Humphry Davy

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Sir Humphry Davy
Sir Humphry Davy, Bt by Thomas Phillips.jpg
Born (1778-12-17)17 December 1778
Penzance, Cornwall, England
Died 29 May 1829(1829-05-29) (aged 50)
Geneva, Switzerland
Nationality British
Fields Chemistry
Institutions Royal Society, Royal Institution
Known for Electrolysis, aluminium, sodium, potassium, calcium, magnesium, barium, boron, Davy lamp
Influences Benjamin Thompson
Influenced Michael Faraday, William Thomson
Notable awards Copley Medal (1805)
Rumford Medal (1816)
Royal Medal (1827)

Sir Humphry Davy, 1st Baronet PRS MRIA FGS (17 December 1778 – 29 May 1829) was a Cornish chemist and inventor,[1] who is best remembered today for isolating a series of substances for the first time: potassium and sodium in 1808 and calcium, strontium, barium, magnesium and boron the following year, as well as discovering the elemental nature of chlorine and iodine. He also studied the forces involved in these separations, inventing the new field of electrochemistry. Berzelius called Davy's 1806 Bakerian Lecture On Some Chemical Agencies of Electricity[2] "one of the best memoirs which has ever enriched the theory of chemistry."[3] He was a Baronet, President of the Royal Society (PRS), Member of the Royal Irish Academy (MRIA), and Fellow of the Geological Society (FGS). He also invented the Davy Lamp and a very early form of incandescent light bulb.

Education, apprenticeship and poetry[edit]

Davy was born in Penzance, Cornwall in England on 17 December 1778. Davy's brother, John Davy, writes that the society of their hometown was characterised by "an almost unbounded credulity respecting the supernatural and monstrous [...] Amongst the middle and higher classes, there was little taste for literature, and still less for science [...] Hunting, shooting, wrestling, cockfighting, generally ending in drunkenness, were what they most delighted in".[4] At the age of six, Davy was sent to the grammar school at Penzance. Three years later, his family moved to Varfell, near Ludgvan, and subsequently, in term-time Davy boarded with John Tonkin, his godfather and later his guardian.[1] On leaving Penzance grammar school in 1793, Tonkin paid for Davy to attend Truro Grammar School in 1793 to finish his education under the Rev Dr Cardew, who, in a letter to Davies Gilbert, said dryly: "I could not discern the faculties by which he was afterwards so much distinguished." Yet, Davy entertained his school friends with writing poetry, Valentines, and telling stories from One Thousand and One Nights. Reflecting on his school days, in a letter to his mother, Davy wrote: "Learning naturally is a true pleasure; how unfortunate then it is that in most schools it is made a pain."[5] Davy said: "I consider it fortunate I was left much to myself as a child, and put upon no particular plan of study... What I am I made myself."[6] Davy's brother praises his "native vigour": "there belonged, however, to his mind, it cannot be doubted, the genuine quality of genius, or of that power of intellect which exalts its possessor above the crowd.[4]

After Davy's father died in 1794, Tonkin apprenticed him to John Bingham Borlase, a surgeon with a practice in Penzance. Davy's indenture is dated 10 February 1795. In the apothecary's dispensary, Davy became a chemist, and conducted his earliest chemical experiments in a garret in Tonkin's house. Davy's friends said: "This boy Humphry is incorrigible. He will blow us all into the air." His elder sister complained of the ravages made on her dresses by corrosive substances.[6] Davy was taught French by a refugee priest, and in 1797 read Lavoisier's Traité élémentaire de chimie: much of his future work can be seen as reacting against Lavoisier's work and the dominance of French chemists.

As a poet, over one hundred and sixty manuscript poems were written by Davy, the majority of which are found in his personal notebooks. Most of his written poems were not published, and he chose instead to share a few of them with his friends. Eight of his known poems were published. His poems reflected his views on both his career and also his pereception of certain aspects of human life. He wrote on human endeavours and aspects of life like death, metaphysics, geology, natural theology and chemistry.[7]

John Ayrton Paris remarked that poetry written by the young Davy "bear the stamp of lofty genius". Davy's first preserved poem entitled The Sons of Genius is dated 1795 and marked by the usual immaturity of youth. Other poems written in the following years, especially On the Mount's Bay and St Michael's Mount, are descriptive verses, showing sensibility but no true poetic imagination. Three of Davy's paintings from around 1796 have been donated to the Penlee House museum at Penzance. One is of the view from above Gulval showing the church, Mount's Bay and the Mount, while the other two depict Loch Lomond in Scotland.[8][9]

While writing verses at the age of 17 in honour of his first love, he was eagerly discussing the question of the materiality of heat with his Quaker friend and mentor Robert Dunkin. Dunkin remarked: 'I tell thee what, Humphry, thou art the most quibbling hand at a dispute I ever met with in my life.' One winter day he took Davy to the Larigan River,[10] To show him that rubbing two plates of ice together developed sufficient energy by motion, to melt them, and that after the motion was suspended, the pieces were united by regelation. It was a crude form of analogous experiment exhibited by Davy in the lecture-room of the Royal Institution that elicited considerable attention.[6] As professor at the Royal Institution, Davy repeated many of the ingenious experiments he learned from his friend and mentor, Robert Dunkin.

