|Name, symbol||strontium, Sr|
|Pronunciation||// or //
STRON-sh(ee)-əm or STRON-tee-əm
|Appearance||silvery white metallic; with a pale yellow tint|
|Strontium in the periodic table|
|Atomic number (Z)||38|
|Group, block||group 2 (alkaline earth metals), s-block|
|Element category||alkaline earth metal|
|Standard atomic weight (±) (Ar)||87.62(1)|
|Electron configuration||[Kr] 5s2|
|2, 8, 18, 8, 2|
|Melting point||1050 K (777 °C, 1431 °F)|
|Boiling point||1650 K (1377 °C, 2511 °F)|
|Density near r.t.||2.64 g/cm3|
|when liquid, at m.p.||2.375 g/cm3|
|Heat of fusion||7.43 kJ/mol|
|Heat of vaporization||141 kJ/mol|
|Molar heat capacity||26.4 J/(mol·K)|
|Oxidation states||2, 1 (a strongly basic oxide)|
|Electronegativity||Pauling scale: 0.95|
|Ionization energies||1st: 549.5 kJ/mol
2nd: 1064.2 kJ/mol
3rd: 4138 kJ/mol
|Atomic radius||empirical: 215 pm|
|Covalent radius||195±10 pm|
|Van der Waals radius||249 pm|
|Crystal structure||face-centered cubic (fcc)|
|Thermal expansion||22.5 µm/(m·K) (at 25 °C)|
|Thermal conductivity||35.4 W/(m·K)|
|Electrical resistivity||132 nΩ·m (at 20 °C)|
|Young's modulus||15.7 GPa|
|Shear modulus||6.03 GPa|
|Naming||after the mineral strontianite, itself named after Strontian, Scotland|
|Discovery||William Cruickshank (1787)|
|First isolation||Humphry Davy (1808)|
|Most stable isotopes of strontium|
Strontium is a chemical element with symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white or yellowish metallic element that is highly reactive chemically. The metal turns yellow when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors, calcium and barium. It occurs naturally in the minerals celestine, strontianite, and putnisite, and is mostly mined from the first two of these. While natural strontium is stable, the synthetic 90Sr isotope, present in radioactive fallout, is radioactive and has a half-life of 28.90 years: this is one of the most dangerous components of fallout, as strontium mimics its vertical neighbor calcium and is similarly taken up by the body. Natural stable strontium, on the other hand, is not dangerous to health.
Both strontium and strontianite are named after Strontian, a village in Scotland near which the mineral was discovered in 1790 by Adair Crawford and William Cruickshank; it was identified as a new element the next year from its crimson-red flame test color. Strontium was first isolated as a metal in 1808 by Humphry Davy using the then-newly discovered process of electrolysis. The production of sugar from sugar beet was in the 19th century the largest application of strontium (see strontian process). At the peak of production of television cathode ray tubes, as much as 75 percent of strontium consumption in the United States was used for the faceplate glass. With the displacement of cathode ray tubes by other display methods, consumption of strontium has dramatically declined.
Strontium is a gray, silvery metal that is softer than calcium and even more reactive toward water, with which it reacts on contact to produce strontium hydroxide and hydrogen gas. It burns in air to produce both strontium oxide and strontium nitride, but since it does not react with nitrogen below 380 °C, at room temperature, it forms only the oxide spontaneously. Three allotropes of metallic strontium exist, with transition points at 235 and 540 °C.
Because of its extreme reactivity with oxygen and water, this element occurs naturally only in compounds with other elements, such as in the minerals strontianite and celestite. It is kept under a liquid hydrocarbon such as mineral oil or kerosene to prevent oxidation; freshly exposed strontium metal rapidly turns a yellowish color with the formation of the oxide. Finely powdered strontium metal is pyrophoric meaning it will ignite spontaneously in air at room temperature. Volatile strontium salts impart a bright red color to flames, and these salts are used in pyrotechnics and in the production of flares. Natural strontium is a mixture of four stable isotopes.
