmann also introduced the isolobal analogy for predicting the bonding properties of organometallic compounds.[20] For this work Hoffmann received the 1981 Nobel Prize in chemistry, sharing it with Japanese chemist Kenichi Fukui, who had independently resolved similar issues. (Woodward was not included in the prize, which is given only to living persons.)[21]

Some of Hoffman's most recent work, with Neil Ashcroft and Vanessa Labet, examines bonding in matter under extreme high pressure.[6]

"What gives me the greatest joy in this work? That as we tease apart what goes on in hydrogen under pressures such as those that one finds at the center of the earth, two explanations subtly contend with each other... [physical and chemical] ... Hydrogen under extreme pressure is doing just what an inorganic molecule at 1 atmosphere does!"[6]

Artistic interests[edit]

The World Of Chemistry with Roald Hoffmann[edit]

Hoffmann is the co-host of the Annenberg/CPB educational series, The World of Chemistry, with Don Showalter.

Entertaining Science[edit]

Since the spring of 2001, Hoffmann has been the host of the monthly series Entertaining Science at New York City's Cornelia Street Cafe,[22] which explores the juncture between the arts and science.

Non-fiction[edit]

He has published books on the connections between art and science: Roald Hoffmann on the Philosophy, Art, and Science of Chemistry and Beyond the Finite: The Sublime in Art and Science.[23]

Poetry[edit]

Hoffmann is also a writer of poetry.[24] His collections include The Metamict State (1987, ISBN 0-8130-0869-7),[25] Gaps and Verges (1990, ISBN 0-8130-0943-X),[18] and Chemistry Imagined, co-produced with artist Vivian Torrence.[18][26]

Plays[edit]

He co-authored with Carl Djerassi the play Oxygen, about the discovery of oxygen and the experience of being a scientist. Hoffman's play, "Should’ve" (2006) about ethics in science in art, has been produced in workshops; as has a play based on his experiences in the holocaust, "We Have Something That Belongs to You" (2009).[23]

Music[edit]

Hoffmann and Brian Alan produced an English cover of Wei Wei's song "Dedication of Love", part of an international music project raising funds to help the victims of the Sichuan Earthquake.[27]

Honors and awards[edit]

Roald Hoffmann with the AIC Gold Medal

Nobel Prize in Chemistry[edit]

In 1981, Hoffmann received the Nobel Prize in Chemistry, which he shared with Kenichi Fukui "for their theories, developed independently, concerning the course of chemical reactions".[21][28]

Other awards[edit]

Hoffmann has won many other awards,[29] and is the recipient of more than 25 honorary degrees.[30]

  • Fellow of the American Academy of Arts and Sciences, elected 1971[33]
  • Inorganic Chemistry Award (American Chemical Society), 1982 (sponsored by Monsanto)[36]
  • Fellow of the American Philosophical Society, elected 1984[29]
  • Harvard Centennial Medalist, 1994[41]
  • Pimentel Award in Chemical Education, 1996[42]
  • Literaturpreis of the Verband der Chemischen Industrie for his textbook The Same and Not The Same, 1997[43]
  • Fellow of the American Chemical Society, 2009[47]

Hoffmann is a member of the International Academy of Quantum Molecular Science [48] and the Board of Sponsors of The Bulletin of the Atomic Scientists.[49]

In August 2007, the American Chemical Society held a symposium at its biannual national meeting to honor Hoffmann's 70th birthday.[50]

See also[edit]

References[edit]