Even though he initially started writing his poems albeit haphazardly, as a reflection of his views on his career, and on life generally, most of his final poems concentrated more on immortality and death. This was after he started experiencing failing health and a decline both in health and career.[11]

Early scientific interests[edit]

Davies Giddy met Davy in Penzance carelessly swinging on the half-gate of Dr Borlase's house, and interested by his talk invited him to his house at Tredrea and offered him the use of his library. This led to an introduction to Dr Edwards, who lived at Hayle Copper House. Edwards was a lecturer in chemistry in the school of St. Bartholomew's Hospital. He permitted Davy to use his laboratory and possibly directed his attention to the floodgates of the port of Hayle, which were rapidly decaying as a result of the contact between copper and iron under the influence of seawater. Galvanic corrosion was not understood at that time, but the phenomenon prepared Davy's mind for subsequent experiments on ship's copper sheathing. Gregory Watt, son of James Watt, visited Penzance for his health's sake, and while lodging at the Davy's house became a friend and gave him instructions in chemistry. Davy was acquainted with the Wedgwood family, who spent a winter at Penzance.[6]

Thomas Beddoes and John Hailstone were engaged in a geological controversy on the rival merits of the Plutonian and Neptunist hypotheses. They travelled together to examine the Cornish coast accompanied by Davies Gilbert and made Davy's acquaintance. Beddoes, who had established at Bristol a 'Pneumatic Institution,' needed an assistant to superintend the laboratory. Gilbert recommended Davy, and in 1798 Gregory Watt showed Beddoes the Young man's Researches on Heat and Light, which were subsequently published by him in the first volume of West-Country Contributions. After prolonged negotiations, mainly by Gilbert, Mrs Davy and Borlase consented to Davy's departure, but Tonkin wished him to remain in his native town as a surgeon, and altered his will when he found that Davy insisted on going to Dr Beddoes.

In 1802, Humphry Davy had what was then, the most powerful electrical battery in the world at the Royal Institution. With it, Davy created the first incandescent light by passing electric current through a thin strip of platinum, chosen because the metal had an extremely high melting point. It was neither sufficiently bright nor long lasting enough to be of practical use, but demonstrated the principle. By 1806 he was able to demonstrate a much more powerful form of electric lighting to the Royal Society in London. It was an early form of arc light which produced its illumination from an electric arc created between two charcoal rods.

Pneumatic Institution[edit]

On 2 October 1798, Davy joined the Pneumatic Institution at Bristol. It had been established to investigate the medical powers of factitious airs and gases (gases produced experimentally or artificially), and Davy was to superintend the various experiments. The arrangement agreed between Dr Beddoes and Davy was generous, and enabled Davy to give up all claims on his paternal property in favour of his mother. He did not intend to abandon the medical profession and was determined to study and graduate at Edinburgh, but he soon began to fill parts of the institution with voltaic batteries. While living in Bristol, Davy met the Earl of Durham, who was a resident in the institution for his health, and became close friends with Gregory Watt, James Watt, Samuel Taylor Coleridge and Robert Southey, all of whom became regular users of nitrous oxide (laughing gas), to which Davy became addicted. The gas was first synthesized in 1772 by the natural philosopher and chemist Joseph Priestley, who called it phlogisticated nitrous air (see phlogiston).[12] Priestley described his discovery in the book Experiments and Observations on Different Kinds of Air (1775), in which he described how to produce the preparation of "nitrous air diminished", by heating iron filings dampened with nitric acid.[13]

James Watt built a portable gas chamber to facilitate Davy's experiments with the inhalation of nitrous oxide. At one point the gas was combined with wine to judge its efficacy as a cure for hangover (his laboratory notebook indicated success). The gas was popular among Davy's friends and acquaintances, and he noted that it might be useful for performing surgical operations.[14] Anesthetics were not regularly used in medicine or dentistry until decades after Davy's death.[15]

Davy threw himself energetically into the work of the laboratory and formed a long romantic friendship with Mrs Anna Beddoes, the novelist Maria Edgeworth's sister, who acted as his guide on walks and other fine sights of the locality. The critic Maurice Hindle was the first to reveal that Davy and Anna had written poems for each other.[16] Wahida Amin has transcribed and discussed a number of poems written between 1803 and 1808 to "Anna" and one to her infant child.[17] In December 1799 Davy visited London for the first time and extended his circle of friends. Davy features in the diary of William Godwin, with their first meeting recorded for 4 December 1799.[18]

In the gas experiments Davy ran considerable risks. His respiration of nitric oxide which may have combined with air in the mouth to form nitric acid (HNO3),[19] severely injured the mucous membrane, and in Davy's attempt to inhale four quarts of "pure hydrocarbonate" gas in an experiment with carbon monoxide he "seemed sinking into annihilation." On being removed into the open air, Davy faintly articulated, "I do not think I shall die,"[19] but some hours elapsed before the painful symptoms ceased.[6] Davy was able to take his own pulse as he staggered out of the laboratory and into the garden, and he described it in his notes as "threadlike and beating with excessive quickness".

In this year the first volume of the West-Country Collections was issued. Half consisted of Davy's essays On Heat, Light, and the Combinations of Light, On Phos-oxygen and its Combinations, and on the Theory of Respiration. On 22 February 1799 Davy, wrote to Davies Gilbert, "I am now as much convinced of the non-existence of caloric as I am of the existence of light." In another letter to Gilbert, on 10 April, Davy informs him: "I made a discovery yesterday which proves how necessary it is to repeat experiments. The gaseous oxide of azote (the laughing gas) is perfectly respirable when pure. It is never deleterious but when it contains nitrous gas. I have found a mode of making it pure." He said that he breathed sixteen quarts of it for nearly seven minutes, and that it "absolutely intoxicated me." During this year Davy published his Researches, Chemical and Philosophical, chiefly concerning Nitrous Oxide and its Respiration. In after years Davy regretted he had ever published these immature hypotheses, which he subsequently designated "the dreams of misemployed genius which the light of experiment and observation has never conducted to truth."[6]

Davy's later time at the institution was spent partially in experimentation. In 1800, Davy informed Gilbert that he had been "repeating the galvanic experiments with success" in the intervals of the experiments on the gases, which "almost incessantly occupied him from January to April."

