Synthesis of carbon nanotubes

From Wikipedia, the free encyclopedia
Jump to navigation Jump to search
powder of carbon nanotubes

Techniques have been developed to produce carbon nanotubes in sizable quantities, including arc discharge, laser ablation, high-pressure carbon monoxide disproportionation, and chemical vapor deposition (CVD). Most of these processes take place in a vacuum or with process gases. CVD growth of CNTs can occur in vacuum or at atmospheric pressure. Large quantities of nanotubes can be synthesized by these methods; advances in catalysis and continuous growth are making CNTs more commercially viable.[1]


Arc discharge[edit]

Nanotubes were observed in 1991 in the carbon soot of graphite electrodes during an arc discharge, by using a current of 100 amps, that was intended to produce fullerenes.[2] However the first macroscopic production of carbon nanotubes was made in 1992 by two researchers at NEC's Fundamental Research Laboratory.[3] The method used was the same as in 1991. During this process, the carbon contained in the negative electrode sublimates because of the high-discharge temperatures.

The yield for this method is up to 30% by weight and it produces both single- and multi-walled nanotubes with lengths of up to 50 micrometers with few structural defects.[4] Arc-discharge technique uses higher temperatures (above 1,700 °C) for CNT synthesis which typically causes the expansion of CNTs with fewer structural defects in comparison with other methods.[5]

Laser ablation[edit]

In laser ablation, a pulsed laser vaporizes a graphite target in a high-temperature reactor while an inert gas is bled into the chamber. Nanotubes develop on the cooler surfaces of the reactor as the vaporized carbon condenses. A water-cooled surface may be included in the system to collect the nanotubes.

This process was developed by Dr. Richard Smalley and co-workers at Rice University, who at the time of the discovery of carbon nanotubes, were blasting metals with a laser to produce various metal molecules. When they heard of the existence of nanotubes they replaced the metals with graphite to create multi-walled carbon nanotubes.[6] Later that year the team used a composite of graphite and metal catalyst particles (the best yield was from a cobalt and nickel mixture) to synthesize single-walled carbon nanotubes.[7]

The laser ablation method yields around 70% and produces primarily single-walled carbon nanotubes with a controllable diameter determined by the reaction temperature. However, it is more expensive than either arc discharge or chemical vapor deposition.[4]

The effective equation for few cycle optical pulse dynamics was obtained by virtue of the Boltzmann collision-less equation solution for conduction band electrons of semiconductor carbon nanotubes in the case when medium with carbon nanotubes has spatially-modulated refractive index.[8]

Plasma torch[edit]

Single-walled carbon nanotubes can also be synthesized by a thermal plasma method, first invented in 2000 at INRS (Institut national de la recherche scientifique) in Varennes, Canada, by Olivier Smiljanic. In this method, the aim is to reproduce the conditions prevailing in the arc discharge and laser ablation approaches, but a carbon-containing gas is used instead of graphite vapors to supply the necessary carbon. Doing so, the growth of SWNT is more efficient (decomposing the gas can be 10 times less energy-consuming than graphite vaporization). The process is also continuous and low cost. A gaseous mixture of argon, ethylene and ferrocene is introduced into a microwave plasma torch, where it is atomized by the atmospheric pressure plasma, which has the form of an intense 'flame'. The fumes created by the flame contain SWNT, metallic and carbon nanoparticles and amorphous carbon.[9][10]

Another way to produce single-walled carbon nanotubes with a plasma torch is to use the induction thermal plasma method, implemented in 2005 by groups from the University of Sherbrooke and the National Research Council of Canada.[11] The method is similar to arc discharge in that both use ionized gas to reach the high temperature necessary to vaporize carbon-containing substances and the metal catalysts necessary for the ensuing nanotube growth. The thermal plasma is induced by high-frequency oscillating currents in a coil, and is maintained in flowing inert gas. Typically, a feedstock of carbon black and metal catalyst particles is fed into the plasma, and then cooled down to form single-walled carbon nanotubes. Different single-wall carbon nanotube diameter distributions can be synthesized.

The induction thermal plasma method can produce up to 2 grams of nanotube material per minute, which is higher than the arc discharge or the laser ablation methods.