  1. ^ Hoffmann's birth name was Roald Safran. Hoffmann is the surname adopted by his stepfather in the years after World War II
  2. ^ Hoffman, J. (2011). "Q&A: Chemical connector Roald Hoffmann talks about language, ethics and the sublime". Nature 480 (7376): 179. doi:10.1038/480179a.  edit
  3. ^ "Roald Hoffmann". HowStuffWorks. Retrieved October 4, 2013. 
  4. ^ The Long Ukrainian Winters featuring Roald Hoffman, lecture at the World Science Festival.
  5. ^ The Tense Middle by Roald Hoffmann, story on NPR. Retrieved September 29, 2006.
  6. ^ a b c d Hoffmann, Roald (2012). "Passerelles". Chemical Heritage Magazine 30 (2): 37. Retrieved 20 March 2015. 
  7. ^ a b "Roald Hoffmann - Biographical". Nobel Prize. Retrieved 20 March 2015. 
  8. ^ Holocaust monument dedicated in western Ukraine. Jewish Telegraphic Agency. July 20, 2009
  9. ^ a b Cardellini, Liberato (2007). "Looking for Connections: An Interview with Roald Hoffmann" (PDF). Journal of Chemical Education 84 (10): 1631–1635. Retrieved 3 April 2015. 
  10. ^ "Roald Hoffmann's land between chemistry, poetry and philosophy". Retrieved October 31, 2007. 
  11. ^ Hoffmann, R.; Lipscomb, W. N. (1962). "Theory of Polyhedral Molecules. III. Population Analyses and Reactivities for the Carboranes". The Journal of Chemical Physics 36 (12): 3489. doi:10.1063/1.1732484.  edit
  12. ^ a b Hoffmann, R.; Lipscomb, W. N. (1962). "Theory of Polyhedral Molecules. I. Physical Factorizations of the Secular Equation". The Journal of Chemical Physics 36 (8): 2179. doi:10.1063/1.1732849.  edit
  13. ^ Hoffmann, R.; Lipscomb, W. N. (1962). "Boron Hydrides: LCAO—MO and Resonance Studies". The Journal of Chemical Physics 37 (12): 2872. doi:10.1063/1.1733113.  edit
  14. ^ Hoffmann, R.; Lipscomb, W. N. (1962). "Sequential Substitution Reactions on B10H10−2 and B12H12−2". The Journal of Chemical Physics 37 (3): 520. Bibcode:1962JChPh..37..520H. doi:10.1063/1.1701367.  edit
  15. ^ Hoffmann, R.; Lipscomb, W. N. (1963). "Intramolecular Isomerization and Transformations in Carboranes and Substituted Polyhedral Molecules" (PDF). Inorganic Chemistry 2: 231. doi:10.1021/ic50005a066.  edit
  16. ^ Lipscomb WN. Boron Hydrides, W. A. Benjamin Inc., New York, 1963, Chapter 3.
  17. ^ Hoffmann, R. (1963). "An Extended Hückel Theory. I. Hydrocarbons". The Journal of Chemical Physics 39 (6): 1397. Bibcode:1963JChPh..39.1397H‎. doi:10.1063/1.1734456.  edit
  18. ^ a b c Browne, Malcolm W. (July 6, 1993). "SCIENTIST AT WORK: Roald Hoffmann; Seeking Beauty In Atoms". New York Times. Retrieved 20 March 2015. 
  19. ^ "Robert Burns Woodward". Chemical Heritage Foundation. Retrieved 20 March 2015. 
  20. ^ Hoffmann, Roald. "Building bridges between inorganic and organic chemistry - Nobel lecture, 8 December 1981" (PDF). Nobel Prize. Retrieved 20 March 2015. 
  21. ^ a b c The Nobel Prize in Chemistry 1981. Nobelprize.org. Retrieved on April 2, 2014.
  22. ^ "A Brief History". The Cornelia Street Café. Retrieved March 22, 2013. 
  23. ^ a b Romanska, Magda (June 14, 2014). "Between Art and Science: A Conversation with Roald Hoffmann". Cosmopolitan Review. Retrieved 20 March 2015. 