Strontium is named after the Scottish village of Strontian (Gaelic Sròn an t-Sithein), where it was discovered in the ores of the lead mines. In 1790, Adair Crawford, a physician engaged in the preparation of barium, and his colleague William Cruickshank, recognised that the Strontian ores exhibited properties that differed from those in other "heavy spars" sources. This allowed Adair to conclude on page 355 "... it is probable indeed, that the scotch mineral is a new species of earth which has not hitherto been sufficiently examined." The physician and mineral collector Friedrich Gabriel Sulzer analysed together with Johann Friedrich Blumenbach the mineral from Strontian and named it strontianite. He also came to the conclusion that it was distinct from the witherite and contained a new earth (neue Grunderde). In 1793 Thomas Charles Hope, a professor of chemistry at the University of Glasgow proposed the name strontites. He confirmed the earlier work of Crawford and recounted: " ... Considering it a peculiar earth I thought it necessary to give it an name. I have called it Strontites, from the place it was found; a mode of derivation in my opinion, fully as proper as any quality it may possess, which is the present fashion." The element was eventually isolated by Sir Humphry Davy in 1808 by the electrolysis of a mixture containing strontium chloride and mercuric oxide, and announced by him in a lecture to the Royal Society on 30 June 1808. In keeping with the naming of the other alkaline earths, he changed the name to strontium.
The first large-scale application of strontium was in the production of sugar from sugar beet. Although a crystallisation process using strontium hydroxide was patented by Augustin-Pierre Dubrunfaut in 1849 the large scale introduction came with the improvement of the process in the early 1870s. The German sugar industry used the process well into the 20th century. Prior to World War I the beet sugar industry used 100,000 to 150,000 tons of strontium hydroxide for this process per year. The strontium hydroxide was recycled in the process, but the demand to substitute losses during production was high enough to create a significant demand initiating mining of strontianite in the Münsterland. The mining of strontianite in Germany ended when mining of the celestite deposits in Gloucestershire started. These mines supplied most of the world strontium supply from 1884 to 1941. Although the celestite deposits in the Granada basin were known for some time the large scale mining did not start before the 1950s.
During atmospheric nuclear weapons testing, it was observed that strontium-90 is one of the nuclear fission products with a relative high yield. The similarity to calcium and the chance that the strontium-90 might become enriched in bones made research on the metabolism of strontium an important topic.
Strontium commonly occurs in nature, being the 15th most abundant element on Earth (its heavier congener barium being the 14th), estimated to average approximately 360 parts per million in the Earth's crust and is found chiefly as the sulfate mineral celestite (SrSO4) and the carbonate strontianite (SrCO3). Of the two, celestite occurs much more frequently in deposits of sufficient size for mining. Because strontium is used most often in the carbonate form, strontianite would be the more useful of the two common minerals, but few deposits have been discovered that are suitable for development.
In groundwater strontium behaves chemically much like calcium. At intermediate to acidic pH Sr2+ is the dominant strontium species. In the presence of calcium ions, strontium commonly forms coprecipitates with calcium minerals such as calcite and anhydrite at an increased pH. At intermediate to acidic pH, dissolved strontium is bound to soil particles by cation exchange.
The mean strontium content of ocean water is 8 mg/l. At a concentration between 82 and 90 µmol/l of strontium, the concentration is considerably lower than the calcium concentration, which is normally between 9.6 and 11.6 mmol/l.
A large proportion of mined celestite (SrSO4) is converted to the carbonate by two processes. Either the celestite is directly leached with sodium carbonate solution or the celestite is roasted with coal to form the sulfide. The second stage produces a dark-coloured material containing mostly strontium sulfide. This so-called "black ash" is dissolved in water and filtered. Strontium carbonate is precipitated from the strontium sulfide solution by introduction of carbon dioxide. The sulfate is reduced to the sulfide by the carbothermic reduction:
- SrSO4 + 2 C → SrS + 2 CO2
About 300,000 tons are processed in this way annually.