Chemical vapor deposition (CVD)[edit]

Nanotubes being grown by plasma enhanced chemical vapor deposition

The catalytic vapor phase deposition of carbon was reported in 1952[12] and 1959,[13] but it was not until 1993[14] that carbon nanotubes were formed by this process. In 2007, researchers at the University of Cincinnati (UC) developed a process to grow aligned carbon nanotube arrays of length 18 mm on a FirstNano ET3000 carbon nanotube growth system.[15]

During CVD, a substrate is prepared with a layer of metal catalyst particles, most commonly nickel, cobalt,[16] iron, or a combination.[17] The metal nanoparticles can also be produced by other ways, including reduction of oxides or oxides solid solutions. The diameters of the nanotubes that are to be grown are related to the size of the metal particles. This can be controlled by patterned (or masked) deposition of the metal, annealing, or by plasma etching of a metal layer. The substrate is heated to approximately 700 °C. To initiate the growth of nanotubes, two gases are bled into the reactor: a process gas (such as ammonia, nitrogen or hydrogen) and a carbon-containing gas (such as acetylene, ethylene, ethanol or methane). Nanotubes grow at the sites of the metal catalyst; the carbon-containing gas is broken apart at the surface of the catalyst particle, and the carbon is transported to the edges of the particle, where it forms the nanotubes. This mechanism is still being studied.[18] The catalyst particles can stay at the tips of the growing nanotube during growth, or remain at the nanotube base, depending on the adhesion between the catalyst particle and the substrate.[19] Thermal catalytic decomposition of hydrocarbon has become an active area of research and can be a promising route for the bulk production of CNTs. Fluidised bed reactor is the most widely used reactor for CNT preparation. Scale-up of the reactor is the major challenge.[20][21]

CVD is the most widely used method for the production of carbon nanotubes.[22] For this purpose, the metal nanoparticles are mixed with a catalyst support such as MgO or Al2O3 to increase the surface area for higher yield of the catalytic reaction of the carbon feedstock with the metal particles. One issue in this synthesis route is the removal of the catalyst support via an acid treatment, which sometimes could destroy the original structure of the carbon nanotubes. However, alternative catalyst supports that are soluble in water have proven effective for nanotube growth.[23]

If a plasma is generated by the application of a strong electric field during growth (plasma-enhanced chemical vapor deposition), then the nanotube growth will follow the direction of the electric field.[24] By adjusting the geometry of the reactor it is possible to synthesize vertically aligned carbon nanotubes[25] (i.e., perpendicular to the substrate), a morphology that has been of interest to researchers interested in electron emission from nanotubes. Without the plasma, the resulting nanotubes are often randomly oriented. Under certain reaction conditions, even in the absence of a plasma, closely spaced nanotubes will maintain a vertical growth direction resulting in a dense array of tubes resembling a carpet or forest.

Of the various means for nanotube synthesis, CVD shows the most promise for industrial-scale deposition, because of its price/unit ratio, and because CVD is capable of growing nanotubes directly on a desired substrate, whereas the nanotubes must be collected in the other growth techniques. The growth sites are controllable by careful deposition of the catalyst.[26] In 2007, a team from Meijo University demonstrated a high-efficiency CVD technique for growing carbon nanotubes from camphor.[27] Researchers at Rice University, until recently led by the late Richard Smalley, have concentrated upon finding methods to produce large, pure amounts of particular types of nanotubes. Their approach grows long fibers from many small seeds cut from a single nanotube; all of the resulting fibers were found to be of the same diameter as the original nanotube and are expected to be of the same type as the original nanotube.[28]

Super-growth CVD[edit]

Super-growth CVD (water-assisted chemical vapor deposition) was developed by Kenji Hata, Sumio Iijima and co-workers at AIST, Japan.[29] In this process, the activity and lifetime of the catalyst are enhanced by addition of water into the CVD reactor. Dense millimeter-tall vertically aligned nanotube arrays (VANTAs) or "forests", aligned normal to the substrate, were produced. The forests height could be expressed, as

In this equation, β is the initial growth rate and is the characteristic catalyst lifetime.[30]

Their specific surface exceeds 1,000 m2/g (capped) or 2,200 m2/g (uncapped),[31] surpassing the value of 400–1,000 m2/g for HiPco samples. The synthesis efficiency is about 100 times higher than for the laser ablation method. The time required to make SWNT forests of the height of 2.5 mm by this method was 10 minutes in 2004. Those SWNT forests can be easily separated from the catalyst, yielding clean SWNT material (purity >99.98%) without further purification. For comparison, the as-grown HiPco CNTs contain about 5–35%[32] of metal impurities; it is therefore purified through dispersion and centrifugation that damages the nanotubes. Super-growth avoids this problem. Patterned highly organized single-walled nanotube structures were successfully fabricated using the super-growth technique.

The mass density of super-growth CNTs is about 0.037 g/cm3.[33][34] It is much lower than that of conventional CNT powders (~1.34 g/cm3), probably because the latter contain metals and amorphous carbon.