William Wordsworth and Samuel Taylor Coleridge moved to the Lake District in 1800, and asked Davy to deal with the Bristol publishers of the Lyrical Ballads, Biggs & Cottle. Coleridge asked Davy to proofread the second edition of the Lyrical Ballads, the first to contain Wordsworth's Preface in a letter dated 16 July 1800: "Will you be so kind as just to look over the sheets of the lyrical Ballads".[20] Wordsworth subsequently wrote to Davy on 29 July 1800, sending him the first manuscript sheet of poems and asking him specifically to correct: "any thing you find amiss in the punctuation a business at which I am ashamed to say I am no adept".[21] Wordsworth was ill in the autumn of 1800 and slow in sending poems for the second edition; the volume appeared on 26 January 1801 even though it was dated 1800.[22] While it is impossible to know whether Davy was at fault, this edition of the Lyrical Ballads contained many errors, including the poem "Michael" being left incomplete.[23] In a personal notebook marked on the front cover "Clifton 1800 From August to Novr", Davy wrote his own Lyrical Ballad: "As I was walking up the street".[24] Wordsworth features in Davy's poem as the recorder of ordinary lives in the line: "By poet Wordsworths Rymes" [sic].

Royal Institution[edit]

In 1799, Count Rumford had proposed the establishment in London of an 'Institution for Diffusing Knowledge', i.e. the Royal Institution. The house in Albemarle Street was bought in April 1799.[25] Rumford became secretary to the institution, and Dr Thomas Garnett was the first lecturer.

1802 satirical cartoon by James Gillray showing a Royal Institution lecture on pneumatics, with Davy holding the bellows and Count Rumford looking on at extreme right. Dr Thomas Garnett is the lecturer, holding the victim's nose.

In February 1801 Davy was interviewed by the committee of the Royal Institution, comprising Joseph Banks, Benjamin Thompson (who had been appointed Count Rumford) and Henry Cavendish. Davy wrote to Davies Gilbert on 8 March 1801 about the offers made by Banks and Thompson, a possible move to London and the promise of funding for his work in galvanism. He also mentioned that he might not be collaborating further with Beddoes on therapeutic gases. The next day Davy left Bristol to take up his new post at the Royal Institution,[15] it having been resolved 'that Humphry Davy be engaged in the service of the Royal Institution in the capacity of assistant lecturer in chemistry, director of the chemical laboratory, and assistant editor of the journals of the institution, and that he be allowed to occupy a room in the house, and be furnished with coals and candles, and that he be paid a salary of 100l. per annum.'[6]

On 25 April 1801, Davy gave his first lecture on the relatively new subject of 'Galvanism'. He and his friend Coleridge had had many conversations about the nature of human knowledge and progress, and Davy's lectures gave his audience a vision of human civilisation brought forward by scientific discovery. "It [science] has bestowed on him powers which may almost be called creative; which have enabled him to modify and change the beings surrounding him, and by his experiments to interrogate nature with power, not simply as a scholar, passive and seeking only to understand her operations, but rather as a master, active with his own instruments."[15] The first lecture garnered rave reviews, and by the June lecture Davy wrote to John King that his last lecture had attendance of nearly 500 people. "There was Respiration, Nitrous Oxide, and unbounded Applause. Amen!"[15]

Davy's lectures also included spectacular and sometimes dangerous chemical demonstrations for his audience, a generous helping of references to divine creation, and genuine scientific information. Not only a popular lecturer, the young and handsome Davy acquired a huge female following around London, and nearly half of the attendees pictured in Gillray's cartoon are female. When Davy's lecture series on Galvanism ended, he progressed to a new series on Agricultural Chemistry, and his popularity continued to skyrocket. By June 1802, after just over a year at the Institution and at the age of 23, Davy was nominated to full lecturer at the Royal Institution of Great Britain. Garnett quietly resigned, citing health reasons.[15]

In November 1804 Davy became a Fellow of the Royal Society, over which he would later preside. He was one of the founding members of the Geological Society in 1807[26] and was elected a foreign member of the Royal Swedish Academy of Sciences in 1810 and a Foreign Honorary Member of the American Academy of Arts and Sciences in 1822.[27]

Discovery of new elements[edit]

Sodium metal, about 10 g, under oil
Magnesium metal crystals

Davy was a pioneer in the field of electrolysis using the voltaic pile to split common compounds and thus prepare many new elements. He went on to electrolyse molten salts and discovered several new metals, including sodium and potassium, highly reactive elements known as the alkali metals. Davy discovered potassium in 1807, deriving it from caustic potash (KOH). Before the 19th century, no distinction had been made between potassium and sodium. Potassium was the first metal that was isolated by electrolysis. Davy isolated sodium in the same year by passing an electric current through molten sodium hydroxide.

Discovery of calcium, magnesium, strontium and barium[edit]

During the first half of 1808, Davy conducted a series of further electrolysis experiments on alkaline earths including lime, magnesia, strontites and barytes. At the beginning of June, Davy received a letter from the Swedish chemist Berzelius claiming that he, in conjunction with Dr. Pontin, had successfully obtained amalgams of calcium and barium by electrolysing lime and barytes using a mercury cathode. Davy managed to successfully repeat these experiments almost immediately and expanded Berzelius' method to strontites and magnesia.[28] He noted that while these amalgams oxidated in only a few minutes when exposed to air they could be preserved for lengthy periods of time when submerged in naphtha before becoming covered with a white crust.[29] On 30 June 1808 Davy reported to the Royal Society that he had successfully isolated four new metals which he named barium, calcium, strontium and magnium (later changed to magnesium) which were subsequently published in the Philosophical Transactions. Although Davy conceded magnium was an "undoubtedly objectionable" name he argued the more appropriate name magnesium was already being applied to metallic manganese and wished to avoid creating an equivocal term.[30]

The observations gathered from these experiments also led to Davy isolating boron in 1809.