The metal is produced commercially by reducing strontium oxide with aluminium. The strontium is distilled from the mixture. Strontium metal can in principle be prepared by electrolysis of a solution of strontium chloride in molten potassium chloride:
- Sr2+ + 2
- 2 Cl− → Cl2 + 2
Strontium has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Only 87Sr is radiogenic; it is produced by decay from the radioactive alkali metal 87Rb, which has a half-life of 4.88 × 1010 years. Thus, there are two sources of 87Sr in any material: first the portion formed in stars along with the isotopes 84Sr, 86Sr, and 88Sr; and second the portion formed by radioactive decay of 87Rb. The ratio 87Sr/86Sr is the parameter typically reported in geologic investigations; ratios in minerals and rocks have values ranging from about 0.7 to greater than 4.0. Because strontium has an atomic radius similar to that of calcium, it readily substitutes for Ca in minerals.
Sixteen unstable isotopes are known to exist. Of greatest importance are 90Sr with a half-life of 28.78 years and 89Sr with a half-life of 50.5 days. 90Sr is a by-product of nuclear fission found in nuclear fallout, and presents a health problem because it substitutes for calcium in bone, preventing expulsion from the body. This isotope is one of the best long-lived high-energy beta emitters known, and is used in SNAP (Systems for Nuclear Auxiliary Power) devices. These devices hold promise for use in spacecraft, remote weather stations, navigational buoys, etc., where a lightweight, long-lived, nuclear-electric power source is required. The 1986 Chernobyl nuclear accident contaminated about 30,000 km2 with greater than 10 kBq/m2 with 90Sr.
89Sr is a short-lived artificial radioisotope used in the treatment of bone cancer. In circumstances where cancer patients have widespread and painful bony metastases (secondaries), the administration of 89Sr results in the delivery of radioactive emissions (beta particles in this case) directly to the area of bony problem (where calcium turnover is greatest). 89Sr is manufactured as the chloride salt (which is soluble), and when dissolved in normal saline can be injected intravenously. Typically, cancer patients will be treated with a dose of 150 MBq. Following this treatment, patients must take the precautions of sitting to urinate and double-flushing the toilet because the urine is radioactive. The beta particles travel about 3.5 mm in bone (energy 0.583 MeV) and 6.5 mm in tissue, so isolation of such patients is not normally necessary, but they should not have anyone (typically young children) sitting in their laps for 10 to 40 days. The span of time is a factor of the variable clearing time for 89Sr, which depends on renal function and the number of bony metastases. When the patient has many bony metastases, the entire 89Sr dose can be absorbed by the bone and the radioactivity is retained, to decay over a 50.5-day half-life. In 10 half-lives (or about 500 days) 99.9% of the radioactive strontium will decay. Where the patient has few bony metastases, the large proportion of 89Sr will not be absorbed by the bone and will be filtered by the kidney, so that the effective half-life (a combination of the physical and biological half-life) will be much shorter.
Consuming 75% of production, the primary use for strontium is in glass for colour television cathode ray tubes. It prevents X-ray emission. All parts of the CRT must absorb X-rays. In the neck and the funnel of the tube, lead glass is used for this purpose, but this type of glass shows a browning effect due to the interaction of the X-rays with the glass. Therefore, the front panel is made from a different glass mixture with strontium and barium to absorb the X-rays. The average values for the glass mixture determined for a recycling study in 2005 is 8.5% strontium oxide and 10% barium oxide. This application for strontium is declining because the CRTs are replaced by other display methods. This decline has a significant influence on the mining and refining of strontium.