The super-growth method is basically a variation of CVD. Therefore, it is possible to grow material containing SWNT, DWNTs and MWNTs, and to alter their ratios by tuning the growth conditions.[35] Their ratios change by the thinness of the catalyst. Many MWNTs are included so that the diameter of the tube is wide.[34]

The vertically aligned nanotube forests originate from a "zipping effect" when they are immersed in a solvent and dried. The zipping effect is caused by the surface tension of the solvent and the van der Waals forces between the carbon nanotubes. It aligns the nanotubes into a dense material, which can be formed in various shapes, such as sheets and bars, by applying weak compression during the process. Densification increases the Vickers hardness by about 70 times and density is 0.55 g/cm3. The packed carbon nanotubes are more than 1 mm long and have a carbon purity of 99.9% or higher; they also retain the desirable alignment properties of the nanotubes forest.[36]

Liquid Electrolysis method[edit]

In 2015, researchers in the George Washington University discovered a new pathway to synthesize MWCNTs by electrolysis of molten carbonates.[37] The mechanism is similar to CVD. Some metal ions were reduced to a metal form and attached on the cathode as the nucleation point for the growing of CNTs. The reaction on the cathode is

The formed lithium oxide can in-situ absorb carbon dioxide (if present) and form lithium carbonate, as shown in the equation.

Thus the net reaction is

In other words, the reactant is only greenhouse gas of carbon dioxide, while the product is high valued CNTs. This discovery was highlighted by Science[38][39], BBC news[40], MIT technology news[41], etc., as a possible technology for carbon dioxide capture and conversions.

Natural, incidental, and controlled flame environments[edit]

Fullerenes and carbon nanotubes are not necessarily products of high-tech laboratories; they are commonly formed in such mundane places as ordinary flames,[42] produced by burning methane,[43] ethylene,[44] and benzene,[45] and they have been found in soot from both indoor and outdoor air.[46] However, these naturally occurring varieties can be highly irregular in size and quality because the environment in which they are produced is often highly uncontrolled. Thus, although they can be used in some applications, they can lack in the high degree of uniformity necessary to satisfy the many needs of both research and industry. Recent efforts have focused on producing more uniform carbon nanotubes in controlled flame environments.[47][48][49][50] Such methods have promise for large-scale, low-cost nanotube synthesis based on theoretical models,[51] though they must compete with rapidly developing large scale CVD production.


Removal of catalysts[edit]

Nanoscale metal catalysts are important ingredients for fixed- and fluidized-bed CVD synthesis of CNTs. They allow increasing the growth efficiency of CNTs and may give control over their structure and chirality.[52] During synthesis, catalysts can convert carbon precursors into tubular carbon structures but can also form encapsulating carbon overcoats. Together with metal oxide supports they may therefore attach to or become incorporated into the CNT product.[53] The presence of metal impurities can be problematic for many applications. Especially catalyst metals like nickel, cobalt or yttrium may be of toxicological concern.[54] While unencapsulated catalyst metals may be readily removable by acid washing, encapsulated ones require oxidative treatment for opening their carbon shell.[55] The effective removal of catalysts, especially of encapsulated ones, while preserving the CNT structure is a challenge and has been addressed in many studies.[56][57] A new approach to break carbonaceaous catalyst encapsulations is based on rapid thermal annealing.[58]

Application-related issues[edit]

Centrifuge tube with a solution of carbon nanotubes, which were sorted by diameter using density-gradient ultracentrifugation.[59]

Many electronic applications of carbon nanotubes crucially rely on techniques of selectively producing either semiconducting or metallic CNTs, preferably of a certain chirality. Several methods of separating semiconducting and metallic CNTs are known, but most of them are not yet suitable for large-scale technological processes. The most efficient method relies on density-gradient ultracentrifugation, which separates surfactant-wrapped nanotubes by the minute difference in their density. This density difference often translates into difference in the nanotube diameter and (semi)conducting properties.[59] Another method of separation uses a sequence of freezing, thawing, and compression of SWNTs embedded in agarose gel. This process results in a solution containing 70% metallic SWNTs and leaves a gel containing 95% semiconducting SWNTs. The diluted solutions separated by this method show various colors.[60][61] The separated carbon nanotubes using this method have been applied to electrodes, e.g. electric double-layer capacitor.[62] Moreover, SWNTs can be separated by the column chromatography method. Yield is 95% in semiconductor type SWNT and 90% in metallic type SWNT.[63]