Discovery of chlorine[edit]

Chlorine was discovered in 1774 by Swedish chemist Carl Wilhelm Scheele, who called it "dephlogisticated marine acid" (see phlogiston theory) and mistakenly thought it contained oxygen. Davy showed that the acid of Scheele's substance, called at the time oxymuriatic acid, contained no oxygen. This discovery overturned Lavoisier's definition of acids as compounds of oxygen. In 1810, chlorine was given its current name by Humphry Davy, who insisted that chlorine was in fact an element.[31] The name chlorine, chosen by Davy for "one of [the substance's] obvious and characteristic properties - its colour", comes from the Greek χλωρος (chlōros), meaning green-yellow.

Popular public figure[edit]

Davy revelled in his public status, as his lectures gathered many spectators. He became well known in 1799 due to his experiments with the physiological action of some gases, including laughing gas (nitrous oxide), with enthusiastic experimental subjects including his poet friends Robert Southey and Samuel Taylor Coleridge.[19]

Davy later injured himself in a laboratory accident with nitrogen trichloride.[32] Pierre Louis Dulong first prepared this compound in 1812, and lost two fingers and an eye in two separate explosions with it. In a letter to John Children, Davy wrote: "It must be used with great caution. It is not safe to experiment upon a globule larger than a pin's head. I have been severely wounded by a piece scarcely bigger. My sight, however, I am informed, will not be injured".[33] Davy's accident induced him to hire Michael Faraday as a co-worker, particularly for assistance with handwriting and record keeping.[33]

European travels[edit]

Sir Humphry Davy, 1830 engraving based on the painting by Sir Thomas Lawrence (1769–1830)
A diamond crystal in its matrix

In 1812, Davy was knighted and gave up his lecturing position at the Royal Institution. He was given the title of Honorary Professor of Chemistry.[33] He gave a farewell lecture to the Institution, and married a wealthy widow, Jane Apreece. (While Davy was generally acknowledged as being faithful to his wife, their relationship was stormy, and in later years he travelled to continental Europe alone.)

Davy then published his Elements of Chemical Philosophy, part 1, volume 1, though other parts of this title were never completed. He made notes for a second edition, but it was never required.[33] In October 1813, he and his wife, accompanied by Michael Faraday as his scientific assistant (and valet), travelled to France to collect a medal that Napoleon Bonaparte had awarded Davy for his electro-chemical work. Faraday noted that 'Tis indeed a strange venture at this time, to trust ourselves in a foreign and hostile country, where so little regard is had to protestations of honour, that the slightest suspicion would be sufficient to separate us for ever from England, and perhaps from life'.[34] Davy's party sailed from Plymouth to Morlaix by cartel, where they were searched.[33]

Upon reaching Paris, Davy was a guest of honour at a meeting of the First Class of the Institut de France and met with André-Marie Ampère and other French chemists.[33]

While in Paris, Davy attended lectures at the Ecole Polytechnique, including those by Joseph Louis Gay-Lussac on a mysterious substance isolated by Bernard Courtois. Davy wrote a paper for the Royal Society on the element, which is now called iodine.[35][36] This led to a dispute between Davy and Gay-Lussac on who had the priority on the research.[33]

Davy's party did not meet Napoleon in person, but they did visit the Empress Joséphine de Beauharnais at the Château de Malmaison.[33] The party left Paris in December 1813, travelling south to Italy.[37] They sojourned in Florence, where using the burning glass of the Grand Duke of Tuscany [38] in a series of experiments conducted with Faraday's assistance, Davy succeeded in using the sun's rays to ignite diamond, proving it is composed of pure carbon.

Davy's party continued to Rome, where he undertook experiments on iodine and chlorine and on the colours used in ancient paintings. This was the first chemical research on the pigments used by artists.[33]

He also visited Naples and Mount Vesuvius, where he collected samples of crystals. By June 1814, they were in Milan, where they met Alessandro Volta, and then continued north to Geneva. They returned to Italy via Munich and Innsbruck, and when their plans to travel to Greece and Istanbul were abandoned after Napoleon's escape from Elba, they returned to England.

After the Battle of Waterloo, Davy wrote to Lord Liverpool urging that the French be treated with severity.[33]

Davy lamp[edit]

The Davy lamp
Statue of Davy in Penzance, Cornwall, holding his safety lamp

After his return to England in 1815, Davy began experimenting with lamps that could be used safely in coal mines. The Revd Dr Robert Gray of Bishopwearmouth in Sunderland, founder of the Society for Preventing Accidents in Coalmines, had written to Davy suggesting that he might use his 'extensive stores of chemical knowledge' to address the issue of mining explosions caused by firedamp, or methane mixed with oxygen, which was often ignited by the open flames of the lamps then used by miners. Incidents such as the Felling mine disaster of 1812 near Newcastle, in which 92 men were killed, not only caused great loss of life among miners but also meant that their widows and children had to be supported by the public purse. The Revd Gray and a fellow clergyman also working in a north-east mining area, the Revd John Hodgson of Jarrow, were keen that action should be taken to improve underground lighting and especially the lamps used by miners.[40]

Davy conceived of using an iron gauze to enclose a lamp's flame, and so prevent the methane burning inside the lamp from passing out to the general atmosphere. Although the idea of the safety lamp had already been demonstrated by William Reid Clanny and by the then unknown (but later very famous) engineer George Stephenson, Davy's use of wire gauze to prevent the spread of flame was used by many other inventors in their later designs. George Stephenson's lamp was very popular in the north-east coalfields, and used the same principle of preventing the flame reaching the general atmosphere, but by different means.[41] Unfortunately, although the new design of gauze lamp initially did seem to offer protection, it gave much less light, and quickly deteriorated in the wet conditions of most pits. Rusting of the gauze quickly made the lamp unsafe, and the number of deaths from firedamp explosions rose yet further.

