Scattering length

The scattering length in quantum mechanics describes low-energy scattering. It is defined as the following low-energy limit,

${\displaystyle \lim _{k\to 0}k\cot \delta (k)=-{\frac {1}{a}}\;,}$

where ${\displaystyle a}$ is the scattering length, ${\displaystyle k}$ is the wave number, and ${\displaystyle \delta (k)}$ is the s-wave phase shift. The elastic cross section, ${\displaystyle \sigma _{e}}$, at low energies is determined solely by the scattering length,

${\displaystyle \lim _{k\to 0}\sigma _{e}=4\pi a^{2}\;.}$

General concept

When a slow particle scatters off a short ranged scatterer (e.g. an impurity in a solid or a heavy particle) it cannot resolve the structure of the object since its de Broglie wavelength is very long. The idea is that then it should not be important what precise potential ${\displaystyle V(r)}$ one scatters off, but only how the potential looks at long length scales. The formal way to solve this problem is to do a partial wave expansion (somewhat analogous to the multipole expansion in classical electrodynamics), where one expands in the angular momentum components of the outgoing wave. At very low energy the incoming particle does not see any structure, therefore to lowest order one has only a spherical symmetric outgoing wave, the so-called s-wave scattering (angular momentum ${\displaystyle l=0}$). At higher energies one also needs to consider p and d-wave (${\displaystyle l=1,2}$) scattering and so on. The idea of describing low energy properties in terms of a few parameters and symmetries is very powerful, and is also behind the concept of renormalization.

Example

As an example on how to compute the s-wave (i.e. angular momentum ${\displaystyle l=0}$) scattering length for a given potential we look at the infinitely repulsive spherical potential well of radius ${\displaystyle r_{0}}$ in 3 dimensions. The radial Schrödinger equation (${\displaystyle l=0}$) outside of the well is just the same as for a free particle:

${\displaystyle -{\frac {\hbar ^{2}}{2m}}u''(r)=Eu(r),}$

where the hard core potential requires that the wave function ${\displaystyle u(r)}$ vanishes at ${\displaystyle r=r_{0}}$, ${\displaystyle u(r_{0})=0}$. The solution is readily found:

${\displaystyle u(r)=A\sin(kr+\delta _{s})}$.

Here ${\displaystyle k={\sqrt {2mE}}/\hbar }$ and ${\displaystyle \delta _{s}=-k\cdot r_{0}}$ is the s-wave phase shift (the phase difference between incoming and outgoing wave), which is fixed by the boundary condition ${\displaystyle u(r_{0})=0}$; ${\displaystyle A}$ is an arbitrary normalization constant.

One can show that in general ${\displaystyle \delta _{s}(k)\approx -k\cdot a_{s}+O(k^{2})}$ for small ${\displaystyle k}$ (i.e. low energy scattering). The parameter ${\displaystyle a_{s}}$ of dimension length is defined as the scattering length. For our potential we have therefore ${\displaystyle a=r_{0}}$, in other words the scattering length for a hard sphere is just the radius. (Alternatively one could say that an arbitrary potential with s-wave scattering length ${\displaystyle a_{s}}$ has the same low energy scattering properties as a hard sphere of radius ${\displaystyle a_{s}}$.) To relate the scattering length to physical observables that can be measured in a scattering experiment we need to compute the cross section ${\displaystyle \sigma }$. In scattering theory one writes the asymptotic wavefunction as (we assume there is a finite ranged scatterer at the origin and there is an incoming plane wave along the ${\displaystyle z}$-axis)

${\displaystyle \psi (r,\theta )=e^{ikz}+f(\theta ){\frac {e^{ikr}}{r}}}$

where ${\displaystyle f}$ is the scattering amplitude. According to the probability interpretation of quantum mechanics the differential cross section is given by ${\displaystyle d\sigma /d\Omega =|f(\theta )|^{2}}$ (the probability per unit time to scatter into the direction ${\displaystyle \mathbf {k} }$). If we consider only s-wave scattering the differential cross section does not depend on the angle ${\displaystyle \theta }$, and the total scattering cross section is just ${\displaystyle \sigma =4\pi |f|^{2}}$. The s-wave part of the wavefunction ${\displaystyle \psi (r,\theta )}$ is projected out by using the standard expansion of a plane wave in terms of spherical waves and Legendre polynomials ${\displaystyle P_{l}(\cos \theta )}$

${\displaystyle e^{ikz}\approx {\frac {1}{2ikr}}\sum _{l=0}^{\infty }(2l+1)P_{l}(\cos \theta )\left[(-1)^{l+1}e^{-ikr}+e^{ikr}\right]}$

By matching the ${\displaystyle l=0}$ component of ${\displaystyle \psi (r,\theta )}$ to the s-wave solution ${\displaystyle \psi (r)=A\sin(kr+\delta _{s})/r}$ (where we normalize ${\displaystyle A}$ such that the incoming wave ${\displaystyle e^{ikz}}$ has a prefactor of unity) one has

${\displaystyle f={\frac {1}{2ik}}(e^{2i\delta _{s}}-1)\approx \delta _{s}/k\approx -a_{s}}$

This gives

${\displaystyle \sigma ={\frac {4\pi }{k^{2}}}\sin ^{2}\delta _{s}=4\pi a_{s}^{2}}$

References

• Landau, L. D.; Lifshitz, E. M. (2003). Quantum Mechanics: Non-relativistic Theory. Amsterdam: Butterworth-Heinemann. ISBN 0-7506-3539-8.