In addition to separation of semiconducting and metallic SWNTs, it is possible to sort SWNTs by length, diameter, and chirality. The highest resolution length sorting, with length variation of <10%, has thus far been achieved by size exclusion chromatography (SEC) of DNA-dispersed carbon nanotubes (DNA-SWNT).[64] SWNT diameter separation has been achieved by density-gradient ultracentrifugation (DGU)[65] using surfactant-dispersed SWNTs and by ion-exchange chromatography (IEC) for DNA-SWNT.[66] Purification of individual chiralities has also been demonstrated with IEC of DNA-SWNT: specific short DNA oligomers can be used to isolate individual SWNT chiralities. Thus far, 12 chiralities have been isolated at purities ranging from 70% for (8,3) and (9,5) SWNTs to 90% for (6,5), (7,5) and (10,5)SWNTs.[67] There have been successful efforts to integrate these purified nanotubes into devices, e. g. FETs.[68]

An alternative to separation is development of a selective growth of semiconducting or metallic CNTs. Recently, a new CVD recipe that involves a combination of ethanol and methanol gases and quartz substrates resulting in horizontally aligned arrays of 95–98% semiconducting nanotubes was announced.[69]

Nanotubes are usually grown on nanoparticles of magnetic metal (Fe, Co), which facilitates production of electronic (spintronic) devices. In particular, control of current through a field-effect transistor by magnetic field has been demonstrated in such a single-tube nanostructure.[70]