There was some discussion as to whether Davy had discovered the principles behind his lamp without the help of the work of Smithson Tennant, but it was generally agreed that the work of both men had been independent. Davy refused to patent the lamp, and its invention led to his being awarded the Rumford medal in 1816.[1]

Acid-base studies[edit]

In 1815 Davy suggested that acids were substances that contained replaceable hydrogen ions;– hydrogen that could be partly or totally replaced by metals. When acids reacted with metals they formed salts. Bases were substances that reacted with acids to form salts and water. These definitions worked well for most of the nineteenth century.[42]

Herculaneum papyri[edit]

Humphry Davy experimented on fragments of the Herculaneum papyri before his departure to Naples in 1818. His early experiments showed hope of success. In his report to the Royal Society Davy writes that: 'When a fragment of a brown MS. in which the layers were strongly adhered, was placed in an atmosphere of chlorine, there was an immediate action, the papyrus smoked and became yellow, and the letters appeared much more distinct; and by the application of heat the layers separated from each other, giving fumes of muriatic acid.'[43]

The success of the early trials prompted Davy to travel to Naples to conduct further research on the Herculaneum papyri. Accompanied by his wife, they set off on 26 May 1818 to stay in Flanders where Davy was invited to by the coal miners.[44] They then traveled to Carniola (now Slovenia) which proved to become 'his favourite Alpine retreat' before finally arriving in Italy. In Italy, they befriended Lord Byron in Rome and then went on to travel to Naples.[45]

Initial experiments were again promising and his work resulted in 'partially unrolling 23 MSS., from which fragments of writing were obtained' [46] but after returning to Naples on 1 December 1819 from a summer in the Alps, Davy complained that 'the Italians at the museum [were] no longer helpful but obstructive'.[47] Davy decided to renounce further work on the papyri because 'the labour, in itself difficult and unpleasant, been made more so, by the conduct of the persons at the head of this department in the Museum'.[46]

Work on the electrochemical protection of ships' copper bottoms[edit]

From 1761 onwards, copper plating had been fitted to the undersides of Royal Navy ships, to protect the wood from attack by shipworms.[48] However, the copper bottoms were gradually corroded by exposure to the salt water. Between 1820-25, Davy, assisted by Michael Faraday, attempted to protect the copper by electrochemical means. He attached sacrificial pieces of zinc or iron to the copper, which provided cathodic protection to the host metal.[49] It was discovered, however, that protected copper became foul quickly, i.e. pieces of weed and/or marine creatures became attached to the hull, which had a detrimental effect on the handling of the ship. The Navy Board approached Davy in 1822, asking for help. Davy conducted a number of tests in Portsmouth Dockyard, which led to the Navy Board adopting the use of Davy's "protectors". By 1824, it had become apparent that fouling of the copper bottoms was still occurring on the majority of protected ships. By the end of 1825, the Admiralty ordered the Navy Board to cease fitting the protectors to sea-going ships, and to remove those that had already been fitted. Davy's scheme was seen as a public failure, despite the fact that, as Frank A. J. L. James comments, "The somewhat ironical problem [...] was not that they were unsuccessful. They did after all preserve the copper as Davy said they would. The problem was that the protectors, on most ships, had a chemical side effect which provided nutrients for weeds, barnacles etc. thus fouling the ships".[48]

President of the Royal Society[edit]

Elections took place on St Andrew's Day and Davy was elected on 30 November 1820. Although he was unopposed, other candidates had received initial backing. These candidates embodied the factional difficulties that beset Davy's presidency and which eventually defeated him.

The Society was in transition from a club for gentlemen interested in natural philosophy, connected with the political and social elite, to an academy representing increasingly specialised sciences. The previous president, Joseph Banks, had held the post for over 40 years and had presided autocratically over what David Miller calls the "Banksian Learned Empire", in which natural history was prominent.[50]

Banks had groomed the engineer, author and politician Davies Gilbert to succeed him and preserve the status quo, but Gilbert declined to stand. Fellows who thought royal patronage was important proposed Prince Leopold of Saxe-Coburg (later Leopold I of Belgium), who also withdrew, as did the Whig Edward St Maur, 11th Duke of Somerset. Davy was the outstanding scientist but some fellows did not approve of his popularising work at the Royal Institution.

The strongest alternative had been William Hyde Wollaston, who was supported by the "Cambridge Network" of outstanding mathematicians such as Charles Babbage and John Herschel, who tried to block Davy. They were aware that Davy supported some modernisation, but thought that he would not sufficiently encourage aspiring young mathematicians, astronomers and geologists, who were beginning to form specialist societies. Davy was only 41, and reformers were fearful of another long presidency.

In his early years Davy was optimistic about reconciling the reformers and the Banksians. In his first speech as president he declared:

I trust that, with these new societies, we shall always preserve the most amicable relations... I am sure there is no desire in [the Royal Society] to exert anything like patriarchal authority in relation to these institutions".[51]

Davy spent much time juggling the factions but, as his reputation declined in the light of failures such as his research into copper-bottomed ships, he lost popularity and authority. This was compounded by a number of political errors. In 1825 his promotion of the new Zoological Society courted the landed gentry and alienated expert zoologists. He offended the mathematicians and reformers by failing to ensure that Babbage received one of the new Royal Medals (a project of his) or the vacant secretaryship of the Society in 1826. In November 1826 the mathematician Edward Ryan recorded that:

The Society, every member almost... are in the greatest rage at the President's proceedings and nothing is now talked of but removing him."[52]

In the event he was again re-elected unopposed, but he was now visibly unwell. In January 1827 he set off to Italy for reasons of his health. It did not improve and, as the 1827 election loomed, it was clear that he would not stand again. He was succeeded by Davies Gilbert.

