Talk:Organocopper chemistry
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I was looking the carbocupration section, and it referred to "magnesium(I) bromide" which must be an error - should this be simply magnesium bromide? Walkerma (talk) 01:25, 5 March 2008 (UTC)
- I cannot remember why I wrote that, I should have referenced the statement back then. I have opted for its deletion V8rik (talk) 20:09, 5 March 2008 (UTC)
Higher Order Cuprates[edit]
Should we mentione Higher Order Cuprates?
Lipshutz B.H., Wilhelm R. S., Kozlowski J. A. (1984). "The chemistry of higher order organocuprates". Tetrahedron. 40: 5005–5038. {{cite journal}}: Unknown parameter |Issue= ignored (|issue= suggested) (help)CS1 maint: multiple names: authors list (link)--Stone (talk) 13:03, 14 March 2008 (UTC)
Cyanocuprates[edit]
Cyanocuprates should also definitely be mentioned here.
Lipshutz, B. H. Synthesis 1987, 325.
--OrganicReactions (talk) 04:27, 9 July 2010 (UTC)
Cu(III) intermediates[edit]
The intermediate is square planar, so in the picture this should be taken into account. --Azaline Gomberg (talk) 14:53, 4 March 2012 (UTC)
Copper based reduction reactions[edit]
This entire section is very badly written and the structures illustrating the Stryker reduction are wrong. — Preceding unsigned comment added by Das f (talk • contribs) 14:16, 17 March 2017 (UTC)
- It was not very well written. Some student wrote an essay. You might consider doing the revision.--Smokefoot (talk) 17:44, 17 March 2017 (UTC)
Copper acetylide is non-organic[edit]
Currently,the article states that the first ever organocopper compound synthesized was Copper Acetylide, to my understanding most chemists only consider a molecule organic if it has a carbon-hydrogen bond, which Copper Acetylide lacks. Should this be changed or am i mistaken of the definition of organic? MadePublic (talk) 22:22, 15 November 2022 (UTC)
- I'm not sure about the definition on organic being a carbon-hydrogen bond, as I recall it being carbon-carbon, but that is besides the point. The term organo-metal is not based on "organic molecule" + metal, it is based on a carbon-metal bond. This way, copper acetylide would qualify as organometallic (organocopper), since it has at least one Cu-C bond. Raccoonskydiver (talk) 00:49, 27 February 2024 (UTC)