  1. ^ K. Takeuchi, T. Hayashi, Y. A. Kim, K. Fujisawa, M. Endo "The state-of-the-art science and applications of carbon nanotubes", February 2014, Volume 5, Issue 1, pp 15
  2. ^ Iijima, Sumio (1991). "Helical microtubules of graphitic carbon". Nature. 354 (6348): 56–58. Bibcode:1991Natur.354...56I. doi:10.1038/354056a0.
  3. ^ Ebbesen, T. W.; Ajayan, P. M. (1992). "Large-scale synthesis of carbon nanotubes". Nature. 358 (6383): 220–222. Bibcode:1992Natur.358..220E. doi:10.1038/358220a0.
  4. ^ a b Collins, P.G. (2000). "Nanotubes for Electronics". Scientific American: 67–69.
  5. ^ Eatemadi, Ali; Daraee, Hadis; Karimkhanloo, Hamzeh; Kouhi, Mohammad; Zarghami, Nosratollah; Akbarzadeh, Abolfazl; Abasi, Mozhgan; Hanifehpour, Younes; Woo Joo, Sang (2014). "Carbon nanotubes: properties, synthesis, purification, and medical applications". Nanoscale Research Letters. 9 (1): 1–13. Bibcode:2014NRL.....9....1L. doi:10.1186/1556-276X-9-1. PMC 3895740. PMID 24380376.
  6. ^ Guo, Ting; Nikolaev, Pavel; Rinzler, Andrew G.; Tomanek, David; Colbert, Daniel T.; Smalley, Richard E. (1995). "Self-Assembly of Tubular Fullerenes" (PDF). J. Phys. Chem. 99 (27): 10694–10697. doi:10.1021/j100027a002.
  7. ^ Guo, Ting; Nikolaev, P; Thess, A; Colbert, D; Smalley, R (1995). "Catalytic growth of single-walled nanotubes by laser vaporization" (PDF). Chem. Phys. Lett. 243 (1–2): 49–54. Bibcode:1995CPL...243...49B. doi:10.1016/0009-2614(95)00825-O. Archived from the original (PDF) on 24 July 2011.
  8. ^ M.B. Belonenko; et al. (2014). "Few cycle pulses in the bragg medium containing carbon nanotubes" (PDF). Nanosystems: Physics, Chemistry, Mathematics. 14 (5): 644.
  9. ^ Smiljanic, Olivier; Stansfield, B.L.; Dodelet, J.-P.; Serventi, A.; Désilets, S. (22 April 2002). "Gas-phase synthesis of SWNT by an atmospheric pressure plasma jet". Chemical Physics Letters. 356 (3–4): 189–193. Bibcode:2002CPL...356..189S. doi:10.1016/S0009-2614(02)00132-X.
  10. ^ Smiljanic, Olivier. "Method and apparatus for producing single-wall carbon nanotubes". US Patent.
  11. ^ Kim, K.S.; Cota-Sanchez, German; Kingston, Chris; Imris, M.; Simard, Benoît; Soucy, Gervais (2007). "Large-scale production of single-wall carbon nanotubes by induction thermal plasma". Journal of Physics D: Applied Physics. 40 (8): 2375–2387. Bibcode:2007JPhD...40.2375K. doi:10.1088/0022-3727/40/8/S17.
  12. ^ Радушкевич, Л. В. (1952). О Структуре Углерода, Образующегося При Термическом Разложении Окиси Углерода На Железном Контакте (PDF). Журнал Физической Химии (in Russian). 26: 88–95.
  13. ^ Walker Jr., P. L.; Rakszawski, J. F.; Imperial, G. R. (1959). "Carbon Formation from Carbon Monoxide-Hydrogen Mixtures over Iron Catalysts. I. Properties of Carbon Formed". J. Phys. Chem. 63 (2): 133–140. doi:10.1021/j150572a002.
  14. ^ José-Yacamán, M.; Miki-Yoshida, M.; Rendón, L.; Santiesteban, J. G. (1993). "Catalytic growth of carbon microtubules with fullerene structure". Appl. Phys. Lett. 62 (6): 657. Bibcode:1993ApPhL..62..657J. doi:10.1063/1.108857.
  15. ^ Beckman, Wendy (27 April 2007). "UC Researchers Shatter World Records with Length of Carbon Nanotube Arrays". University of Cincinnati.
  16. ^ Inami, Nobuhito; Ambri Mohamed, Mohd; Shikoh, Eiji; Fujiwara, Akihiko (2007). "Synthesis-condition dependence of carbon nanotube growth by alcohol catalytic chemical vapor deposition method" (PDF). Sci. Technol. Adv. Mater. 8 (4): 292–295. Bibcode:2007STAdM...8..292I. doi:10.1016/j.stam.2007.02.009.
  17. ^ N. Ishigami; Ago, H; Imamoto, K; Tsuji, M; Iakoubovskii, K; Minami, N (2008). "Crystal Plane Dependent Growth of Aligned Single-Walled Carbon Nanotubes on Sapphire". J. Am. Chem. Soc. 130 (30): 9918–9924. doi:10.1021/ja8024752. PMID 18597459.
  18. ^ Naha, Sayangdev; Ishwar K. Puri (2008). "A model for catalytic growth of carbon nanotubes". Journal of Physics D: Applied Physics. 41 (6): 065304. Bibcode:2008JPhD...41f5304N. doi:10.1088/0022-3727/41/6/065304.
  19. ^ Banerjee, Soumik, Naha, Sayangdev, and Ishwar K. Puri (2008). "Molecular simulation of the carbon nanotube growth mode during catalytic synthesis". Applied Physics Letters. 92 (23): 233121. Bibcode:2008ApPhL..92w3121B. doi:10.1063/1.2945798. hdl:10919/47394.