Last years and death[edit]

Michael Faraday, portrait by Thomas Phillips c. 1841–1842[53]

In January 1819, Davy was awarded a baronetcy. Although Sir Francis Bacon (also later made a peer[54]) and Sir Isaac Newton had already been knighted, this was, at the time, the first such honour ever conferred on a man of science in Britain. This was followed a year later with the Presidency of the Royal Society.

Davy's laboratory assistant, Michael Faraday, went on to enhance Davy's work and would become the more famous and influential scientist. Davy is supposed to have even claimed Faraday as his greatest discovery. Davy later accused Faraday of plagiarism, however, causing Faraday (the first Fullerian Professor of Chemistry) to cease all research in electromagnetism until his mentor's death.

Of a sanguine, somewhat irritable temperament, Davy displayed characteristic enthusiasm and energy in all his pursuits. As is shown by his verses and sometimes by his prose, his mind was highly imaginative; the poet Coleridge declared that if he "had not been the first chemist, he would have been the first poet of his age", and Southey said that "he had all the elements of a poet; he only wanted the art." In spite of his ungainly exterior and peculiar manner, his happy gifts of exposition and illustration won him extraordinary popularity as a lecturer, his experiments were ingenious and rapidly performed, and Coleridge went to hear him "to increase his stock of metaphors." The dominating ambition of his life was to achieve fame, but though that sometimes betrayed him into petty jealousy, it did not leave him insensible to the claims on his knowledge of the "cause of humanity", to use a phrase often employed by him in connection with his invention of the miners' lamp. Of the smaller observances of etiquette he was careless, and his frankness of disposition sometimes exposed him to annoyances which he might have avoided by the exercise of ordinary tact.[55]

According to one of Davy's biographers, June Z. Fullmer, he was a deist.[56]

Davy's grave at Cimetière Plainpalais in Geneva

He spent the last months of his life writing Consolations in Travel, an immensely popular, somewhat freeform compendium of poetry, thoughts on science and philosophy. Published posthumously, the work became a staple of both scientific and family libraries for several decades afterward. Davy spent the winter in Rome, hunting in the Campagna on his fiftieth birthday. But on 20 February 1829 he had another stroke. After spending many months attempting to recuperate, Davy died in a hotel room in Geneva, Switzerland, on 29 May 1829.[1]

He had wished to be buried where he died, but had also wanted the burial delayed in case he was only comatose. He refused to allow a post-mortem for similar reasons. But the laws of Geneva did not allow any delay and he was given a public funeral on the following Monday, in the Plainpalais Cemetery, outside the city walls. Jane organised a memorial tablet for him, in Westminster Abbey shortly afterwards, at a cost of £142.[57][58]

Legacy and honours[edit]

  • A plaque to honour him is on the wall of the Royal Panopticon of Science and Arts in 1854.
  • A lunar crater (Davy) is named after Sir Humphry Davy. It has a diameter of 34 km and coordinates of 11.8S, 8.1W.
  • In his hometown of Penzance, Cornwall, a statue of Davy stands in front of the imposing Market House, (now owned by Lloyds TSB) at the top of the town's main street Market Jew Street. Nearby is a house on which a commemorative plaque claims the location as the site of his birth.
  • Penzance also has a secondary school named Humphry Davy School. Similar to James Prescott Joule and Isaac Newton, Davy is also remembered in his hometown by a pub – "The Sir Humphry Davy" at 32 Alverton Street, west of the Market House.
  • Outside the entrance to Sunderland Football Club's Stadium of Light stands a giant Davy Lamp, in recognition of local mining heritage and the importance of Davy's safety lamp to the mining industry.
  • Davy was a founding Fellow of the Zoological Society of London
  • A satellite of the University of Sheffield at Golden Smithies Lane in Wath upon Dearne (Manvers) was called Humphry Davy House and was home to the School of Nursing and Midwifery, until April 2009.
  • There is a road, Humphry Davy Way, adjacent to the docks in Bristol named after Sir Humphry Davy.
  • There is a street named after Sir Humphry Davy (Humphry-Davy-Straße) in the industrial quarter of the town of Cuxhaven, Schleswig-Holstein, Germany.
  • The University of Plymouth has named one of its science buildings after the chemist.
  • The Royal Society of London has awarded the Davy Medal annually since 1877 "for an outstandingly important recent discovery in any branch of chemistry."
  • Davy is the subject of a humorous song by Richard Gendall, recorded in 1980 by folk-singer Brenda Wootton, each verse of which recalls one of Davy's major discoveries.
  • English playwright Nick Darke wrote Laughing Gas (2005) a comedy script about the life of Sir Humphry Davy, unfinished at the time of Nick Darke's death; completed posthumously by actor and playwright Carl Grose and produced by the Truro-based production company O-region.
  • Davy's passion for outdoors and fly-fishing earned him title "father of modern fly-fishing" and his book Salmonia is often considered as "fly-fisherman bible".
  • Bentley's first clerihew, published in 1905, was written about Sir Humphry Davy:
Sir Humphry Davy
Abominated gravy.
He lived in the odium
Of having discovered sodium.[59]
  • The mineral davyne was named in his honor by W. Haidinger in 1827.[60]


See Fullmer's work for a full list of Davy's articles.[61]

Humphry Davy's books are as follows:

Davy also contributed articles on chemistry to Rees's Cyclopædia, but the topics are not known.

His collected works were published in 1839–1840:

  • Davy, John (1839–1840). The Collected Works of Sir Humphry Davy. London: Smith, Elder, and Company. ISBN 0-217-88944-1. 