  24. ^ Amato, Ivan (August 21, 2007). "Roald Hoffmann: Chemist And Poet". Chemical & Engineering News. Retrieved 20 March 2015. 
  25. ^ "25 years ago: Roald Hoffmann publishes his poetry". Chemistry World. Energy Science Technology. 28 February 2013. Retrieved 20 March 2015. 
  26. ^ a b King, Julia (December 11, 1989). "Nobelist Roald Hoffmann: Chemist, Poet, Above All A Teacher". The Scientist. Retrieved 20 March 2015. 
  27. ^ BoA sings for Sichuan's Earthquake ! « BoA’s Jewelry Box. Boamyjewel.wordpress.com. June 7, 2008.
  28. ^ Roald Hoffmann at the Wayback Machine (archived April 22, 2008). Cornell Chemistry Faculty Research
  29. ^ a b c "Roald Hoffmann". NNDB Tracking the Entire World. Retrieved 3 April 2015. 
  30. ^ Ziabari, Kourosh (12 October 2012). "I Heard On Radio That I Was Awarded The Nobel Prize : Prof. Roald Hoffmann". Counter Currents. 
  31. ^ "ACS Award in Pure Chemistry". ACS Chemistry for Life. American Chemical Society. Retrieved 3 April 2015. 
  32. ^ "Award Winners". International Academy of Quantum Molecular Sciences. Retrieved 3 April 2015. 
  33. ^ "Professor Roald Hoffmann". American Academy of Arts & Sciences. Retrieved 3 April 2015. 
  34. ^ Annual Report - National Academy of Sciences. National Academy of Sciences (U.S.). p. 123. ISBN 9780217684378. Retrieved 3 April 2015. 
  35. ^ "Arthur C. Cope Award". ACS Chemistry for Life. American Chemical Society. Retrieved 3 April 2015. 
  36. ^ "ACS Award in Inorganic Chemistry". ACS Chemistry for Life. American Chemical Society. Retrieved 3 April 2015. 
  37. ^ "Print National Medal of Science Winners". Alfred P. Sloan Foundation. Retrieved 3 April 2015. 
  38. ^ "Roald Hoffmann (1937– )". National Medal of Science 50th Anniversary. National Science Foundation. Retrieved 3 April 2015. 
  39. ^ "Foreign Members". The Royal Society. Retrieved 3 April 2015. 
  40. ^ "Roald Hoffmann". Kungl. Vetenskapsakademien. Royal Swedish Academy of Sciences. Retrieved 3 April 2015. 
  41. ^ "GSAS Centennial Medalists". Graduate School of Arts and Sciences. Harvard University. Retrieved 3 April 2015. 
  42. ^ Hoffmann, Roald (September 1996). "Teach to Search: ACS 1996 Pimentel Award". Journal of Chemical Education 73 (9): A202. doi:10.1021/ed073pA202. Retrieved 3 April 2015. 
  43. ^ Koch, Wolfram. "Theaterdonner auf dem Chemiker-Kongress". 
  44. ^ "Kolos Medal Laureates". Warsaw University. Faculty of Chemistry. Retrieved 3 April 2015. 
  45. ^ "Past Winners of the AIC Gold Medal". Chemical Heritage Foundation. Retrieved 3 April 2015. 
  46. ^ "Chemist and writer Roald Hoffmann wins Grady-Stack Award for science journalism". ACS Chemistry for Life. American Chemical Society. Retrieved March 22, 2009. 
  47. ^ "ACS Fellows". ACS Chemistry for Life. American Chemical Society. Retrieved 3 April 2015. 
  48. ^ "Roald Hoffmann". International Academy of Quantum Molecular Sciences. Retrieved 3 April 2015. 
  49. ^ "Board of Sponsors". Bulletin of the Atomic Scientists. Retrieved 3 April 2015. 
  50. ^ Kovac, Jeffrey; Weisberg, Michael (2012). Roald Hoffmann on the philosophy, art, and science of chemistry. New York: Oxford University Press. ISBN 9780199755905. Retrieved 3 April 2015. 

External links[edit]