  20. ^ Pinilla, JL; Moliner, R; Suelves, I; Lazaro, M; Echegoyen, Y; Palacios, J (2007). "Production of hydrogen and carbon nanofibers by thermal decomposition of methane using metal catalysts in a fluidized bed reactor". International Journal of Hydrogen Energy. 32 (18): 4821–4829. doi:10.1016/j.ijhydene.2007.08.013.
  21. ^ Muradov, N (2001). "Hydrogen via methane decomposition: an application for decarbonization of fossil fuels". International Journal of Hydrogen Energy. 26 (11): 1165–1175. doi:10.1016/S0360-3199(01)00073-8.
  22. ^ Kumar, M. (2010). "Chemical vapor deposition of carbon nanotubes: a review on growth mechanism and mass production". Journal of Nanoscience and Nanotechnology. 10 (6): 6. CiteSeerX doi:10.1166/jnn.2010.2939.
  23. ^ Eftekhari, A.; Jafarkhani, P; Moztarzadeh, F (2006). "High-yield synthesis of carbon nanotubes using a water-soluble catalyst support in catalytic chemical vapor deposition". Carbon. 44 (7): 1343–1345. doi:10.1016/j.carbon.2005.12.006.
  24. ^ Ren, Z. F.; Huang, ZP; Xu, JW; Wang, JH; Bush, P; Siegal, MP; Provencio, PN (1998). "Synthesis of Large Arrays of Well-Aligned Carbon Nanotubes on Glass". Science (Submitted manuscript). 282 (5391): 1105–7. Bibcode:1998Sci...282.1105R. doi:10.1126/science.282.5391.1105. PMID 9804545.
  25. ^ SEM images & TEM images of carbon nanotubes, aligned carbon nanotube arrays, and nanoparticles.
  26. ^ Neupane, Suman; Lastres, Mauricio; Chiarella, M; Li, W.Z.; Su, Q; Du, G.H. (2012). "Synthesis and field emission properties of vertically aligned carbon nanotube arrays on copper". Carbon. 50 (7): 2641–50. doi:10.1016/j.carbon.2012.02.024.
  27. ^ Kumar, Mukul; Ando, Yoshinori (2007). "Carbon Nanotubes from Camphor: An Environment-Friendly Nanotechnology" (PDF). Journal of Physics: Conference Series. 61 (1): 643–646. Bibcode:2007JPhCS..61..643K. doi:10.1088/1742-6596/61/1/129.
  28. ^ Smalley, Richard E.; Li, Yubao; Moore, Valerie C.; Price, B. Katherine; Colorado, Ramon; Schmidt, Howard K.; Hauge, Robert H.; Barron, Andrew R.; Tour, James M. (2006). "Single Wall Carbon Nanotube Amplification: En Route to a Type-Specific Growth Mechanism". Journal of the American Chemical Society. 128 (49): 15824–15829. doi:10.1021/ja065767r. ISSN 0002-7863. PMID 17147393.
  29. ^ Hata, K.; Futaba, DN; Mizuno, K; Namai, T; Yumura, M; Iijima, S (2004). "Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes". Science. 306 (5700): 1362–1365. Bibcode:2004Sci...306.1362H. CiteSeerX doi:10.1126/science.1104962. PMID 15550668.
  30. ^ Futaba, Don; Hata, Kenji; Yamada, Takeo; Mizuno, Kohei; Yumura, Motoo; Iijima, Sumio (2005). "Kinetics of Water-Assisted Single-Walled Carbon Nanotube Synthesis Revealed by a Time-Evolution Analysis". Phys. Rev. Lett. 95 (5): 056104. Bibcode:2005PhRvL..95e6104F. doi:10.1103/PhysRevLett.95.056104. PMID 16090893.
  31. ^ Hiraoka, Tatsuki; Izadi-Najafabadi, Ali; Yamada, Takeo; Futaba, Don N.; Yasuda, Satoshi; Tanaike, Osamu; Hatori, Hiroaki; Yumura, Motoo; et al. (2009). "Compact and light supercapacitors from a surface-only solid by opened carbon nanotubes with 2,200 m2/g". Advanced Functional Materials. 20 (3): 422–428. doi:10.1002/adfm.200901927.
  32. ^ "Unidym product sheet SWNT" (PDF). Archived from the original (PDF) on 2011-07-17.
  33. ^ "Characteristic of Carbon nanotubes by super-growth method" (in Japanese).
  34. ^ a b K.Hata. "From Highly Efficient Impurity-Free CNT Synthesis to DWNT forests, CNTsolids and Super-Capacitors" (PDF).
  35. ^ Yamada, Takeo; Namai, Tatsunori; Hata, Kenji; Futaba, Don N.; Mizuno, Kohei; Fan, Jing; Yudasaka, Masako; Yumura, Motoo; Iijima, Sumio (2006). "Size-selective growth of double-walled carbon nanotube forests from engineered iron catalysts". Nature Nanotechnology. 1 (2): 131–136. Bibcode:2006NatNa...1..131Y. doi:10.1038/nnano.2006.95. PMID 18654165.