Because strontium is so similar to calcium, it is incorporated in the bone. All four stable isotopes are incorporated, in roughly the same proportions they are found in nature. However, the actual distribution of the isotopes tends to vary greatly from one geographical location to another. Thus, analyzing the bone of an individual can help determine the region it came from. This approach helps to identify the ancient migration patterns and the origin of commingled human remains in battlefield burial sites. In the same way, strontium is useful to forensic scientists.
87Sr/86Sr ratios are commonly used to determine the likely provenance areas of sediment in natural systems, especially in marine and fluvial environments. Dasch (1969) showed that surface sediments of Atlantic displayed 87Sr/86Sr ratios that could be regarded as bulk averages of the 87Sr/86Sr ratios of geological terranes from adjacent landmasses. A good example of a fluvial-marine system to which Sr isotope provenance studies have been successfully employed is the River Nile-Mediterranean system, Due to the differing ages of the rocks that constitute the majority of the Blue and White Nile, catchment areas of the changing provenance of sediment reaching the River Nile delta and East Mediterranean Sea can be discerned through Sr isotopic studies. Such changes are climatically controlled in the Late Quaternary.
More recently, 87Sr/86Sr ratios have also been used to determine the source of ancient archaeological materials such as timbers and corn in Chaco Canyon, New Mexico. 87Sr/86Sr ratios in teeth may also be used to track animal migrations or in criminal forensics.
Strontium carbonate and other strontium salts are added to fireworks to give a deep red colour. This same effect identifies strontium cations in the flame test. Fireworks consumes about 5% of the world's production.
89Sr is the active ingredient in Metastron (the generic version of Metastron, generic strontium chloride Sr-89 Injection, its manufactured by Bio-Nucleonics Inc.), a radiopharmaceutical used for bone pain secondary to metastatic bone cancer. The strontium is processed like calcium by the body, preferentially incorporating it into bone at sites of increased osteogenesis. This localization focuses the radiation exposure on the cancerous lesion.
90Sr has been used as a power source for radioisotope thermoelectric generators (RTGs). 90Sr produces approximately 0.93 watts of heat per gram (it is lower for the form of 90Sr used in RTGs, which is strontium fluoride). However, 90Sr has one third the lifetime and a lower density than 238Pu, another RTG fuel. The main advantage of 90Sr is that it is cheaper than 238Pu and is found in nuclear waste. The Soviet Union deployed nearly 1000 of these RTGs on its northern coast as a power source for lighthouses and meteorology stations.
Small amounts are used in the refining of zinc to remove small amounts of lead impurities.
Other possible applications follow:
- Strontium titanate has an extremely high refractive index and an optical dispersion greater than that of diamond, making it useful in a variety of optics applications. For this property, it has been cut and polished as gemstone, in particular, simulating diamond. However, it is very soft and easily scratched, so it is rarely used.
- Ferrite magnets.
- Strontium aluminate is used as a bright phosphor with long persistence of phosphorescence.
- Strontium oxide is used to improve the quality of some pottery glazes.
- Strontium ranelate is used in the treatment of osteoporosis. It is a prescription drug in the EU, but not in the USA.
- Strontium barium niobate is used as a photographic material for holograms.
Strontium metal is used in 90%-aluminium 10% alloys of an eutectic composition for the modification of aluminium-silicon casting alloys. AJ62, a durable, creep-resistant magnesium alloy used in car and motorcycle engines by BMW, contains 2% strontium by weight.
Strontium is used in scientific studies of neurotransmitter release in neurons. Like calcium, strontium facilitates synaptic vesicle fusion with the synaptic membrane. But, unlike calcium, strontium causes asynchronous vesicle fusion. Therefore, replacing calcium in a culture medium with strontium allows scientists to measure the effects of a single-vesicle fusion event, e.g., the size of the postsynaptic response elicited by the neurotransmitter content of a single vesicle.