  1. ^ a b c d David Knight (2004) "Davy, Sir Humphry, baronet (1778–1829)" in Oxford Dictionary of National Biography, Oxford University Press
  2. ^ "On Some Chemical Agencies of Electricity". Archived from the original on 26 October 2007. Retrieved 2 March 2008. 
  3. ^ Berzelius, J. J.; trans. A. Jourdan and M. Esslinger. Traité de chimie (in French). 1 (trans.,of experimental science. ed.). p. 164. 
  4. ^ a b Davy, John (1836). Memoirs of the Life of Sir Humphry Davy. Vol. 1 of 2. London, UK: Longman, Rees, Orme, Brown, Green, & Longman. 
  5. ^ Knight, David (1992). Humphry Davy: Science and Power. Cambridge, UK: Cambridge University Press. ISBN 0-631-16816-8. 
  6. ^ a b c d e f g  Hunt, Robert (1888). "Davy, Humphry". Dictionary of National Biography. London: Smith, Elder & Co. 
  7. ^ Amin, Wahida (2013). The Poetry and Science of Humphry Davy. (PDF) (Unpublished PhD thesis, University of Salford, UK). 
  8. ^ Anon (22 September 2011). "Davy paintings donated to museum". The Cornishman. 
  9. ^ Davy's picture of Mounts Bay was included in the Penlee House exhibition "Penzance 400: A Celebration of the History of Penzance" 29 March – 7 June 2014
  10. ^ The Larigan, or Laregan, river is a stream in Penzance.
  11. ^ Amin, Wahida (2013). The Poetry and Science of Humphry Davy. (PDF) (Unpublished PhD thesis, University of Salford, UK). 
  12. ^ Keys TE (1941). "The Development of Anesthesia". Anesthesiology journal (Sep.1941, vol.2, is.5, p.552-574). 
  13. ^ Priestley J (1776). "Experiments and Observations on Different Kinds of Air (vol.2, sec.3)". 
  14. ^ In his 1800 Researches, Chemical and Philosophical (p.556), Davy commented: "As nitrous oxide in its extensive operation appears capable of destroying pain, it may probably be used with advantage during surgical operations in which no great effusion of blood takes place."
  15. ^ a b c d e Holmes, Richard (2008). The Age of Wonder. Pantheon Books. ISBN 978-0-375-42222-5. 
  16. ^ Hindle, Maurice. "Nature, Power, and the Light of Suns: The Poetry of Humphry Davy" (PDF). Retrieved 4 May 2017. 
  17. ^ Amin, Wahida. "THE POETRY AND SCIENCE OF HUMPHRY DAVY" (PDF). Retrieved 4 May 2017. 
  18. ^ Godwin, William. "William Godwin's Diary". Retrieved 4 May 2017. 
  19. ^ a b c Jay, Mike (8 August 2014). ""O, Excellent Air Bag": Humphry Davy and Nitrous Oxide". The Public Domain Review. Open Knowledge Foundation. 4 (16).  open access publication – free to read
  20. ^ Coleridge, Samuel Taylor (1956–71). Griggs, E. L., ed. The Collected Letters of Samuel Taylor Coleridge. Clarendon Press. pp. vol 1, 606. 
  21. ^ Wordsworth, William (1967). de Selincourt, E., ed. The Letters of William and Dorothy Wordsworth. Clarendon Press. pp. vol. 1, 289. 
  22. ^ Sharrock, Roger (1962). "The Chemist and the Poet: Sir Humphry Davy and the Preface to the Lyrical Ballads". Notes and Records of the Royal Society. 17: 57–76. 
  23. ^ Wordsworth, William (1800). Lyrical Ballads. Biggs & Cottle. p. 210. 
  24. ^ Davy, Humphry. Royal Institution HD 20c. pp. 44, 46, 52. 
  25. ^ Holmes 2008, pp. 285.
  26. ^ History of the Geological Society, UK.
  27. ^ "Book of Members, 1780–2010: Chapter D" (PDF). American Academy of Arts and Sciences. Retrieved 8 September 2016. 
  28. ^ Davy, Humphry (1808). "Electrochemical Researches, on the Decomposition of the Earths; With Observations in the Metals Obtained from the Alkaline Earths, and on the Amalgam Procured from Ammonia". Philosophical Transactions of the Royal Society. 98: 339–340. 
  29. ^ Davy, Humphry (1808). "Electro-Chemical Researches, on the Decomposition of the Earths; With Observations on the Metals Obtained from the Alkaline Earths, and on the Amalgam Procured from Ammonia". Philosophical Transactions of the Royal Society. 98: 340. 
  30. ^ Davy, Humphry (1808). "Electro-chemical Researches, on the Decomposition of the Earths; With Observations in the Metals Obtained from the Alkaline Earths, and on the Amalgam Procured from Ammonia". Philosophical Transactions of the Royal Society. 98: 346. 
  31. ^ Davy, Humphry (1811). "On Some of the Combinations of Oxymuriatic Gas and Oxygene, and on the Chemical Relations of These Principles, to Inflammable Bodies". Philosophical Transactions of the Royal Society. 101: 1–35. doi:10.1098/rstl.1811.0001. 
  32. ^ Humphry, Davy (1813). "On a New Detonating Compound". Philosophical Transactions of the Royal Society. 103: 1–7. JSTOR 107383. doi:10.1098/rstl.1813.0002. 
  33. ^ a b c d e f g h i j * Knight, David (1992). Humphry Davy: Science and Power. Cambridge, UK: Cambridge University Press. ISBN 0-631-16816-8. 
  34. ^ Jones, H.B. (1870). The life and letters of Faraday, Vol. 1. p. 75. 
  35. ^ Davy, H. (1813). "Sur la nouvelle substance découverte par M. Courtois, dans le sel de Vareck". Annales de chimie. 88: 322. 
  36. ^ Davy, Humphry (1 January 1814). "Some Experiments and Observations on a New Substance Which Becomes a Violet Coloured Gas by Heat" (PDF). Phil. Trans. R. Soc. Lond. 104 (0): 74. doi:10.1098/rstl.1814.0007. 
  37. ^ For information on the continental tour of Davy and Faraday, see Williams, L. Pearce (1965). Michael Faraday: A Biography. New York: Basic Books. p. 36. ISBN 0-306-80299-6. 
  38. ^ * Faraday, Michael (1991). Bowers, Brian; Symons, Lenore, eds. Curiosity Perfectly Satisfyed: Faraday's Travels in Europe, 1813-1815. London, UK: Peregrinus. ISBN 9780863412349. 
  39. ^ Davy, Humphry. "Letter to Lord Liverpool, Summer 1815[?]". List of letters: Humphry Davy and his circle. Retrieved 4 May 2017. 
  40. ^ Knight, David (1992). Humphry Davy: Science and Power. Cambridge, UK: Cambridge University Press, pp. 105-6. ISBN 0-631-16816-8.
  41. ^ Holmes 2008, pp. 364–373.
  42. ^ HSC, Conquering Chemistry Fourth Edition p. 146.
  43. ^ Davy, 1821, page 193
  44. ^ Davy, John (1836). Memoirs of the life of sir Humphry Davy. London: Longman, Rees, Orme, Brown, Green & Longman. p. 97. 
  45. ^ Knight, David (1992). Humphry Davy: Science & Power. Cambridge: Cambridge University Press. p. 118. 
  46. ^ a b Davy, 1821, page 203
  47. ^ page 119 of Knight 1992
  48. ^ a b James, Frank A. J. L. (1992). "Davy in the Dockyard: Humphry Davy, the Royal Society and the Electro-chemical Protection of the Copper Sheeting of His Majesty's Ships in the mid 1820s". Physis. 29: 205–25. 
  49. ^ Knight, David (1992). Humphry Davy: Science and Power. Cambridge: Cambridge University Press. 
  50. ^ David Philip Miller, "Between hostile camps: Sir Humphry Davy's presidency of the Royal Society of London", British Journal for the History of Science (1983): 1-47.
  51. ^ Cited in David Philip Miller, "Between hostile camps: Sir Humphry Davy's presidency of the Royal Society of London", British Journal for the History of Science (1983): 30-31.
  52. ^ Cited in David Philip Miller, "Between hostile camps: Sir Humphry Davy's presidency of the Royal Society of London", British Journal for the History of Science (1983): 39.
  53. ^ National Portrait gallery NPG 269
  54. ^ As Baron Verulam and later Viscount St Alban.
  55. ^  One or more of the preceding sentences incorporates text from a publication now in the public domainChisholm, Hugh, ed. (1911). "Davy, Sir Humphry". Encyclopædia Britannica. 7 (11th ed.). Cambridge University Press. pp. 871–873. 
  56. ^ Fullmer, June Z. (2000). Young Humphry Davy: The Making of an Experimental Chemist, Volume 237. American Philosophical Society. p. 158. ISBN 9780871692375. In prominent alliance with his concept, Davy celebrated a natural-philosophic deism, for which his critics did not attack him, nor, indeed, did they bother to mention it. Davy never appeared perturbed by critical attacks on his "materialism" because he was well aware that his deism and his materialism went hand in hand; moreover, deism appeared to be the abiding faith of all around him. 
  57. ^ Knight, David (1992). Humphry Davy: Science and Power. Cambridge, UK: Cambridge University Press. p. 168. ISBN 0-631-16816-8. 
  58. ^ Davy is buried in plot 208 of the Plainpalais Cemetery, Rue des Rois, Geneva. For contemporary information on Davy's funeral service and memorials, see Paris, John Ayrton (1831). The Life of Sir Humphry Davy, Bart., LL.D. London: Henry Colburn and Richard Bentley. pp. 516–517. 
  59. ^ Bentley, E. Clerihew (1982). The First Clerihews. Oxford University Press. ISBN 0-19-212980-5. 
  60. ^ Haidinger, W (1827). "Über den Davyn, eine neue Mineralspecies". Annalen der Physik und Chemie. 87: 470–474. 
  61. ^ Fullmer, 1969