  36. ^ Futaba, Don N.; Hata, Kenji; Yamada, Takeo; Hiraoka, Tatsuki; Hayamizu, Yuhei; Kakudate, Yozo; Tanaike, Osamu; Hatori, Hiroaki; et al. (2006). "Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes". Nature Materials. 5 (12): 987–994. Bibcode:2006NatMa...5..987F. doi:10.1038/nmat1782. PMID 17128258.
  37. ^ Ren, Jiawen; Li, Fang-Fang; Lau, Jason; González-Urbina, Luis; Licht, Stuart (2015-08-05). "One-Pot Synthesis of Carbon Nanofibers from CO2". Nano Letters. 15 (9): 6142–6148. doi:10.1021/acs.nanolett.5b02427. ISSN 1530-6984.
  38. ^ "A carbon capture strategy that pays". Science | AAAS. 2015-08-19. Retrieved 2018-10-26.
  39. ^ Service, Robert F. (2015-09-11). "Conjuring chemical cornucopias out of thin air". Science. 349 (6253): 1160–1160. doi:10.1126/science.349.6253.1160. ISSN 0036-8075. PMID 26359385.
  40. ^ Webb, Jonathan (2015-08-20). "Carbon fibres made from air". BBC News. Retrieved 2018-10-26.
  41. ^ "MIT Technology Review | Researcher Demonstrates How to Suck Carbon from the Air, Make Stuff from It | HTA Network". Retrieved 2018-10-26.
  42. ^ Singer, J.M. (1959). "Carbon formation in very rich hydrocarbon-air flames. I. Studies of chemical content, temperature, ionization and particulate matter". Seventh Symposium (International) on Combustion.
  43. ^ Yuan, Liming; Saito, Kozo; Pan, Chunxu; Williams, F.A; Gordon, A.S (2001). "Nanotubes from methane flames". Chemical Physics Letters. 340 (3–4): 237–241. Bibcode:2001CPL...340..237Y. doi:10.1016/S0009-2614(01)00435-3.
  44. ^ Yuan, Liming; Saito, Kozo; Hu, Wenchong; Chen, Zhi (2001). "Ethylene flame synthesis of well-aligned multi-walled carbon nanotubes". Chemical Physics Letters. 346 (1–2): 23–28. Bibcode:2001CPL...346...23Y. doi:10.1016/S0009-2614(01)00959-9.
  45. ^ Duan, H. M.; McKinnon, J. T. (1994). "Nanoclusters Produced in Flames". Journal of Physical Chemistry. 98 (49): 12815–12818. doi:10.1021/j100100a001.
  46. ^ Murr, L. E.; Bang, J.J.; Esquivel, E.V.; Guerrero, P.A.; Lopez, D.A. (2004). "Carbon nanotubes, nanocrystal forms, and complex nanoparticle aggregates in common fuel-gas combustion sources and the ambient air". Journal of Nanoparticle Research. 6 (2/3): 241–251. Bibcode:2004JNR.....6..241M. doi:10.1023/B:NANO.0000034651.91325.40.
  47. ^ Vander Wal, R.L. (2002). "Fe-catalyzed single-walled carbon nanotube synthesis within a flame environment". Combust. Flame. 130 (1–2): 37–47. doi:10.1016/S0010-2180(02)00360-7.
  48. ^ Saveliev, A.V.; Merchan-Merchan, Wilson; Kennedy, Lawrence A. (2003). "Metal catalyzed synthesis of carbon nanostructures in an opposed flow methane oxygen flame". Combust. Flame. 135 (1–2): 27–33. doi:10.1016/S0010-2180(03)00142-1.
  49. ^ Height, M.J.; Howard, Jack B.; Tester, Jefferson W.; Vander Sande, John B. (2004). "Flame synthesis of single-walled carbon nanotubes". Carbon. 42 (11): 2295–2307. doi:10.1016/j.carbon.2004.05.010.
  50. ^ Sen, S.; Puri, Ishwar K (2004). "Flame synthesis of carbon nanofibers and nanofibers composites containing encapsulated metal particles". Nanotechnology. 15 (3): 264–268. Bibcode:2004Nanot..15..264S. doi:10.1088/0957-4484/15/3/005.
  51. ^ Naha, Sayangdev; Sen, Swarnendu; De, Anindya K.; Puri, Ishwar K. (2007). "A detailed model for the Flame synthesis of carbon nanotubes and nanofibers". Proceedings of the Combustion Institute. 31 (2): 1821–29. doi:10.1016/j.proci.2006.07.224.
  52. ^ Yamada T, Namai T, Hata K, Futaba DN, Mizuno K, Fan J, et al. (2006). "Size-selective growth of double-walled carbon nanotube forests from engineered iron catalysts". Nature Nanotechnology. 1 (2): 131–136. Bibcode:2006NatNa...1..131Y. doi:10.1038/nnano.2006.95. PMID 18654165.
  53. ^ MacKenzie KJ, Dunens OM, Harris AT (2010). "An updated review of synthesis parameters and growth mechanisms for carbon nanotubes in fluidized beds". Industrial & Engineering Chemical Research. 49 (11): 5323–38. doi:10.1021/ie9019787.
  54. ^ Jakubek LM, Marangoudakis S, Raingo J, Liu X, Lipscombe D, Hurt RH; Marangoudakis; Raingo; Liu; Lipscombe; Hurt (2009). "The inhibition of neuronal calcium ion channels by trace levels of yttrium released from carbon nanotubes". Biomaterials. 30 (31): 6351–6357. doi:10.1016/j.biomaterials.2009.08.009. PMC 2753181. PMID 19698989.