The important concept for isotopic tracing is that Sr derived from any mineral through weathering reactions will have the same 87Sr/86Sr as the mineral. Therefore, differences in 87Sr/86Sr among ground waters require either (a) differences in mineralogy along contrasting flowpaths or (b) differences in the relative amount of Sr weathered from the same suite of minerals. This latter situation can arise in several ways:
- First, differences in initial water chemistry within a homogeneous rock unit will affect the relative weathering rates of the minerals. For example, sections of the soil zone affected by evaporative concentration of recharge waters or by differences in pCO2 can be expected to have different 87Sr/86Sr.
- Second, differences in the relative mobilities of water at scales ranging from inter-grain pores to the catchment scale may also profoundly affect 87Sr/86Sr (Bullen et al., 1996). For example, the chemical composition and the resultant 87Sr/86Sr in immobile waters at a plagioclase-hornblende grain boundary versus a quartz-mica boundary will be different.
- Third, a difference in the relative "effective" surface areas of minerals in one portion of the rock unit will also cause differences in chemistry and isotopic composition; "poisoning" reactive surfaces by organic coatings is an example of this kind of process.
In a fundamental sense, because the waters in shallow systems are not in chemical equilibrium with the rocks, it is unrealistic to expect that waters along flowpaths within even a constant-mineralogy unit should have a constant 87Sr/86Sr. Instead, the waters moving along specific flowpaths slowly react with the rocks and gradually approach chemical equilibrium over long periods.
Strontium forms a variety of salts, the properties of which are always intermediate between those of barium and calcium. The salts tend to be colourless. The sulfate and carbonate are poorly soluble, hence their occurrence as minerals. Most compounds are derived from the carbonate or the sulfide, obtained from minerals. As is typical for an alkaline earth derivative, the sulfide hydrolyzes readily:
- SrS + 2 H2O → Sr(OH)2 + H2S
- SrS + H2O + CO2 → SrCO3 + H2S
Strontium nitrate can also be prepared in this way.
Acantharea, a relative large group of marine radiolarian protozoa, produce intricate mineral skeletons composed of strontium sulfate. In biological systems, calcium is substituted in a small extent by strontium. In the human body, most of the absorbed strontium is deposited in the bones. The ratio of strontium to calcium in human bones is between 1:1000 and 1:2000 roughly in the same range as in the blood serum.
Effect on the human body
The human body absorbs strontium as if it were calcium. Because the elements are chemically similar, the stable strontium isotopes might not pose a significant health threat — in fact, the levels found naturally may actually be beneficial (see below). But the radioactive 90Sr can cause various bone disorders and diseases, including bone cancer. The amount of radioactive 90Sr absorbed into a body is measured in strontium units.
The drug strontium ranelate, a compound of strontium and ranelic acid, aids bone growth, increases bone density, and lessen the incidence of vertebral, peripheral, and hip fractures. Women receiving the drug show a 12.7% increase in bone density. Women receiving a placebo had a 1.6% decrease. Half the increase in bone density (measured by X-ray densitometry) is discounted because strontium has greater atomic density than calcium, while the other half is a true increase in bone mass. Strontium ranelate is registered as a prescription drug in Europe and many countries worldwide. It must be prescribed by a doctor, must be delivered by a pharmacist, and requires strict medical supervision.
A long history of medical research into the benefits of strontium began in the 1950s. These studies indicate a lack of undesirable side-effects. Several other salts of strontium such as strontium citrate and strontium carbonate are available in the United States under the Dietary Supplements Health and Education Act of 1994, providing close to the recommended strontium content, about 680 milligrams per day, of strontium ranelate. The long-term safety and efficacy have not been evaluated on humans in large-scale medical trials. However, some companies do manufacture strontium pills for increasing bone health.
Topically applied, strontium has been shown to accelerate the recovery rate of the epidermal permeability barrier (skin barrier). “[…]epidermal permeability barrier functions as the first line of defense in human body’s defense system by inhibiting external irritation and blocking the invasion of microbes or pollutants or their absorption by human body.[…] Topical application of strontium chloride solution accelerated permeability barrier recovery rate, compared with vehicle-applied skin.”
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