  • Davy, Humphry (January 1821). "Some Observations and Experiments on the Papyri Found in the Ruins of Herculaneum". Philosophical Transactions. 111: 191–208. 
  • Fullmer, June Z. (1969). Sir Humphry Davy's Published Works. Cambridge, Massachusetts: Harvard University Press. ISBN 0-674-80961-0. 
  • Hartley, Harold (1960). "The Wilkins Lecture. Sir Humphry Davy, Bt., P.R.S. 1778–1829". Proceedings of the Royal Society A. 255 (1281): 153–180. Bibcode:1960RSPSA.255..153H. JSTOR 2413906. doi:10.1098/rspa.1960.0060. 
  • Hartley, Harold (1966). Humphry Davy. London: Nelson. ISBN 0-85409-729-5. 
  • Holmes, Richard (2008). The age of wonder. New York: Vintage Books. ISBN 978-1-4000-3187-0. 
  • Knight, David (1992). Humphry Davy: Science and Power. Cambridge, UK: Cambridge University Press. ISBN 0-631-16816-8. 
  • Lamont-Brown, Raymond (2004). Humphry Davy, Life Beyond the Lamp. Stroud: Sutton Publishing. ISBN 0-7509-3231-7. 
  • Partington, J. R. (1964). History of Chemistry. 4. London: Macmillan. pp. 29–76. 
  • Treneer, Anne (1963). The Mercurial Chemist: a Life of Sir Humphry Davy. London: Methuen. 

External links[edit]

Baronetage of the United Kingdom
New creation Davy baronets
(of Grosvenor Street)