  55. ^ Hou PX, Liu C, Cheng HM (2008). "Purification of carbon nanotubes". Carbon. 46 (15): 2003–2025. doi:10.1016/j.carbon.2008.09.009.
  56. ^ Ebbesen TW, Ajayan PM, Hiura H, Tanigaki K; Ajayan; Hiura; Tanigaki (1994). "Purification of nanotubes". Nature. 367 (6463): 519. Bibcode:1994Natur.367..519E. doi:10.1038/367519a0.
  57. ^ Xu Y-Q, Peng H, Hauge RH, Smalley RE; Peng; Hauge; Smalley (2005). "Controlled multistep purification of single-walled carbon nanotubes". Nano Letters. 5 (1): 163–168. Bibcode:2005NanoL...5..163X. CiteSeerX doi:10.1021/nl048300s. PMID 15792432.
  58. ^ Meyer-Plath A, Orts-Gil G, Petrov S, et al. (2012). "Plasma-thermal purification and annealing of carbon nanotubes". Carbon. 50 (10): 3934–3942. doi:10.1016/j.carbon.2012.04.049.
  59. ^ a b Arnold, Michael S.; Green, Alexander A.; Hulvat, James F.; Stupp, Samuel I.; Hersam, Mark C. (2006). "Sorting carbon nanotubes by electronic structure using density differentiation". Nature Nanotechnology. 1 (1): 60–5. Bibcode:2006NatNa...1...60A. doi:10.1038/nnano.2006.52. PMID 18654143.
  60. ^ Tanaka, Takeshi; Jin, Hehua; Miyata, Yasumitsu; Fujii, Shunjiro; Suga, Hiroshi; Naitoh, Yasuhisa; Minari, Takeo; Miyadera, Tetsuhiko; et al. (2009). "Simple and Scalable Gel-Based Separation of Metallic and Semiconducting Carbon Nanotubes". Nano Letters. 9 (4): 1497–1500. Bibcode:2009NanoL...9.1497T. doi:10.1021/nl8034866. PMID 19243112.
  61. ^ T.Tanaka. "New, Simple Method for Separation of Metallic and Semiconducting Carbon Nanotubes".
  62. ^ Yamada, Y.; Tanaka, T.; Machida, K.; Suematsu, S.; Tamamitsu, K.; Kataura, H.; Hatori, H. (2012). "Electrochemical behavior of metallic and semiconducting single-wall carbon nanotubes for electric double-layer capacitor". Carbon. 50 (3): 1422–1424. doi:10.1016/j.carbon.2011.09.062.
  63. ^ Tanaka, Takeshi; Urabe, Yasuko; Nishide, Daisuke; Kataura, Hiromichi (2009). "Continuous Separation of Metallic and Semiconducting Carbon Nanotubes Using Agarose Gel". Applied Physics Express. 2 (12): 125002. Bibcode:2009APExp...2l5002T. doi:10.1143/APEX.2.125002.
  64. ^ Huang, Xueying; McLean, Robert S.; Zheng, Ming (2005). "High-Resolution Length Sorting and Purification of DNA-Wrapped Carbon Nanotubes by Size-Exclusion Chromatography". Anal. Chem. 77 (19): 6225–6228. doi:10.1021/ac0508954. PMID 16194082.
  65. ^ Mark C Hersam (2008). "Progress towards monodisperse single-walled carbon nanotubes". Nature Nanotechnology. 3 (7): 387–394. Bibcode:2008NatNa...3..387H. doi:10.1038/nnano.2008.135. PMID 18654561.
  66. ^ Zheng, M.; Jagota, A; Strano, MS; Santos, AP; Barone, P; Chou, SG; Diner, BA; Dresselhaus, MS; et al. (2003). "Structure-Based Carbon Nanotube Sorting by Sequence-Dependent DNA Assembly". Science. 302 (5650): 1545–1548. Bibcode:2003Sci...302.1545Z. doi:10.1126/science.1091911. PMID 14645843.
  67. ^ Tu, Xiaomin; Manohar, Suresh; Jagota, Anand; Zheng, Ming (2009). "DNA sequence motifs for structure-specific recognition and separation of carbon nanotubes". Nature. 460 (7252): 250–253. Bibcode:2009Natur.460..250T. doi:10.1038/nature08116. PMID 19587767.
  68. ^ Zhang, Li; Tu, Xiaomin; Welsher, Kevin; Wang, Xinran; Zheng, Ming; Dai, Hongjie (2009). "Optical characterizations and electronic devices of nearly pure (10,5) single-walled carbon nanotubes". J Am Chem Soc. 131 (7): 2454–2455. arXiv:0902.0010. doi:10.1021/ja8096674. PMID 19193007.
  69. ^ Ding, Lei; Tselev, Alexander; Wang, Jinyong; Yuan, Dongning; Chu, Haibin; McNicholas, Thomas P.; Li, Yan; Liu, Jie (2009). "Selective Growth of Well-Aligned Semiconducting Single-Walled Carbon Nanotubes". Nano Letters. 9 (2): 800–5. Bibcode:2009NanoL...9..800D. doi:10.1021/nl803496s. PMID 19159186.
  70. ^ Mohamed, Mohd Ambri; Inami, Nobuhito; Shikoh, Eiji; Yamamoto, Yoshiyuki; Hori, Hidenobu; Fujiwara, Akihiko (2008). "Fabrication of spintronics device by direct synthesis of single-walled carbon nanotubes from ferromagnetic electrodes" (PDF). Sci. Technol. Adv. Mater. 9 (2): 025019. Bibcode:2008STAdM...9b5019A. doi:10.1088/1468-6996/9/2/025019. PMC 5099751. PMID 27877994.